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Solid-State NMR Studies of Catalytic Reactions on Molecular Sieves

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Spectroscopic and Computational Studies of Supramolecular Systems

Part of the book series: Topics in Inclusion Science ((TISC,volume 4))

Abstract

Molecular sieves are a class of porous open-framework solids, which includes aluminosilicates (zeolites), aluminophosphates and silicoaluminophosphates of diverse structures. Zeolites, the original molecular sieves, are built from corner-sharing SiO4 4 and AlO4 5- tetrahedra and contain regular systems of intracrystalline cavities and channels of molecular dimensions. The net negative charge of the framework, equal to the number of the constituent aluminium atoms, is balanced by exchangeable cations, Mn+, typically sodium, located in the channels which normally also contain water. The name “zeolite” (from the Greek ζεω = to boil and λιθoσ = stone) was coined by Cronstedt [1] in 1756 to describe the behaviour of the newly discovered mineral stilbite which, when heated, rapidly loses water and thus seems to boil. . . . .

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Authors
  1. Jacek Klinowski
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Editors and Affiliations

  1. Environmental Science Division, Institute of Environmental and Biological Sciences, Lancaster University, UK

    J. E. D. Davies

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© 1992 Springer Science+Business Media Dordrecht

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Klinowski, J. (1992). Solid-State NMR Studies of Catalytic Reactions on Molecular Sieves. In: Davies, J.E.D. (eds) Spectroscopic and Computational Studies of Supramolecular Systems. Topics in Inclusion Science, vol 4. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7989-6_5

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  • DOI: https://doi.org/10.1007/978-94-015-7989-6_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4203-3

  • Online ISBN: 978-94-015-7989-6

  • eBook Packages: Springer Book Archive

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