Abstract
One of the potentially most important responses of the atmosphere to increasing amounts of trace constituents is a change in the amount and distribution of ozone (O3) in the stratosphere (the region of the atmosphere from approximately 12–50 km). Ozone is important to the terrestrial environment because it absorbs the bulk of the Sun’s ultraviolet (UV) radiation in the important UVB wavelength region (290–320 nm). If ozone abundances were reduced, more DNA-destroying radiation would penetrate to the Earth’s surface, leading to an increased incidence of skin cancers, cataracts, and damage to plant and animal life. This inverse relationship between ozone amounts and penetration of ultraviolet radiation has made the determination of what changes in ozone amounts are actually occurring and what changes are forecast for the future into important environmental questions.
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References
WMO, Atmospheric Ozone, 1985: Assessment of our Understanding of the Processes Controlling its Present Distribution and Change. WMO Report No. 16, WMO, Geneva, 1986.
Farman, J. C., Gardiner, B. G. & Shanklin, J. D., Large losses of total ozone in Antarctica reveal seasonal CIOx/NOX interaction. Nature, 315 (1985) 207–10.
Stolarski, R. S., Krueger, A. J., Schoeberl, M. R., McPeters, R. D., Newman, P. A. & Alpert, J. C., Nimbus 7 SBUV/TOMS measurements of the springtime Antarctic ozone hole. Nature, 322 (1986) 808–11.
NASA, Present state of Knowledge of the Upper Atmosphere 1988: An Assessment Report. NASA Reference Publication 1208, NASA, Washington, DC, 1988.
Heath, D. F., Non-seasonal changes in total column ozone from satellite observations, 1970–86. Nature, 332 (1988) 219–27.
Brasseur, G. & Solomon, S., Aeronomy of the Middle Atmosphere. Reidel Publishing, Boston, MA, 1984.
Shimazaki, T., Minor Constituents in the Middle Atmosphere. Reidel Publishing, Boston, MA, 1985.
Wayne, R. P., Chemistry of Atmospheres. Oxford University Press ( Clarendon ), London, 1985.
Whitten, R. C. & S. S. Prasad, Ozone in the Free Atmosphere. Van Nostrand Reinhold Company, New York, 1985.
Jackman, C. H., Stolarski, R. S. & Kaye, J. A., Two-dimensional monthly average ozone balance from Limb Infrared Monitor of the Stratosphere and Stratospheric and Mesospheric Sounder data. J. Geophys. Res., 91 (1986) 1103–16.
Cicerone, R. J., Walters, S. & Liu, S. C., Nonlinear response of stratospheric ozone column to chlorine injections. J. Geophys. Res., 88 (1983) 3647–61.
Prather, M. J., McElroy, M. B. & Wofsy, S. C., Reductions in ozone at high concentrations of stratospheric halogens. Nature, 312 (1984) 227–31.
McElroy, M. B., Salawitch, R. S., Wofsy, S. C. & Logan, J. A., Reductions of Antarctic ozone due to synergistic interactions of chlorine and bromine. Nature, 321 (1986) 759–62.
DeMore, W. B., Molina, M. J., Sander, S. P., Golden, D. M., Hampson, R. F., Kurylo, M. J., Howard, C. J. & Ravishankara, A. R., Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. JPL Publ. 87–41, Pasadena, CA, 1987.
Douglass, A. R. & Rood, R. B., Derivation of photochemical information near 1 mbar from ozone and temperature data. J. Geophys. Res., 91 (1986) 13153–66.
Eckman, R. S., Haigh, J. D. & Pyle, J. A., An important uncertainty in coupled chlorine-carbon dioxide studies of atmospheric ozone modification. Nature, 329 (1987) 616–19.
McCormick, M. P., Steele, H. M., Hamill, P., Chu, W. P. & Swissler, T. J., Polar stratospheric cloud sightings by SAM I1. J. Atmos. Sci., 39 (1982) 1387–97.
Tung, K. K. & Yang, H., Dynamic variability of column ozone. J. Geophys. Res., 93 (1988) 11 123–8.
Tung, K. K., Ko, M. K. W., Rodriguez, J. M. & Sze, N. D., Are Antarctic ozone variations a manifestation of dynamics or chemistry? Nature, 322 (1986) 811–14.
Mahlman, J. D. & Fels, S. B., Antarctic ozone decreases: A dynamical cause. Geophys. Res. Lett., 13 (1986) 1316–19.
Newman, P. A. & Schoeberl, M. R., October Antarctic temperature and total ozone trends from 1979–1985. Geophys. Res. Lett., 13 (1986) 1206–9.
Parrish, A., de Zafra, R. L., Jaramillo, M., Connor, B., Solomon, P. M. & Barett, J. W., Extremely low N2O concentrations in the springtime stratosphere at McMurdo Station, Antarctica. Nature, 332 (1988) 53–5.
Fahey, D. W., Kelly, K. K., Kawa, S. R., Tuck, A. F., Loewenstein, M., Chan, K. R. & Heidt, L. E., Observations of denitrification and dehydration in the winter polar stratosphere. Nature, 344 (1990) 321–4.
Solomon, S., Garcia, R. R., Rowland, F. S. & Wuebbles, D. J., On the depletion of Antarctic ozone. Nature, 321 (1986) 755–8.
Molina, M. J. & Molina, L. T., Production of Cl2O2 from the self-reaction of the CIO radical. J. Phys. Chem., 91 (1987) 433–6.
Zurer, P., Ozone hole’s hidden chlorine chemistry explained. Chem. Eng. News., 68 (21 May 1990 ) 43–4.
Federal Coordinator for Meteorological Services and Supporting Research, National Plan for Stratospheric Monitoring 1988–1997. Report FCM-P171988, US Department of Commerce, Washington, DC, 1988.
Houghton, J. T., Taylor, F. W. & Rodgers, C. D., Remote Sounding of Atmospheres. Cambridge University Press, London, 1984.
Dobson, G. M. B., Measurements of the amount of ozone in the Earth’s atmosphere and its relation to other geophysical conditions. Proc. Roy. Soc. Lond. Ser. A, 122 (1929) 456–86.
Krueger, A. J., The global distribution of total ozone: TOMS satellite measurements. Planet Space Sci., 37 (1989) 1555–65.
Miller, A. J., A review of satellite observations of atmospheric ozone. Planet. Space Sci., 37 (1989) 1539–54.
Cebula, R. P., Park, H. & Heath, D. F., Characterization of the Nimbus-7 SBUV radiometer for the long-term monitoring of stratospheric ozone. J. Atmos. Ocean Tech., 5 (1988) 215–28.
Bowman, K. P., Global trends in total ozone. Science, 239 (1988) 48–50.
McCormick, M. P., Zawodny, J. M., Veiga, R. E., Larsen, J. C. & Wang, P. H., An overview of SAGE I and II ozone measurements. Planet. Space Sci., 37 (1989) 1567–86.
McPeters, R. D., Heath, D. F. & Bhartia, P. K., Average ozone profiles for 1979 from the NIMBUS 7 SBUV instrument. J. Geophys. Res., 89 (1984) 5199–214.
WMO, Report of the International Ozone Trends Panel 1988, WMO Report No. 18, Geneva, Switzerland, 1989.
Lait, L. R., Schoeberl, M. R. & Newman, P. A., Quasi-biennial modulation of the Antarctic ozone depletion. J. Geophys. Res., 94 (1989) 11559–71.
Mankin, W. G. & Coffey, M. T., Increased stratospheric hydrogen chloride in the El Chichon cloud. Science, 226 (1984) 170–2.
Newell, R. E. & Selkirk, H. B., Recent large fluctuations in total ozone. Q. J. R. Meteorol. Soc., 114 (1988) 595–617.
Michelangeli, D. V., Allen, M. & Yung, Y. L., El Chichon volcanic aerosols: impact of radiative, thermal, and chemical perturbations. J. Geophys. Res., 94 (1989) 18429–43.
Hofmann, D. J. & Solomon, S., Ozone destruction through heterogeneous chemistry following the eruption of El Chichon. J. Geophys. Res., 94 (1989) 5029–41.
Jackman, C. H., Douglass, A. R., Rood, R. B., McPeters, R. D. & Meade, P. E., The effect of solar proton events on the middle atmosphere during the past two solar cycles as computed using a two-dimensional model. J. Geophys. Res., 95 (1990) 7417–28.
Jackman, C. H., Seals, R. K., Jr. & Prather, M. J., Two-Dimensional Inter-comparison of Stratospheric Models. NASA Conference Publication 3042, NASA, Washington, DC, 1989.
Fisher, D. A., Hales, C. H., Filkin, D. L., Ko, M. K. W., Sze, N. D., Connell, P. S., Wuebbles, D. J., Isaksen, I. S. A. & Stordal, F., Model calculations of the relative effects of CFCs and their replacements on stratospheric ozone. Nature, 344 (1990) 508–12.
Nicolet, M., On the production of nitric oxide by cosmic rays in the mesosphere and stratosphere. Planet. Space Sci., 23 (1975) 637–49.
Rood, R. B., Allen, D. J., Baker, W. E., Lamich, D. J. & Kaye, J. A., The use of assimilated stratospheric data in constituent transport experiments. J. Atmos. Sci., 46 (1989) 687–701.
Kaye, J. A. & Rood, R. B., Chemistry and transport in a three-dimensional stratospheric model. J. Geophys. Res., 94 (1989) 1057–83.
Grose, W. L., Nealy, J. E., Turner, R. E. & Blackshear, W. T., Modeling the transport of chemically active constituents in the stratosphere. In Transport Processes in the Middle Atmosphere, ed. G. Visconti & R. Garcia. D. Reidel, Hingham, MA, 1987, pp. 29–250.
Rose, K. & Brasseur, G., A three-dimensional model of chemically active trace species in the middle atmosphere during disturbed winter conditions. J. Geophys. Res., 94 (1989) 16387–401.
Mahlman, J. D., Levy, H. II & Moxim, W. J., Three-dimensional simulations of stratospheric N2O: Predictions for other trace constituents. J. Geophys. Res., 91 (1986) 2687–707.
Golombek, A. & Prinn, R. G., A global three-dimensional model of the circulation and chemistry of CFC13i CF2C12, CH3CC13. J. Geophys. Res., 91 (1986) 3985–4001.
Carriole, D. & Deque, M., Southern hemisphere medium-scale waves and total ozone disturbances in a spectral general circulation model. J. Geophys. Res., 91 (1986) 10 825–46.
Komhyr, W. D., Grass, R. D., Reitelbach, P. J., Kuester, S. E., Franchois, P. R. & Fanning, M. L., Total ozone, ozone vertical distributions, and stratospheric temperatures at South Pole, Antarctica, in 1986 and 1987. J. Geophys. Res., 94 (1989) 11429–36.
Kiehl, J. T., Boville, B. A. & Briegleb, B. P., Response of a general circulation model to a prescribed Antarctic ozone hole. Nature, 332 (1988) 501–4.
Hofmann, D. J., Harder, J. W., Rolf, S. R. & Rosen, J. M., Balloon-borne observations of the development and vertical structure of the Antarctic ozone hole in 1986. Nature, 326 (1987) 59–62.
Deshler, T., Hofmann, D. J., Hereford, J. V. & Sutter, C. B., Ozone and temperature profiles over McMurdo station Antarctic in the spring of 1989. Geophys. Res. Lett., 17 (1990) 151–4.
Solomon, P. M., Connor, B. de Zafra, R. L., Parrish, A., Barrett, J. & Jaramillo, M., High concentrations of chlorine monoxide at low altitudes in the Antarctic spring stratosphere: secular variation. Nature,328 (1987) 411–13.
Anderson, J. G., Brune, W. H. & Profitt, M. H., Ozone destruction by chlorine radicals within the Antarctic vortex: The spatial and temporal evolution of C1O-03 anticorrelation based on in situ ER-2 data. J. Geophys. Res., 94 (1989) 11465–79.
Toon, G. C., Farmer, C. B., Lowes, L. L., Schaper, P. W., Blavier, J.-F. & Norton, R. H., Infrared aircraft measurements of stratospheric composition over Antarctic during September 1987. J. Geophys. Res., 94 (1989) 16 571–96.
Coffey, M. T., Mankin, W. G. & Goldman, A., Airborne measurements of stratospheric constituents over Antarctic in the Austral spring, 1987 2. Halogen and nitrogen trace gases. J. Geophys. Res., 94 (1989) 16795–613.
Mount, G. H., Sanders, R. W., Schmeltekopf, A. L. & Solomon, S., Visible spectroscopy at McMurdo station, Antarctica, 1, Overview and daily variations of NO2 and 03 during austral spring, 1986. J. Geophys. Res., 92, 8320–8.
Farmer, C. B., Toon, G. C., Schaper, P. W., Blavier, J.-F. & Lowes, L. L., Stratospheric trace gases in the spring 1986 Antarctic atmosphere. Nature, 329 (1987) 126–30.
Fahey, D. W., Murphy, D. M., Kelly, K. K., Ko, M. K. W., Proffitt, M. H., Eubank, C. S., Ferry, G. V., Loewenstein, M. & Chan, K. R., Measurements of nitric oxide and total reactive nitrogen in the Antarctic stratosphere: Observations and chemical implications. J. Geophys. Res., 94 (1989) 16665–81.
Wahner, A., Jakoubek, R. O., Mount, G. H., Ravishankara, A. R. & Schmeltekopf, A. L., Remote sensing observations of daytime column NO2 during the Airborne Antarctic Ozone Experiment, August 22 to October 2, 1987. J. Geophys. Res., 94 (1989) 16619–32.
Atkinson, R. J., Matthews, W. A., Newman, P. A. & Plumb, R. A., Evidence of the mid-latitude impact of Antarctic ozone depletion. Nature, 340 (1989) 290–3.
Newman, P. A., Lait, L. R. & Schoeberl, M. R., The morphology and meteorology of southern hemisphere spring total ozone mini-holes. Geophys. Res. Lett., 15 (1988) 923–6.
Prather, M., Garcia, M. M., Suozzo, R. & Rind, D., Global impact of the Antarctic ozone hole: Dynamical dilution with a three-dimensional chemical transport model. J. Geophys. Res., 95 (1990) 3449–71.
Hofmann, D. J., Deshler, T. L., Aimedieu, P., Matthews, W. A., Johnston, P. V., Kondo, Y., Sheldon, W. R., Byrne, G. J. & Benbrook, J. R., Stratospheric clouds and ozone depletion in the Arctic during January 1989. Nature, 340 (1989) 117–21.
Evans, W. F. J., Ozone depletion in the arctic vortex at Alert during February 1989. Geophys. Res. Lett., 17 (1990) 167–70.
Schoeberl, M. R., Proffitt, M. H., Kelly, K. K., Lait, L. R., Newman, P. A., Rosenfield, J. E., Loewenstein, M., Podolske, S. E. & Chan, K. R., Stratospheric constituent trends from ER-2 profile data. Geophys. Res. Lett., 17 (1990) 469–72.
Salawitch, R. J., McElroy, M. B., Yatteau, J. H., Wofsy, S. C., Schoeberl, M. R., Lait, L. R., Newman, P. A., Chan, K. R., Loewenstein, M., Podolske, J. R., Strahan, S. E. & Proffitt, M. H., Loss of ozone in the Arctic vortex for the winter of 1989. Geophys. Res. Lett., 17 (1990) 561–4.
Brune, W., H., Toohey, D. W., Anderson, J. G. & Chan, K. R., In situ observations of CIO in the Arctic stratosphere: ER-2 aircraft results from 59°N to 80°N latitude. Geophys. Res. Lett., 17 (1990) 505–8.
Toohey, D. W., Anderson, J. G., Brune, W. H. & Chan, K. R., In situ measurements of BrO in the Arctic stratosphere. Geophys. Res. Lett., 17 (1990) 513–16.
Kawa, S. R., Fahey, D. W., Anderson, L. C., Loewenstein, M. & Chan, K. R., Measurement of total reactive nitrogen during the airborne Arctic stratospheric expedition. Geophys. Res. Lett., 17 (1990) 485–88.
Browell, E. V., Butler, C. F., Ismail, S., Fenn, M. A., Kooi, S. A., Carter, A. F., Tuck, A. F., Toon, O. B., Proffitt, M. H., Loewenstein, M., Schoeberl, M. R., Isaksen, I. & Braathen, G., Airborne lidar observations in the wintertime Arctic stratosphere: ozone. Geophys. Res. Lett., 17 (1990) 325–8.
Proffitt, M. H., Fahey, D. W., Kelly, K. K. & Tuck, A. F., High-latitude ozone loss outside the Antarctic ozone hole. Nature, 342 (1989) 233–7.
Bojkov, R. D., The 1983 and 1985 anomalies in ozone distribution in perspective. Monthly Weather Review, 115 (1987) 2187–201.
DeLuisi, J. J., Longenecker, D. U., Mateer, C. L. & Wuebbles, D. J., An analysis of northern middle-latitude Umkehr measurements corrected for stratospheric aerosols for 1979–1986. J. Geophys. Res., 94 (1989) 9837–46.
Reinsel, G. C., Tiao, G. C., DeLuisi, J. J., Basu, S. & Charriere, K., Trend analysis of aerosol-corrected Umkehr ozone profile data through 1987. J. Geophys. Res., 94 (1989) 16373–86.
Herman, J. R., Hudson, R. D. & Serafino, G., An analysis of the eight-year trend in ozone depletion from empirical models of Solar Backscattered Ultraviolet instrument degradation. J. Geophys. Res., 95 (1990) 7403–16.
Lubin, D., Frederick, J. E., Booth, C. R., Lucas, T. & Neuschuler, D., Measurements of enhanced springtime ultraviolet radiation at Palmar Station, Antarctica. Geophys. Res. Lett., 16 (1989) 783–5.
EPA, Results of Research Related to Stratospheric Ozone Protection, EPA–600/9–80–043, Office of Research and Development, US Environmental Protection Agency, Washington DC, 1980.
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Kaye, J.A., Jackman, C.H. (1994). Stratospheric Ozone Change. In: Hewitt, C.N., Sturges, W.T. (eds) Global Atmospheric Chemical Change. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-3714-8_4
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