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Pulsed ESR Applied to Microporous and Mesoporous Inorganic Solids

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Multifunctional Mesoporous Inorganic Solids

Part of the book series: NATO ASI Series ((ASIC,volume 400))

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Abstract

Electron spin resonance (ESR) techniques, used with suitable paramagnetic probe ions, are applied to the structural characterisation of micro- and mesoporous inorganic solids. The structural information available is enhanced through the pulsed ESR technique, electron spin echo modulation (ESEM) spectroscopy, which can often resolve weak electron-nuclear hyperfine interactions unresolved in the continuous wave spectrum. Examples are described in which modulation associated with coupled 2D nuclei is used to characterise interactions between paramagnetic probe ions and adsorbed solvents and organic reactant molecules on clays and zeolites. In clays and pillared clays spin echo modulation associated with weak electronnuclear hyperfine coupling with27 Al nuclei provides evidence for interactions between exchangeable cations and both framework and pillar aluminium atoms.

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References

  1. Kevan, L. (1987) Rev. Chem. Intermed., 8, 53.

    Article  CAS  Google Scholar 

  2. Anderson, M.W. and Kevan, L. (1987) J. Chem. Soc. Faraday I, 83, 3505.

    Article  Google Scholar 

  3. Sass, C.E. and Kevan, L. (1988) J. Phys. Chem., 92, 14.

    Article  CAS  Google Scholar 

  4. Sass, C.E. and Kevan, L. (1988) J. Phys. Chem., 92, 5192.

    Article  CAS  Google Scholar 

  5. Ghosh, A.K. and Kevan, L. (1988) J. Amer. Chem. Soc., 110, 8044.

    Article  CAS  Google Scholar 

  6. Brown, D.R. and Kevan, L. (1988) J. Amer. Chem. Soc., 110, 2743.

    Article  CAS  Google Scholar 

  7. Brown, D.R. and Kevan, L. (1988) J. Phys. Chem., 92 1971.

    Article  CAS  Google Scholar 

  8. Brown, D.R., Luca, V. and Kevan, L. (1991) J. Chem. Soc. Faraday, 87 2749.

    Article  CAS  Google Scholar 

  9. Luca, V., Brown, D.R. and Kevan, L. (1991) J. Phys. Chem., 95 10065.

    Article  CAS  Google Scholar 

  10. Kukkadapu, R.K., Luca, V. and Kevan, L. (1992) J. Phys. Chem., 96 415.

    Article  CAS  Google Scholar 

  11. Bogus, W. and Kevan, L. (1989) J. Phys. Chem., 93, 3223.

    Article  CAS  Google Scholar 

  12. Ichikawa, T., Yoshida, H. and Kevan, L. (1981) J. Chem. Phys., 75, 2485.

    Article  CAS  Google Scholar 

  13. Ichikawa, T., Yoshida, H. and Kevan, L. (1982) J. Phys. Chem., 86, 881.

    Article  CAS  Google Scholar 

  14. Narayana, M., Zhan, R.Y. and Kevan, L. (1984) J. Phys. Chem., 88, 3990.

    Article  CAS  Google Scholar 

  15. Narayana, M., Narasimhan, C.S. and Kevan, L. (1983) J. Catal., 79, 237.

    Article  CAS  Google Scholar 

  16. Narayana, M., Narasimhan, C.S. and Kevan, L. (1985) J. Chem. Soc., Faraday I, 81 137.

    Article  CAS  Google Scholar 

  17. Narayana, M., Zhan, R.Y. and Kevan, L. (1985) J. Phys. Chem., 89 636.

    Article  CAS  Google Scholar 

  18. Zhan, R.Y., Narayana, M. and Kevan, L. (1985) J. Chem. Soc. Faraday I, 81, 2085.

    Article  Google Scholar 

  19. McBride, M.B., Pinnavaia, T.J. and Mortland, M.M. (1975) J. Phys. Chem., 79, 2430.

    Article  CAS  Google Scholar 

  20. Clementz, D.M., Pinnavaia, T.J. and Mortland, M.M. (1973) J. Phys. Chem., 77 196.

    Article  CAS  Google Scholar 

  21. McBride, M.B. (1982) Clays Clay Miner., 30, 200.

    Article  CAS  Google Scholar 

  22. Kukkadapu, RK. and Kevan, L. (1989) J.Phys. Chem., 93, 1654.

    Article  CAS  Google Scholar 

  23. Kukkadapu, R.K. and Kevan, L. (1990) J. Chem. Soc. Faraday, 86, 691.

    Article  CAS  Google Scholar 

  24. Dyrek, K., Klapyta, Z. and Sojka, Z. (1983) Clays Clay Miner. 31, 223.

    Article  CAS  Google Scholar 

  25. Martini, G. and Burlamacchi, L. (1979) J. Phys. Chem., 83, 2505.

    Article  CAS  Google Scholar 

  26. Martini, G. and Bassetti, V. (1979) J. Phys. Chem., 83, 2511.

    Article  CAS  Google Scholar 

  27. Brown, D.R. and Kevan, L. (1986) J. Phys. Chem., 90, 1129.

    Article  CAS  Google Scholar 

  28. Braddell, O., Barklie, RC. and Doff, D.H. (1990) Clay Miner., 25, 15.

    Article  CAS  Google Scholar 

  29. McBride, M.B. (1979) Clays Clay Miner., 27, 91.

    Article  CAS  Google Scholar 

  30. McBride, M.B., Pinnavaia, T.J. and Mortland, M.M. (1975) Amer. Miner., 60 66.

    CAS  Google Scholar 

  31. Waterman, K.C., Turro, N.J., Chandar, P. and Somarsundaran, P. (1986) J. Phys. Chem., 90, 6828.

    Article  CAS  Google Scholar 

  32. Chandar, P., Somarsundaran, P., Waterman, K.C. and Turro, N.J. (1987) J. Phys. Chem., 91, 148.

    Article  CAS  Google Scholar 

  33. McBride, M.B. (1976) J. Phys. Chem., 80, 186.

    Article  Google Scholar 

  34. McBride, M.B. (1976) Amer. Chem. Soc. Symp. Ser., 34, 123.

    CAS  Google Scholar 

  35. McBride, M.B. (1977) Clay Miner., 2, 273.

    Article  Google Scholar 

  36. McBride, M.B. (1977) Clays Clay Miner., 25, 6.

    Article  CAS  Google Scholar 

  37. McBride, M.B. (1979) Clays Clay Miner., 27, 97.

    Article  CAS  Google Scholar 

  38. Delvaux, B., Mestdagh, M.M., Vielvoye, L. and Herbillon, A.J. (1989) Clay Miner., 24, 617.

    Article  CAS  Google Scholar 

  39. Luca, V. and Cardile, C.M. (1989) Clays Clay Miner., 37, 325.

    Article  CAS  Google Scholar 

  40. McBride, M.B., Mortland, M.M. and Pinnavaia, T.J. (1975) Clays Clay Miner., 23, 162.

    Article  CAS  Google Scholar 

  41. Goodman, B.A., Nadeau, P.H. and Chadwick, J. (1988) Clay Miner., 23 147.

    Article  CAS  Google Scholar 

  42. Schweiger, A. (1991) Angew. Chem. Int. Ed. Eng., 30, 265.

    Article  Google Scholar 

  43. Kevan, L. and Schwartz, RN. (1979) Time Domain Electron Spin Resonance, Wiley, New York.

    Google Scholar 

  44. Kevan, L. and Bowman, M.K. (1990) Modern Pulsed and Continuous Wave Electron Spin Resonance, Wiley, New York.

    Google Scholar 

  45. Romanelli, M., Goldfarb, D. and Kevan, L. (1988) Magn. Reson. Rev., 11, 179.

    Google Scholar 

  46. Goldfarb, D. and Kevan, L. (1987) J. Chem. Phys., 87, 6323.

    Article  CAS  Google Scholar 

  47. Dyer, A. and Gallardo, T. (1990) in Recent Dev. Ion Exch. [Proc. Int. Conf. Ion. Exch. Processes], Eds. Williams, P.A. and Hudson, M. J., 2,75.

    Google Scholar 

  48. Ichikawa, T., Kevan, L. and Narayana, P.A. (1979) J. Chem. Phys., 71, 3729

    Google Scholar 

  49. Ichikawa, T., Kevan, L. and Narayana, P.A. (1979) J. Phys. Chem., 83, 3378.

    Article  CAS  Google Scholar 

  50. Li, A.S.W. and Kevan, L. (1981) J. Phys. Chem., 85, 2557.

    Article  CAS  Google Scholar 

  51. Grandjean, J. and Laszlo, P. (1989) Clays Clay Miner., 37, 403.

    Article  CAS  Google Scholar 

  52. Ghosh, A.K. and Kevan, L. (1988) J. Amer. Chem. Soc., 110, 8044.

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Catalysis Research Unit, Department of Applied Science, Leeds Polytechnic, Leeds, LS1 3HE, UK

    D. R. Brown

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  1. D. R. Brown
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Editors and Affiliations

  1. Instituto Superior Técnico, Universidade Técnica de Lisboa, Lisboa, Portugal

    César A. C. Sequeira

  2. Department of Chemistry, University of Reading, Reading, UK

    Michael J. Hudson

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© 1993 Springer Science+Business Media Dordrecht

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Brown, D.R. (1993). Pulsed ESR Applied to Microporous and Mesoporous Inorganic Solids. In: Sequeira, C.A.C., Hudson, M.J. (eds) Multifunctional Mesoporous Inorganic Solids. NATO ASI Series, vol 400. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8139-4_30

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  • DOI: https://doi.org/10.1007/978-94-015-8139-4_30

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4275-0

  • Online ISBN: 978-94-015-8139-4

  • eBook Packages: Springer Book Archive

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