Abstract
The area of mesoporous materials tends to suffer from a lack of detailed structural analysis, that is due to a dearth of well crystallisad materials and ill-defined pore size. That is to say that the crystals produced are often 100 small to diffract X-rays coherently, let alone large and sufficiently free of defects for single crystal X-Ray analysis to be possible. This presents a problem to the structural chemist that must be solved by looking further afield than just conventional X-ray methods. One such technique that can cope with short range order is solid state nuclear magnetic resonance (nmr), used with magic angle spinning and also cross-polarisation techniques. This is not to say that other techniques (such as EXAFS, SAXS, Transmission Elation Microscopy, Neutron Diffraction, Nuclear Quadrupole Resonance and Mossbauer) cannot cope with short-range order, or that they are not applicable, or that nmr is without problems, but that nmr is one technique that is readily available and with a wealth of previous studies.
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Hudson, M.J., Workman, A.D. (1993). Solid State Nuclear Magnetic Resonance Spectroscopy. In: Sequeira, C.A.C., Hudson, M.J. (eds) Multifunctional Mesoporous Inorganic Solids. NATO ASI Series, vol 400. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8139-4_27
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DOI: https://doi.org/10.1007/978-94-015-8139-4_27
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