Abstract
The results obtained on the formation, stability and reactions of CXHy hydrocarbon fragments (CH2, CH3, C2H5 and C3H7) on metal single crystal surfaces, particularly on Rh and Pd, are summarized and discussed. CXHy species are produced by thermal and photo-induced dissociation of corresponding iodo compounds. Methods used include X-ray and ultraviolet photoelectron spectroscopy, high resolution electron energy loss spectroscopy and temperature programmed desorption. Studies performed on supported metals on the chemistry of CXHy fragments and on the reaction of adsorbed CH3 and gaseous CO2 are also reported.
Keywords
- Ultraviolet Photoelectron Spectroscopy
- Adsorbed Ethylene
- Hydrocarbon Fragment
- Submonolayer Coverage
- High Resolution Electron Energy Loss Spectroscopy
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Solymosi, F. (1998). Molecular Chemistry of Alkane Activation. In: Derouane, E.G., Haber, J., Lemos, F., Ribeiro, F.R., Guisnet, M. (eds) Catalytic Activation and Functionalisation of Light Alkanes. NATO ASI Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0982-8_14
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DOI: https://doi.org/10.1007/978-94-017-0982-8_14
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