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Electrochemical and in situ STM Studies of UPD and OPD of Metals in Different Model Systems

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Nanoscale Probes of the Solid/Liquid Interface

Part of the book series: NATO ASI Series ((NSSE,volume 288))

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Abstract

Electrochemical and in situ STM studies of underpotential deposition (UPD) and overpotential deposition (OPD) of metals in the systems Ag(hkl)/Pb2+ and Au(hkl)/Ag+ are reviewed. The results are discussed on an atomic level with respect to the mechanism of metal deposition. It is shown that the 2-D UPD adlayers act as precursors for the subsequent OPD process determining the epitaxy and the nucleation and growth mechanism of the 3-D metal bulk phase. Investigations in the multicomponent systems Ag(hkl)/Pb2+, Tl+ and Au(hkl)/Ag+, Pb2+, Tl+ demonstrate the formation of different heterostructured ultra-thin films by LIPD and OPD of metals.

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References

  1. Electrochemical Interfaces: Modern Techniques for In-situ Interface Characterization, Ed. H. Abruna ( VCH Publishers, New York, Weinheim and Cambridge, 1991 ).

    Google Scholar 

  2. Scanning Tunneling Microscopy and Related Methods, Eds. R. J. Behm, N. Garsia, and H. Rohrer, NATO ASI Series E: Applied Sciences- Vol. 184 ( Kluwer Academic Publishers, Dordrecht, Boston and London 1990 ).

    Google Scholar 

  3. Years of STM, Ultramicroscopy 42–44 (1992).

    Google Scholar 

  4. The Liquid/Solid Interface at High Resolution, Faraday Discuss. 94 (1992).

    Google Scholar 

  5. M. G. Samant, M. F. Toney, G. L. Borges, L. Blum, and O. R. Melroy, J. Phys. Chem. 92, 220 (1988).

    Article  CAS  Google Scholar 

  6. M. G. Samant, M. F. Toney, G. L. Borges, L. Blum, and O. R. Melroy, Surf. Sci. 193 L, 29 (1988).

    Google Scholar 

  7. O. R. Melroy, M. F. Toney, G. L. Borgers, M. G. Samant, J. B. Kortright, P. N. Ross, and L. Blum, J. Electroanal. Chem. 258, 403 (1989).

    Article  CAS  Google Scholar 

  8. M. F. Toney and O. R. Melroy, in: Modern Techniques for In-situ Interface Characterization, Ed. H. Abruna ( VCH Publishers, New York, Weinheim and Cambridge, 1991 ) p. 57.

    Google Scholar 

  9. P. Lustenberger, H. Rohrer, R. Christoph, and H. Siegenthaler, J. Electroanal. Chem. 243, 225 (1988).

    Article  CAS  Google Scholar 

  10. R. Christoph, H. Siegenthaler, H. Rohrer, and H. Wiese, Electrochim. Acta 34, 1011 (1989).

    Article  Google Scholar 

  11. H. Siegenthaler and R. Christoph, in: Scanning Tunneling Microscopy and Related Methods, Eds. R. J. Behm, N. Garsia, and H. Rohrer, NATO ASI Series E: Applied Sciences- Vol. 184 ( Kluwer Academic Publishers, Dordrecht, Boston and London 1990 ) p. 315.

    Google Scholar 

  12. D. Carnal, In-situ STM investigation of underpotential deposition of Tl on Ag(111)electrodes, PhD Thesis (University of Bern 1993).

    Google Scholar 

  13. D. Carnal, U. Müller, H. Siegenthaler, J. Chim. Phys., in press.

    Google Scholar 

  14. M. Höpfner, W. Obretenov, K. Jüttner, W. J. Lorenz, G. Staikov, V. Bostanov, and E. Budevski, Surface Sci. 248, 225 (1991).

    Article  Google Scholar 

  15. W. J. Lorenz, L. M. Gassa, U. Schmidt, W. Obretenov, G. Staikov, V. Bostanov, and E. Budevski, Electrochim. Acta 37, 2173 (1992).

    Article  CAS  Google Scholar 

  16. U. Müller, D. Carnal, H. Siegenthaler, E. Schmidt, W. J. Lorenz, W. Obretenov, U. Schmidt, G. Staikov, and E. Budcvski, Phys. Rev. B 46, 12899 (1992).

    Article  Google Scholar 

  17. G. Staikov, E. Budcvski, U. Schmidt, W. Obretenov, and W. J. Lorenz, Proceedings of the International Symposium Galvano ‘91, September 30 - October 2, 1991, Varna, Bulgaria, Eds. N. Atanassov and St. Rashkov (Publishing House of the Bulgarian Academic of Sciences, Sofia, 1992)p. 95.

    Google Scholar 

  18. W. Obretenov, U. Schmidt, W. J. Lorenz, G. Staikov, E. Budevski, D. Carnal, U. Müller, H. Siegenthaler and E. Schmidt, J. Electrochem. Soc. 140, 692 (1993).

    Article  CAS  Google Scholar 

  19. W. Obretenov, U. Schmidt, W. J. Lorenz, G. Staikov, E. Budevski, D. Carnal, U. Müller, H. Siegenthaler, and E. Schmidt, Faraday Discuss. 94, 107 (1992).

    Article  CAS  Google Scholar 

  20. G. Staikov, E. Budcvski, M. Höpfner, W. Obretenov, K. Jüttner, and W. J. Lorenz, Surface Sci. 248, 234 (1991).

    Article  CAS  Google Scholar 

  21. H. J. Pauling, U. Schmidt, G. Staikov, K. Jüttner, W. J. Lorenz, and E. Budevski, Proceedings of the Symposium on Electrochemically Deposited Thin Films, Eds. M. Paunovic, lzumi Ohno, and Yasuhiko Miyoshi,Vol. 92–26 ( The Electrochemical Society, Pennington NJ, 1993 ) p. 19.

    Google Scholar 

  22. G. Staikov, K. Jüttner, W. J. Lorenz, and E. Budevski, Electrochim. Acta, in press.

    Google Scholar 

  23. G. Repphun, U. Schmidt, S. Vinzelberg, G. Staikov, W. J. Lorenz, and J. Halbritter, Phys. Rev. B, submitted.

    Google Scholar 

  24. S. G. Garcia, D. Salinas, C. Mayer, J. R. Vilche, H. J. Pauling, S. Vinzelberg, G. Staikov, and W. J. Lorenz, Surface Sci., submitted.

    Google Scholar 

  25. O. M. Magnussen, J. Hotlos, R. J. Nichols, D. M. Kolb and R. J. Behm, Phys. Rev. Lett. 64, 2929 (1990).

    Article  CAS  Google Scholar 

  26. N. Batina, T. Will and D. M. Kolb, Faraday Discuss. 94, 93 (1992).

    Article  CAS  Google Scholar 

  27. T. Hachiya and K. Itaya, Ultramicroscopy 42–44, 445 (1992).

    Article  Google Scholar 

  28. N. Kimizuka and K. Itaya, Faraday Discuss. 94, 117 (1992).

    Article  CAS  Google Scholar 

  29. Chun-hsien Chen and A. A. Gewirth, Ultramicroscopy 42–44, 437 (1992).

    Article  Google Scholar 

  30. A. A. Gewirth and K. J. Hanson, Interface 2, 1, 37 (1993).

    Google Scholar 

  31. S. G. Corcoran, G. S. Chakarova, and K. Siradzki, Phys. Rev. Lett. 71, 1585 (1993).

    Article  CAS  Google Scholar 

  32. N. J. Tao, J. Pan, Y. Li, P. I. Oden, J. A. DeRose and S. M. Lindsay, Surface Sci. Lett. 271 L338 (1992).

    Article  CAS  Google Scholar 

  33. K. Engelsmann, W. J. Lorenz, and E. Schmidt, J. Electroanal. Chem. 114, 1 (1980).

    Article  CAS  Google Scholar 

  34. W J. Lorenz, E. Schmidt, G. Staikov, and H. Bort, Faraday Symposia of the Chem. Soc. No. 12, 14 (1977).

    Google Scholar 

  35. K. Jüttner, G. Staikov, W. J. Lorenz, and E. Schmidt,J. Electroanal. Chem. 80, 67 (1977).

    Article  Google Scholar 

  36. G. Staikov, K. Jüttner, W. J. Lorenz, and E. Schmidt, Electrochim. Acta 23, 305 (1978).

    Article  CAS  Google Scholar 

  37. G. Staikov, K. Jüttner, W. J. Lorenz, and E. Budevski, Electrochim. Acta 23, 319 (1978).

    Article  CAS  Google Scholar 

  38. H. Bort, K. Jüttner, W. J. Lorenz, and E. Schmidt, J. Electroanal. Chem. 90, 413 (1978).

    Article  CAS  Google Scholar 

  39. K. Jüttner, W. J. Lorenz, G. Staikov, and E. Budevski, Electrochim. Acta 23, 741 (1978).

    Article  Google Scholar 

  40. H. Siegenthalcr and K. Jüttner, Electrochim. Acta 24, 109 (1979).

    Article  Google Scholar 

  41. K. Jüttner and W. J. Lorenz, Z. Phys. Chem. NF 122, 163 (1980).

    Article  Google Scholar 

  42. H. Bort, K. Jüttner, W. J. Lorenz, G. Staikov, and E. Budevski, Electrochim. Acta 28 985 (1983).

    Article  CAS  Google Scholar 

  43. T. Vitanov, A. Popov, G. Staikov, E. Budevski, W. J. Lorenz, and E. Schmidt, Electrochim. Acta 31, 981 (1986).

    Article  CAS  Google Scholar 

  44. A. Bewick and B. Thomas, J. Electroanal. Chem. 65, 911 (1975);

    Article  CAS  Google Scholar 

  45. A. Bewick and B. Thomas, J. Electroanal. Chem. 70, 239 (1976);

    Article  CAS  Google Scholar 

  46. A. Bewick and B. Thomas, J. Electroanal. Chem. 84, 127 (1977);

    Article  CAS  Google Scholar 

  47. A. Bewick and B. Thomas, J. Electroanal. Chem. 85, 329 (1977).

    Article  CAS  Google Scholar 

  48. D. Dickertmann, E. D. Koppitz, and J. W. Schultze, Electrochim. Acta 21, 967 (1976).

    Article  CAS  Google Scholar 

  49. D. Dickertmann and J. W. Schultze, Electrochim. Acta 22, 117 (1977).

    Article  CAS  Google Scholar 

  50. G. Staikov, This volume.

    Google Scholar 

  51. E. Budevski, V. Bostanov, T. Vitanov, Z. Stoynov, A. Kotzeva, and R. Kaischew, Electrochim. Acta 11, 1697 (1966).

    Article  CAS  Google Scholar 

  52. V. Bostanov, A. Kotzeva, and E. Budcvski, Bull. Inst. Chem. Phys. Bulg. Acad. Sci. 6, 33 (1967).

    CAS  Google Scholar 

  53. E. Budevski, V. Bostanov, and G. Staikov, Ann. Rev. Mater. Sci. 10. 85 (1980).

    Article  CAS  Google Scholar 

  54. M. F. Toney, J. G. Gordon, G. L. Borges, O. R. Melroy, D. Yee, and L. B. Sorensen, Phys. Rev. B, submitted.

    Google Scholar 

  55. U. Müller, D. Carnal, H. Siegenthalcr, E. Schmidt, W. J. Lorenz, W. Obretenov, U. Schmidt, G. Staikov, and E. Budevski, Phys. Rev. B, submitted.

    Google Scholar 

  56. G. Staikov, E. Budevski, W. Obretenov, and W. J. Lorenz, J. Electroanal. Chem. 349, 355 (1993).

    Article  CAS  Google Scholar 

  57. C. R. Fuselicr, J. C. Raich, and N. S. Gillis, Surf. Sci. 92, 667 (1980).

    Article  Google Scholar 

  58. A. D. Novaco and J. P. McTague, Phys. Rev. Letters 38, 1286 (1977).

    Article  CAS  Google Scholar 

  59. J. P. McTague and A. D. Novaco, Phys. Rev. B 19, 5299 (1979).

    Article  CAS  Google Scholar 

  60. S. Stoyanov, Surface Sci. 199, 226 (1988).

    Article  CAS  Google Scholar 

  61. C. Kittel, Introduction to Solid State Physics (5th edn)(John Wiley, New York,1976).

    Google Scholar 

  62. K. Engelsmann, W. J. Lorenz, and E. Schmidt, J. Electroanal. Chem. 114, 11 (1980).

    Article  CAS  Google Scholar 

  63. M. Klimmeck and K. Jüttner, Electrochim. Acta 27, 83 (1982).

    Article  CAS  Google Scholar 

  64. J. P. van der Eerden, G. Staikov, D. Kashchiev, W. J. Lorenz, and E. Budevski, Surface Science 82, 364 (1979).

    Article  Google Scholar 

  65. G. Staikov,W. Obretenov, V. Bostanov, E. Budevski, and H. Bort, Electrochim. Acta 25, 1619 (1980).

    Article  Google Scholar 

  66. D. Kashchiev, J. Chem. Phys. 76, 5098 (1982).

    Article  CAS  Google Scholar 

  67. S. Stoyanov, Thin Solid Films 18, 91 (1973).

    Article  CAS  Google Scholar 

  68. A. Milchev, S. Stoyanov, and R. Kaischew, Thin Solid Films 22 255 (1974).

    Article  CAS  Google Scholar 

  69. D. M. Kolb and J. Schneider, Electrochim. Acta 31, 929 (1986).

    Article  CAS  Google Scholar 

  70. X. Gao, A. Hamelin, and M. J. Weaver, Phys. Rev. Lett. 67., 618 (1991).

    Google Scholar 

  71. D. M. Kolb, in: Structure of Electrified Interfaces, Eds. J. Lipkowski and P. N. Ross ( VCH, New York, 1992 ) p. 65.

    Google Scholar 

  72. E. Schmidt and S. Stucki, J. Electroanal. Chem. 39, 63 (1972).

    Article  CAS  Google Scholar 

  73. H.-J. Pauling and K. Jüttner, Electrochim. Acta 37, 2237 (1992).

    Article  CAS  Google Scholar 

  74. K. Yagi, K, Takayabagi, and G. Honjo, in: Crystal Growth, Properties and Applications 7 ( Springer Verlag, Berlin-Heidelberg, 1982 ) p. 47.

    Google Scholar 

  75. T. C. Hsieh and T C. Chiang, Surface Sci. 166, 554 (1986).

    Article  CAS  Google Scholar 

  76. T. Miller,A. Samsavar, G. E. Franklin, and T. C. Chiang, Phys. Rev. Lett. 61, 1404 (1988).

    Article  Google Scholar 

  77. M. M. Dovek, C. A. Lang, J. Nogami, and C. F. Quate, Phys. Rev. B. 40, 11973 (1989).

    Article  CAS  Google Scholar 

  78. D. D. Chambliss and R. J. Wilson, J. Vac. Sci. Technol. B 9, 928 (1991).

    Google Scholar 

  79. G. Reiners, W. J. Lorenz, and H. G. Hertz, Ber. Bunsenges. Phys. Chem. 82, 738 (1978).

    Article  CAS  Google Scholar 

  80. N. Ibl and R. Müller, Z. Elektrochem. 59, 671 (1955).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Chemistry and Electrochemistry, University of Karlsruhe, D-76131, Karlsruhe, Germany

    G. Staikov & W. J. Lorenz

  2. Central Laboratory of Electrochemical Power Sources, Bulgarian Academy of Sciences, BG-1113, Sofia, Bulgaria

    G. Staikov

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  1. G. Staikov
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  2. W. J. Lorenz
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Editors and Affiliations

  1. Department of Chemistry, University of Illinois, 505 S. Mathews Ave, 61801, Urbana, Illinois, USA

    Andrew A. Gewirth

  2. Institut für anorganische Chemie, Universität Bern, Bern, Switzerland

    Hans Siegenthaler

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Staikov, G., Lorenz, W.J. (1995). Electrochemical and in situ STM Studies of UPD and OPD of Metals in Different Model Systems. In: Gewirth, A.A., Siegenthaler, H. (eds) Nanoscale Probes of the Solid/Liquid Interface. NATO ASI Series, vol 288. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8435-7_13

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  • DOI: https://doi.org/10.1007/978-94-015-8435-7_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4541-6

  • Online ISBN: 978-94-015-8435-7

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