Abstract
The nonlinear absorption properties of new fluorinated neutral metal-dithiolenes belonging to the general class [M(R,R’timdt)2] (M = Ni, Pd, Pt; R,R’timdt = monoreduced form of disubstituted imidazolidine-2,4,5-trithione) have been studied. The absorption has been found to saturate with the incident light intensity and the temporal evolution of the absorption saturation has been investigated by means of the picosecond time-resolved pump-probe technique. We observed a strong dependence of both the saturation intensity and the temporal dynamics on the metal ion.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Molecular Nonlinear Optics: Materials, Physical and Devices, ed. J. Zyss, Academic Press, Boston, MA, 1993; Materials for Nonlinear Optics — Chemical Perspectives, ed. S. R. Marder, J. E. Sohn ad G. D. Stucky, ACS Symp. Ser., Americal Chemical Society, Washington DC, 1991; Introduction to Nonlinear Optical Effects in Molecules and Polymers, ed. P. N. Prasad and D. J. Williams, Wiley, New York, 1991; Nonlinear Optical Materials, ed. H. Kuhn and J. Rubillard, CRC Press, Boca Raton, FL, 1992.
U.T. Mueller-Westerhoff, B. Vance and D.I. Yoon, Tetrahedron 1991, 47, 909; J. A. McCleverty, Prog. Inorg. Chem., 1968, 10, 49
F. Bigoli, P. Deplano, F.A. Devillanova, V. Lippolis, P.J. Lukes, M.L. Mercuri, M.A. Pellinghelli and E.F. Trogu,. Chem. Soc, Chem. Commun. 1995, 371;
F. Bigoli, P. Deplano, F. A. Devillanova, J. R. Ferraro, V. Lippolis, P. J. Lukes, M. L. Mercuri, M. A. Pellinghelli and E. F. Trogu, Inorg. Chem. 1997, 36, 1218;
M. Area, F. Demartin, F. A. Devillanova, A. Garau, F. Isaia, F. Lelj, V. Lippolis, S. Pedraglio an G. Verani J. Chem. Soc. Dalton Trans 1998, 3731.
M.C. Aragoni, M. Area, F. Demartin, F.A. Devillanova, A. Garau, F. Isaia, F. Lelj, V. Lippolis and G. Verani, J. Am. Chem. Soc, 1999, 121, 7098.
K. H. Drexage and U. T. Mueller-Westerhoff, IEEE J. Quantum Electron., 1972, QE-8, 759
S. Sheibe, B.J. Pedersen and S.O. Lawesson, Bull. Soc. Chim. Belg., 1978, 87, 229.
F.X. Kärtener and U. Keller, Opt. Lett., 1995, 20, 16.
J.L.A. Dubbeldam and D. Lenstra, Appl. Phys. Lett., 1999, 75, 1066.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2001 Kluwer Academic Publishers
About this chapter
Cite this chapter
Aragoni, M.C., Arca, M., Cassano, T., Devillanova, F.A., Ferrara, M., Tommasi, R. (2001). Picosecond Absorption Saturation Dynamics of New [M(R,R’timdt)2] Metal-Dithiolenes. In: Driessen, A. (eds) Nonlinear Optics for the Information Society. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-1267-1_31
Download citation
DOI: https://doi.org/10.1007/978-94-015-1267-1_31
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-5876-8
Online ISBN: 978-94-015-1267-1
eBook Packages: Springer Book Archive