Abstract
Two aspects of the self-assembly of complex structures around labile metal ions are discussed. Some experimental methods, including ion-spray mass spectroscopy, spectroscopic titrations, and nmr probes, which allow one to study the self-assembly in solution are presented. The types of chemical information carried by the components and the conditions used for the synthesis are illustrated by examples, particularly in the field of double- and triple-helical complexes.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
J.-M. Lehn, A. Rigault, Angew. Chem. Int. Ed. 1988, 27, 1095.
C. Piguet, J.-C. Bünzli, G. Bernardinelli, G. Hopfgartner, A. F. Williams, J. Am. Chem. Soc. 1993, 115, 8197.
J.-M. Lehn, Angew. Chem. Int. Ed. 1990, 29, 1304.
IS. Lindsey, New J. Chem. 1991, 15, 153.
R.F. Carina, G. Bernardinelli, A.F. Williams, Angew. Chem. Int. Ed. 1993, 32, 1463.
C. Piguet, G. Bernardinelli, A.F. Williams, Inorg. Chem. 1989, 28, 2920.
A.P. Bruins, T.R. Covey, J.D. Henion, Anal Chem. 1987, 59, 2642.
G. Hopfgartner, C. Piguet, J.D. Henion, A.F. Williams, Helv. Chim. Acta, 1993, 76, 1759.
G. Hopfgartner, C. Piguet, J.D. Henion, J. Am. Soc. Mass Spec, in press.
S. Rüttimann, C. Piguet, G. Bernardinelli, B. Bocquet, A.F. Williams, J. Am. Chem. Soc. 1992, 114, 4230.
E.C. Constable, Tetrahedron, 1992, 48, 10013.
R.F. Carina, PhD Thesis, University of Geneva, 1994
J.-M. Lehn, J.-P. Sauvage, J. Simon, R. Ziessel, C. Piccinni-Leopardi, G. Germain, J.-P. Declercq, M. Van Meerssche, Nouv. J. Chimie, 1983, 7, 413
C. Piguet, G. Bernardinelli, B. Bocquet, A. Quattropani, A.F. Williams, J. Am. Chem. Soc. 1992, 114, 7440.
A.F. Williams, C. Piguet, G Bernardinelli, Angew Chem. Int. Ed, 1991, 30, 1490.
E.R. Malinowski, D.G. Howery, Factor analysis in Chemistry, J. Wiley, New York, Chichester, Brisbane, and Toroto, 1980
H. Gampp, M. Maeder, C.J. Meyer, A.D. Zuberbühler, Chimia, 1985, 39, 315.
H. Gampp, M. Maeder, C.J. Meyer, A.D. Zuberbühler, Talanta, 1985; 32, 95.
C. Piguet, B. Bocquet, G. Hopfgartner, Helv. Chim. Acta, in press
C. Piguet, G Hopfgartner, B. Bocquet, O. Schaad, submitted for publication.
S. Rüttimann, G. Bernardinelli, A.F. Williams, Angew Chem. Int. Ed. 1993, 32, 392.
J.-M. Lehn in “Perspectives in Coordination Chemistry”, Ed. A.F. Williams, C. Floriani, A.E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, 447.
W. Zarges, J. Hall, J.-M. Lehn, C. Bolm, Helv. Chim. Acta, 1991, 74, 1843
J.-P. Sauvage, Acc. Chem. Res., 1990, 23, 319.
C. Piguet, G. Bernardinelli, B. Bocquet, O. Schaad, A.F. Williams, submitted for publication.
L.J. Charbonnière, G Bernardinelli, C. Piguet, A.M. Sargeson, A.F. Williams, submitted for publication.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1994 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Williams, A.F., Piguet, C., Carina, R.F. (1994). Following the Self-Assembly Process in Solution. In: Fabbrizzi, L., Poggi, A. (eds) Transition Metals in Supramolecular Chemistry. NATO ASI Series, vol 448. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8380-0_22
Download citation
DOI: https://doi.org/10.1007/978-94-015-8380-0_22
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-4483-9
Online ISBN: 978-94-015-8380-0
eBook Packages: Springer Book Archive