Abstract
The Balandin type volcano plots have been considered for the main criterion both in catalysis and electrocatalysis to estimate their fundamental properties and optimal activity: (α) The ones, when some physical feature or catalytic activity itself is plotted usually along transition series, and (β) The others, when catalytic activity arises as a function of some energetic property, the most usually of the adsorption enthalpy of intermediates bonding upon the substrate in the rate determining step (rds).
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Pauling, L.: ‘The Nature of Chemical Bond’, 3rd Ed., Cornell Univ. Press, Ithaca, New York, 1960.
Hume-Rothery, W.: Structures of Metals and Alloys, Institute of Metals, London, 1936.
Brewer, L.: Prediction of high temperature metallic phase diagrams, in V.F. Zackay (ed.), High-Strength Materials, Wiley, New York, pp. 12–103, 1965.
Brewer, L.: Prediction of transition metal phase diagrams, J. Nuclear Materials 51 (1974) 2–11.
Jaksic, M.M.: Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory, J. Mol. Catalysis 38(1986) 161–202.
Jaksic, M.M.: Brewer intermetallic phases as synergetic electrocatalysts for hydrogen evolution, Materials Chem. Phys. 22(1989)1–26.
Jaksic, M.M., and Jaksic, J.M.: Fermi dynamics and some structural bonding aspects of electrocatalysis for hydrogen evolution, Electrochim. Acta 39 (1994) 1695–1714.
Jaksic, M.M., and Krstajic, N.V., Electrocatalysis of hydrogen electrode reactions in the light of electronic density of states and structural bonding factors, in J.O’M. Bockris, B.E. Conway and R.E. White (eds.), Modern Aspects of Electrochemistry, to be published in 1998.
Allen, B.C.: The melting points, Trans. Metallurgical Soc. AIME 227 (1963) 1175–1183.
Methfessel, M., Hennig, D., and Scheffler, M.: Trends in the surface relaxations, surface energies, and work functions of the Ad transition metals, Phys. Rev. B 46 (1992) 4816–4829.
Friedel, J., and Sayers, CM.: On the role of d-d electron correlations in the cohesion and ferromagnetism of transition metals, J. Physique 38 (1977) 697–705.
C. Kittel, Introduction to Solid State Physics, sixth ed., Wiley, New York, 1986.
Parsons, R.: The rate of electrolytic hydrogen evolution and the heat of adsorption of hydrogen, Trans. Faraday Soc. 54(1958) 1053–1063.
Gerischer, H.: Mechanismus der elektrolitischen wasserstoffabscheidung und adsorptionsenergie von atomarem Wasserstoff, Bull. Soc. Chim. Belgrade 67 (1958) 506–527.
Trasatti, S.: The work function in electrochemistry, in H. Gerischer and C.W. Tobias (eds.), Advances in Electrochemistry and Electrochemical Engineering, Wiley, New York, Vol. 10, pp. 213–321, 1977.
Trasatti, S.: Chemical and electrochemical surface reactivity, role of the competition between solvent and reaction intermediate adsorption, in W. E. O’Grady, P.H. Ross and F.G. Will (eds.), Proceedings of the Symposium on Electrocatalysis, The Electrochemical Society, Pennington, N.J., Vol. 82-2, pp. 73–91, 1982.
Ruetschi, P., and Delahay, P.: Influence of electrode material on oxygen overvoltage: A theoretical analysis, J. Chem. Physics 23 (1955) 556–560.
Ruetschi, P., and Delahay, P.: Hydrogen overvoltage and electrode material. A theoretical analysis, J. Chem. Phys. 23 (1955) 195–199.
Trasatti, S.: The concept and physical meaning of absolute potential, a reassessment, J. Electroanal. Chem. 139(1982) 1–13.
Kita, H.: Periodic variation of exchange current density of hydrogen electrode reaction with atomic number and reaction mechanism, J. Electrochem. Soc. 113 (1966) 1095–1106.
Brooman, E.W., and Kuhn, A.T.: Correlations between the rate of the hydrogen electrode reaction and the properties of Alloys, J. Electroanal. Chem. 49 (1974) 325–353.
Brewer, L., and Wengert, P.R.: Transition metal alloys of extraordinary stability: An example of generalized Lewis-acid-base interactions in metallic systems. Metallurgical Trans. 4(1973)83–104.
Bernauer, O., Topler, J., Noreus, D., Hempleman, R., and Richter, D.: Fundamentals and properties of some Ti/Mn based Laves phase hydrides, Int. J. Hydrogen Energy 14 (1989) 187–200.
Krstajic, N.V., Grgur, B.N., Mladenovic, N.S., Vojnovic, M.V. and Jaksic, M.M.: The determination of kinetic parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance, Electrochim. Acta 2(1997)323–330.
Krstajic, N.V., Grgur, B.N., Zdujic, M., Vojnovic, M.V., and Jaksic, M.M.: Kinetic properties of the Ti-Ni intermetallic phases and alloys for hydrogen evolution, J. Alloys Comp., (1997) in press.
Notten, P.H.L. and Hokkeling, P.: Double-phase hydride forming compounds: A new class of highly electrocatalytic materials, J. Electrochem. Soc. 138 (1991)1877–1885.
Preskorn, J.N., Chen. H., Chen, W., and Tornquist, W.J.: Electrochemical and infrared spectroscopic comparison of Pt, ZrPt3, and HfPt3 catalytic properties: Hydrogen evolution and CO adsorption, J. Phys. Chem. 96 (1992) 810–816.
Büchner, H.: The hydrogen/hydride energy concept, in A.F. Andresen and A.J. Maeland (eds.), Hydrides for Energy Storage, Pergamon Press, Oxford, pp. 569–597, 1978.
Lacnjevac, C.M., and Jaksic, M.M.: Synergetic electrocatalytic effects of d-metals on the hydrogen evolution reaction in industrially important electrochemical processes, J. Res. Ins. Catalysis, Hokkaido Univ. 31 (1983) 7–34.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Milan, M., Nedeljko, V. (1998). Electrocatalytic and Hydridic Theory for Hydrogen Electrode Reactions and Prediction of Synergetic Catalysts in the Light of Fermi Dynamics and Structural Bonding Factors. In: Saetre, T.O. (eds) Hydrogen Power: Theoretical and Engineering Solutions. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9054-9_12
Download citation
DOI: https://doi.org/10.1007/978-94-015-9054-9_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-5029-8
Online ISBN: 978-94-015-9054-9
eBook Packages: Springer Book Archive