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Nuclear Spectroscopy on Charge Density Wave Systems pp 275–312Cite as

High Resolution NMR on Organic Radical Salts

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Part of the book series: Physics and Chemistry of Materials with Low-Dimensional Structures ((PCMALS,volume 15))

Abstract

NMR (Nuclear Magnetic Resonance) is one of the most versatile spectroscopic techniques for the investigation of solids because it can provide information about local magnetic and electric fields at the atomic level as well as fluctuations of these fields caused e.g. by conduction electrons in organic conductors. In ordinary organic materials proton and carbon NMR spectroscopy in solution has become a routine method to study the diamagnetic interaction of these nuclei with electrons in closed shells (chemical shift). The NMR investigation of organic radical salts, however, is aimed at gathering information about the interaction of delocalized unpaired electron spins (hyperfine interaction) thereby probing basically the electronic structure of the conduction band which can be viewed as a linear combination of the singly occupied molecular orbitals (SOMO). In isolated organic radicals the hyperfine coupling is usually very large, whereas in organic conductors it is rather small due to electron delocalization (organic conductors) or due to a strong exchange coupling among the electron spins (Mott Hubbard insulators). In organic conductors high resolution NMR spectroscopy is therefore mandatory in order to observe the hyperfine interaction between conduction electrons and the nuclei resulting in the Knight shift.

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Abbreviations

AuBDT:

Au-bis-dithiolene

BEDT-TTF:

Bisethylenedithiolotetrafulvalene

CuBDT:

Cu-bis-dithiolene

DMET:

Dimethyl(ethylenedithio)silenadithiafulvalene

(dmit):

l,3-dithia-2-thione-4,5-dithiolato

DMTM:

Dimethylthiomorpholinium

DMe-DCNQI:

2,5-dimethyl-N, N'-dicyanoquinodiimine

DPPH:

α , α -diphenyl-p-picrylhydrazyl

FA:

Fluoranthene

MDT-TTF:

Methylenedithio-tetrathiafulvalene

MEM:

Methylethylmorpholinium

NMP:

N-methylphenazine

Qn:

Quinolinium

TCNQ:

7,7,8,8-Tetracyano-p-quinodimethane

THF:

Tetrahydrofurane

TMTSF:

Tetramethyltetraselenafulvalene

TMTTF:

Tetramethyltetrathiafulvalene

TTF:

Tetrathiafulvalene

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  1. 2. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, W-7000, Stuttgart 80, Federal Republic of Germany

    Michael Helmle & Michael Mehring

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  1. Michael Helmle
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  1. Physics Department, Technische Universität München, Garching, Germany

    Tilman Butz

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Helmle, M., Mehring, M. (1992). High Resolution NMR on Organic Radical Salts. In: Butz, T. (eds) Nuclear Spectroscopy on Charge Density Wave Systems. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 15. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-1299-2_7

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