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Relaxation processes and physical aging

  • Chapter
The Physics of Glassy Polymers

Abstract

Glassy materials have been of service to mankind for centuries, from the earliest soda-lime-silicate glasses to the present sophisticated developments in, for example, metallic, fluoride and superionic glasses. Throughout this time, artefacts have been produced with a very wide range of functions: objects of exquisite beauty, such as the Venetian ‘mille fiori’ ornaments and the stained glass windows of many ancient cathedrals, high technology applications such as optical fibres for communications,‘ smart’ glass for controlled transmission, and slow-release glasses for regulating drug dosages, as well as the more commonplace requirements for containers and glazing. What is perhaps surprising about this remarkable success of glass in general is that the glassy state should still remain today so difficult to define with any precision. Even the seemingly simple question of whether a glass should be considered as a liquid or as a solid remains open to discussion.

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References

  1. Tammann, G. (1925/1926) Glastech. Ber., 3, 73–87.

    Google Scholar 

  2. Tammann, G. (1930) Der Glaszustand, L. Voss, Leipzig.

    Google Scholar 

  3. Simon, F. (1930) Ergeh, exact Naturwiss., 9, 222–274.

    Google Scholar 

  4. Simon, F. (1931) Z. anorg. allgem. Chem., 203, 220–227.

    Google Scholar 

  5. Kauzmann, W. (1948) Chem. Rev., 43, 219–256.

    CAS  Google Scholar 

  6. Davies, R.O. and Jones, G.O. (1953) Proc. Roy. Soc. London A, 217, 26–42.

    CAS  Google Scholar 

  7. Davies, R.O. and Jones, G.O. (1953) Adv. Phys., 2, 370–410.

    Google Scholar 

  8. Kovacs, AJ. (1963) Fortschr. Hochpolym. Forsch., 3, 394–507.

    Google Scholar 

  9. Rehage, G. and Borchard, W. (1973) in The Physics of Glassy Polymers (ed. R.N. Haward), Applied Science Publishers, London, Ch. 1, pp. 54–107.

    Google Scholar 

  10. Hodge, I.M. (1994) J. Non-Cryst. Solids, 169, 211–266.

    CAS  Google Scholar 

  11. Ngai, K.L. and Wright, G.B. (eds) (1984) Relaxations in Complex Systems. Proceedings of a Workshop held at Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA in July 1983, National Technical Information Service, US Department of Commerce, Springfield, VA.

    Google Scholar 

  12. Dorfmüller, Th. and Williams, G. (eds) (1987) Molecular Dynamics and Relaxation Phenomena in Glasses. Proceedings of a Workshop held at Zentrum für interdisziplinäre Forschung, Universität Bielefeld, Germany in November 1985. Lecture Notes in Physics, 277, Springer-Verlag, Berlin.

    Google Scholar 

  13. Ngai, K.L. and Wright, G.B. (eds) (1991) Relaxations in Complex Systems. Proceedings of International Discussion Meeting held in Aghia Pelaghia, Heraklion, Crete, Greece in June 1990. J. Non-Cryst. Solids, 131-133, 1–1285.

    Google Scholar 

  14. Ngai, K.L. and Wright, G.B. (eds) (1994) Relaxations in Complex Systems 2. Proceedings of 2nd International Discussion Meeting held in Alicante, Spain in June/July 1993. J. Non-Cryst. Solids, 172-174, 1–1457.

    Google Scholar 

  15. Heydemann, P. and Guicking, H.D. (1963) Koll. Z. Z. Polym., 193, 16–25.

    CAS  Google Scholar 

  16. Goldbach, G. and Rehage, G. (1967) Koll. Z. Z. Polym., 216/217, 56–63.

    CAS  Google Scholar 

  17. Wittmann, J.C. and Kovacs, AJ. (1969) J. Polym. Sci. C, 16, 4443–4452.

    Google Scholar 

  18. Struik, L.C.E. (1978) Physical Aging in Amorphous Polymers and Other Materials, Elsevier, Amsterdam.

    Google Scholar 

  19. Greiner, R. and Schwarzl, F.R. (1984) Rheol. Acta, 23, 378–395.

    CAS  Google Scholar 

  20. Struik, L.C.E. (1987) Polymer, 28, 1869–1875.

    CAS  Google Scholar 

  21. Lee, H.H.D. and McGarry, FJ. (1990) J. Macromol. Sci. B: Phys., 29, 185–202.

    Google Scholar 

  22. Nakayama, M., Hanaya, M., Hatate, A. and Oguni, M. (1994) J. Non-Cryst. Solids, 172-174, 1252–1261.

    CAS  Google Scholar 

  23. McCrum, N.G., Read, B.E. and Williams, G. (1967) Anelastic and Dielectric Effects in Polymeric Solids, John Wiley, New York.

    Google Scholar 

  24. Hutchinson, J.M. and Kovacs, AJ. (1976) J. Polym. Sci., Polym. Phys. Edn, 14, 1575–1590.

    CAS  Google Scholar 

  25. Kohlrausch, F. (1866) Annalen der Physik und Chemie, 128, 1–20, 207-227, 399-419.

    Google Scholar 

  26. Williams, G. and Watts, D.C. (1970) Trans. Faraday Soc., 66, 80–85.

    CAS  Google Scholar 

  27. Kovacs, A.J., Aklonis, J.J., Hutchinson, J.M. and Ramos, A.R. (1979) J. Polym. Sci., Polym. Phys. Edn, 17, 1097–1162.

    CAS  Google Scholar 

  28. Tool, A.Q. (1946) J. Am. Ceram. Soc., 29, 240–253.

    CAS  Google Scholar 

  29. Narayanaswamy, O.S. (1971) J. Am. Ceram. Soc., 54, 491–498.

    CAS  Google Scholar 

  30. Moynihan, CT., Easteal, AJ., DeBolt, M.A. and Tucker, J. (1976) J. Am. Ceram. Soc., 59, 12–16.

    CAS  Google Scholar 

  31. Hutchinson, J.M. and Kovacs, AJ. (1977) in The Structure of Non-Crystalline Materials (ed. P.H. Gaskell), Taylor and Francis, London, pp. 167–172.

    Google Scholar 

  32. Ngai, K.L. (1979) Comments on Solid State Physics, 9, 127–139.

    CAS  Google Scholar 

  33. Ngai, K.L. (1980) Comments on Solid State Physics, 9, 141–155.

    CAS  Google Scholar 

  34. Robertson, R.E., Simha, R. and Curro, JJ. (1984) Macromolecules, 17, 911–919.

    CAS  Google Scholar 

  35. Ngai, K.L., Rendell, R.W., Rajagopal, A.K. and Teitler, S. (1986) Ann. NY Acad. Sci., 484, 150–180.

    CAS  Google Scholar 

  36. Hodge, I.M. and O’Reilly, J.M. (1992) Polymer, 33, 4883.

    CAS  Google Scholar 

  37. Cortés, P. (1994) Study of the structural relaxation of linear polyesters by thermal analysis, PhD Thesis, Universidad Politécnica de Cataluña, Barcelona, Spain (in Spanish).

    Google Scholar 

  38. Gibbs, J.H. and DiMarzio, EA (1958) J. Chem. Phys., 28, 373–383.

    CAS  Google Scholar 

  39. Adam, G. and Gibbs, J.H. (1965) J. Chem. Phys., 43, 139–146.

    CAS  Google Scholar 

  40. Mathot, V.B.F. (1984) Polymer, 25, 579–599.

    CAS  Google Scholar 

  41. Hodge, I.M. (1987) Macromolecules, 20, 2897–2908.

    CAS  Google Scholar 

  42. Kovacs, A.J., Hutchinson, J.M. and Aklonis, JJ. (1977) in The Structure of Non-Crystalline Materials (ed. P.H. Gaskell), Taylor and Francis, London, pp. 153–163.

    Google Scholar 

  43. Williams, M.L, Landel, R.F. and Ferry, J.D. (1955) J. Am. Chem. Soc., 77, 3701–3707.

    CAS  Google Scholar 

  44. Doolittle, A.K. (1951) J. Appl. Phys., 22, 1471–1475.

    CAS  Google Scholar 

  45. Cohen, M.H. and Turnbull, D. (1959) J. Chem. Phys., 31, 1164–1169.

    CAS  Google Scholar 

  46. Turnbull, D. and Cohen, M.H. (1961) J. Chem. Phys., 34, 120–125.

    CAS  Google Scholar 

  47. Kovacs, A.J. and Hutchinson, J.M. (1979) J. Polym. Sci., Polym. Phys. Edn, 17, 2031–2058.

    CAS  Google Scholar 

  48. Hutchinson, J.M. (1987) Lecture Notes in Physics, 277, 172–187.

    Google Scholar 

  49. Hutchinson, J.M. and Ruddy, M. (1989) Macromol. Chem., Macromol. Symp., 27, 319–330.

    CAS  Google Scholar 

  50. O’Reilly, J.M., Tribone, JJ. and Greener, J. (1984) Bull. Am. Phys. Soc., 29-30, 326.

    Google Scholar 

  51. Chow, T.S. and Prest, W.M. Jr (1982) J. Appl. Phys., 53, 6568–6573.

    CAS  Google Scholar 

  52. Oudhuis, A.A.C.M. and ten Brinke, G. (1992) Macromolecules, 25, 698–702.

    CAS  Google Scholar 

  53. O’Reilly, J.M. (1987) Crit. Rev. Solid State Mater. Sci., 13, 259–277.

    Google Scholar 

  54. Gomez Ribelles, J.L., Ribes Greus, A. and Diaz Calleja, R. (1990) Polymer, 31, 223–230.

    CAS  Google Scholar 

  55. Moynihan, C.T., Crichton, S.N. and Opalka, S.M. (1991) J. Non-Cryst. Solids, 131-133, 420–434.

    Google Scholar 

  56. Rekhson, S. and Ducroux, J.P. (1992) in The Physics of Non-Crystalline Solids (eds L. Pye, W.C. La Course and HJ. Stevens), Taylor and Francis, London, pp. 315–320.

    Google Scholar 

  57. Ducroux, J.P., Rekhson, S.M. and Merat, F.L. (1994) J. Non-Cryst. Solids, 172-174, 541–553.

    CAS  Google Scholar 

  58. Hodge, I.M. and Huvard, G.S. (1983) Macromolecules, 16, 371–375.

    CAS  Google Scholar 

  59. Privalko, V.P., Demchenko, S.S. and Lipatov, Yu. S. (1986) Macromolecules, 19, 901–904.

    CAS  Google Scholar 

  60. Prest, W.M, Roberts, FJ. and Hodge, I.M. (1983) Proc. 12th NATAS Conference (ed. J.C. Buck), Williamsburg, VA, p. 119.

    Google Scholar 

  61. Hutchinson, J.M. and Ruddy, M. (1988) J. Polym. Sci., Polym. Phys. Edn, 26, 2341–2366.

    CAS  Google Scholar 

  62. Hutchinson, J.M. and Ruddy, M. (1990) J. Polym. Sci., Polym. Phys. Edn, 28, 2127–2163.

    CAS  Google Scholar 

  63. Tribone, JJ, O’Reilly, J.M. and Greener, J. (1986) Macromolecules, 19, 1732–1739.

    CAS  Google Scholar 

  64. Mijovic, J, Nicolais, L, D’Amore, A. and Kenny, J.M. (1994) Polym. Eng. Sci., 34, 381–389.

    CAS  Google Scholar 

  65. Hutchinson, J.M, Ingram, M.D. and Pappin, AJ, submitted to Macromolecules.

    Google Scholar 

  66. Hodge, I.M. and Berens, A.R. (1982) Macromolecules, 15, 762–770.

    CAS  Google Scholar 

  67. Pappin, AJ, Hutchinson, J.M. and Ingram, M.D. (1992) Macromolecules, 25, 1084–1089.

    CAS  Google Scholar 

  68. Sasabe, H. and Moynihan, C.T. (1978) J. Polymer Sci, Polymer Phys. Edn, 16, 1447–1457.

    CAS  Google Scholar 

  69. Montserrat, S., Cortés, P, Pappin, A.J, Quah, K.H. and Hutchinson, J.M. (1994) J. Non-Cryst. Solids, 172-174, 1017–1022.

    CAS  Google Scholar 

  70. Montserrat, S., unpublished data.

    Google Scholar 

  71. Hutchinson, J.M, McCarthy, D., Montserrat, S. and Cortés, P. (1996) J. Polymer Sci., Polymer Phys. Edn, 34, 229–239.

    CAS  Google Scholar 

  72. Cortés, P., Montserrat, S. and Hutchinson, J.M. (1995) Proc. Workshop on Non-Equilibrium Phenomena in Supercooled Fluids, Glasses and Amorphous Materials, Pisa, Italy, 25–29 September.

    Google Scholar 

  73. Billmeyer, F.W. Jr (1971) Textbook of Polymer Science, 2nd edn, Wiley Interscience, New York.

    Google Scholar 

  74. Hodge, I.M. (1991) J. Non-Cryst. Solids, 131-133, 435–441.

    CAS  Google Scholar 

  75. Angell, C.A. (1984) in Relaxations in Complex Systems (eds K.L. Ngai and G.B. Wright), National Technical Information Serice, US Department of Commerce, Springfield, VA, pp. 3–11.

    Google Scholar 

  76. Böhmer, R., Ngai, K.L., Angell, C.A. and Plazek, DJ. (1993) J. Chem. Phys., 99, 4201–4209.

    Google Scholar 

  77. Plazek, D.J. and Ngai, K.L. (1991) Macromolecules, 24, 1222–1224

    CAS  Google Scholar 

  78. Hodge, I.M. (1983) Macromolecules, 16, 898–902.

    CAS  Google Scholar 

  79. Ingram, M.D., Hutchinson, J.M. and Pappin, AJ. (1991) Phvs. Chem. Glasses, 32, 121–128.

    CAS  Google Scholar 

  80. Wendorff, J.H. and Fischer, E.W. (1973) Kolloid Z. Z. Polym., 251, 876–883.

    CAS  Google Scholar 

  81. Curro, J. J. and Roe, R.J. (1984) Polymer, 25, 1424–1430.

    CAS  Google Scholar 

  82. Müller, J. and Wendorff, J.H. (1988) J. Polym. Sci., Polym. Lett. Edn, 26, 421–427.

    Google Scholar 

  83. Roe, R.J. and Curro, J.J. (1983) Macromolecules, 16, 428–434.

    CAS  Google Scholar 

  84. Song, H.H. and Roe, R.J. (1987) Macromolecules, 20, 2723–2732.

    CAS  Google Scholar 

  85. Haward, R.N. (1973) in The Physics of Glassy Polymers (ed. R.N. Haward), Applied Science Publishers, London, pp. 1–53.

    Google Scholar 

  86. Lamarre, L. and Sung, C.S.P. (1983) Macromolecules, 16, 1729–1736.

    CAS  Google Scholar 

  87. Yu, W.C, Sung, C.S.P. and Robertson, R.E. (1988) Macromolecules, 21, 355–364.

    CAS  Google Scholar 

  88. Sung, C.S.P., Gould, I.R. and Turro, N.J. (1984) Macromolecules, 17, 1447–1451.

    CAS  Google Scholar 

  89. Victor, J.G. and Torkelson, J.M. (1987) Macromolecules, 20, 2241–2250.

    CAS  Google Scholar 

  90. Victor, J.G. and Torkelson, J.M. (1988) Macromolecules, 21, 3490–3497.

    CAS  Google Scholar 

  91. Royal, J.S., Victor, J.G. and Torkelson, J.M. (1992) Macromolecules, 25, 729–734.

    CAS  Google Scholar 

  92. Royal, J.S. and Torkelson, J.M. (1992) Macromolecules, 25, 4792–4796.

    CAS  Google Scholar 

  93. Hutchinson, J.M. (1995) Prog. Polym. Sci., 20, 703–760.

    CAS  Google Scholar 

  94. Loutfy, R.O. (1981) Macromolecules, 14, 270–275.

    CAS  Google Scholar 

  95. Meyer, E.F., Jamieson, A.M., Simha, R. et al. (1990) Polymer, 31, 243–247.

    CAS  Google Scholar 

  96. Royal, J.S. and Torkelson, J.M. (1992) Macromolecules, 25, 1705–1710.

    CAS  Google Scholar 

  97. Royal, J.S. and Torkelson, J.M. (1993) Macromolecules, 26, 5331–5335.

    CAS  Google Scholar 

  98. Hasan, O.A., Boyce, M.C, Li, X.S. and Berko, S. (1993) J. Polym. Sci., Polym. Phys. Edn, 31, 185–197.

    CAS  Google Scholar 

  99. Wang, Y.Y., Nakanishi, N., Jean, Y.C. and Sandreczki, T.C. (1990) J. Polym. Sci., Polym. Phys. Edn, 28, 1431–1441.

    CAS  Google Scholar 

  100. Jean, Y.C. and Deng, Q. (1992) J. Polym. Sci., Polym. Phys. Edn, 30, 1359–1364.

    CAS  Google Scholar 

  101. Deng, Q., Sundar, C.S. and Jean, Y.C. (1992) J. Phys. Chem., 96, 492–495.

    CAS  Google Scholar 

  102. Deng, Q. and Jean, Y.C. (1993) Macromolecules, 26, 30–34.

    CAS  Google Scholar 

  103. Kobayashi, Y., Zheng, W, Meyer, E. F. et al. (1988) Proceedings of 8th ICPA, Gent, Belgium, World Scientific Publishing, pp. 812–814.

    Google Scholar 

  104. Kobayashi, Y., Zheng, W, Meyer, E. F. et al. (1989) Macromolecules, 22, 2302–2306.

    CAS  Google Scholar 

  105. McGervey, J.D, Panigrahi, N, Simha, R. and Jamieson, A.M. (1985) Proc. 7th ICPA, New Delhi, India, World Scientific Publishing, pp. 690–691.

    Google Scholar 

  106. Hill, A.J., Jones, P.L., Lind, J.H. and Pearsall, G.W. (1988) J. Polym. Sci. A: Polym. Chem., 26, 1541–1552.

    CAS  Google Scholar 

  107. Kluin, J.E., Yu, Z., Vleeshouwers, S. et al. (1992) Macromolecules, 25, 5089–5093.

    CAS  Google Scholar 

  108. Liu, L.B., Gidley, D. and Yee, A.F. (1992) J. Polym. Sci., Polym. Phys. Edn, 30, 231–238.

    CAS  Google Scholar 

  109. O’Connor, P.J., Kochner, C.W., Landes, B.G. et al. (1992) Polym. Preprints, 33, 308–309.

    Google Scholar 

  110. Kluin, J.E., Yu, Z, Vleeshouwers, S. et al. (1993) Macromolecules, 26, 1853–1861.

    CAS  Google Scholar 

  111. Li, X.S. and Boyce, M.C. (1993) J. Polym. Sci., Polym. Phys. Edn, 31, 869–873.

    CAS  Google Scholar 

  112. Brandt, W. and Wilkenfield, J. (1975) Phys. Rev., 812, 2579–2587.

    Google Scholar 

  113. Rehage, G. and Goldbach, G. (1965) Kolloid Z. Z. Polym., 206, 166–168.

    CAS  Google Scholar 

  114. Rehage, G. and Goldbach, G. (1966) Ber. Bunsenges. Phys. Chem., 70, 1144–1148.

    CAS  Google Scholar 

  115. Goldbach, G. and Rehage, G. (1967) J. Polymer Sci. C, 16, 2289–2298.

    Google Scholar 

  116. Goldbach, G. and Rehage, G. (1967), Rheol. Acta, 6, 30–53.

    CAS  Google Scholar 

  117. Tribone, J.J., O’Reilly, J.M. and Greener, J. (1989) J. Polym. Sci., Polym. Phys. Edn, 27, 837–857.

    CAS  Google Scholar 

  118. McKinney, J.E. and Goldstein, M. (1974) J. Res. Nat. Bur. Std, 78A, 331–353.

    Google Scholar 

  119. Hirai, N. and Eyring, H. (1959) J. Polym. Sci., 37, 51–70.

    CAS  Google Scholar 

  120. Shishkin, N. (1960) Soviet Phys. Solid State, 2, 322–328.

    Google Scholar 

  121. Hellwege, K.H., Knappe, W. and Lehmann, P. (1962) Kolloid Z. Z. Polym., 183, 110–120.

    CAS  Google Scholar 

  122. Bianchi, U. (1965) J. Phys. Chem., 69, 1497–1504.

    CAS  Google Scholar 

  123. Karasz, F.E., Bair, H.E. and O’Reilly, J.M. (1965) J. Phys. Chem., 69, 2657–2667.

    CAS  Google Scholar 

  124. Abu-Isa, I. and Dole, M. (1965) J. Phys. Chem., 69, 2668–2675.

    CAS  Google Scholar 

  125. Gee, G. (1966) Polymer, 1, 177–191.

    Google Scholar 

  126. Breuer, H. and Rehage, G. (1967) Kolloid Z. Z. Polym., 216-217, 159–179.

    Google Scholar 

  127. Ichihara, S., Komatsu, A., Tsujita, Y. et al. (1971) Polym. J., 2, 530–534.

    CAS  Google Scholar 

  128. Quach, A. and Simha, R. (1971) Macromolecules, 4, 268–270.

    Google Scholar 

  129. Billinghurst, P.R. and Tabor, D. (1971) Polymer, 12, 101–117.

    CAS  Google Scholar 

  130. Quach, A. and Simha, R. (1971) J. Appl. Phys., 42, 4592–4606.

    CAS  Google Scholar 

  131. Quach, A. and Simha, R. (1972) J. Phys. Chem., 76, 416–421.

    CAS  Google Scholar 

  132. Sasabe, H. and Saito, S. (1972) Polym. J, 3, 749–755.

    Google Scholar 

  133. Weitz, A. and Wunderlich, B. (1974) J. Polym. Sci., Polym. Phys. Edn, 12, 2473–2491.

    CAS  Google Scholar 

  134. Oels, H.J. and Rehage, G. (1977) Macromolecules, 10, 1036–1043.

    CAS  Google Scholar 

  135. Stevens, J.R., Oakley, R.W, Chau, K.W. and Hunt, J.L. (1986) J. Chem. Phys., 84, 1006–1014.

    CAS  Google Scholar 

  136. O’Reilly, J.M. (1962) J. Polym. Sci., 57, 429–444.

    Google Scholar 

  137. Zösel, A. (1964) Kolloid Z. Z. Polym., 199, 113–125.

    Google Scholar 

  138. Bianchi, U, Turturro, A. and Basile, G. (1967) J. Phys. Chem., 71, 3555–3558.

    CAS  Google Scholar 

  139. Sasabe, H. and Saito, S. (1972) Polym. J., 3, 631–639.

    CAS  Google Scholar 

  140. Parry, EJ. and Tabor, D. (1973) Polymer, 14, 623–627.

    CAS  Google Scholar 

  141. McKinney, J.E. and Simha, R. (1977) J. Res. Nat. Bur. Std, 81A, 283–297.

    CAS  Google Scholar 

  142. Naoki, M. and Owada, A. (1984) Polymer, 25, 75–83.

    CAS  Google Scholar 

  143. McKinney, J.E. and Belcher, H.V. (1963) J. Res. Nat. Bur. Std, 67A, 43–53.

    Google Scholar 

  144. Parry, EJ. and Tabor, D. (1973) Polymer, 14, 628–631.

    CAS  Google Scholar 

  145. McKinney, J.E. and Simha, R. (1974) Macromolecules, 7, 894–901.

    CAS  Google Scholar 

  146. Quach, A, Wilson, P.S. and Simha, R. (1974) J. Macromol. Sci. B: Phys., 9, 533–550.

    CAS  Google Scholar 

  147. Olabisi, O. and Simha, R. (1975) Macromolecules, 8, 206–210.

    CAS  Google Scholar 

  148. Skorodumov, V.F. and Godovskii, Yu, K. (1993) Vysokomol. Soed. Ser. B, 35, 214–226.

    CAS  Google Scholar 

  149. Ichihara, S, Komatsu, A. and Hata, T. (1971) Polym. J., 2, 650–655.

    CAS  Google Scholar 

  150. Zoller, P. and Bolli, P. (1980) J. Macromol Sci. B: Phys., 18, 549–562.

    Google Scholar 

  151. Fakhreddine, Y.A. and Zoller, P. (1991) J. Polym. Sci., Polym. Phys. Edn, 29, 1141–1146.

    CAS  Google Scholar 

  152. Zoller, P. (1978) J. Polym. Sci., Polym. Phys. Edn, 16, 1261–1275.

    CAS  Google Scholar 

  153. Maeda, Y., Karasz, F.E., MacKnight, WJ. and Vukovic, R. (1986) J. Polym. Sci., Polym. Phys. Edn, 24, 2345–2357.

    CAS  Google Scholar 

  154. Parry, EJ. and Tabor, D. (1973) Polymer, 14, 617–622.

    CAS  Google Scholar 

  155. Yoon, H.N., Pae, K.D. and Sauer, J.A. (1976) J. Polym. Scl., Polym. Phys. Edn, 14, 1611–16127.

    CAS  Google Scholar 

  156. Zoller, P., Kehl, T.A., Starkweather, H.W. Jr and Jones, G.A. (1989) J. Polym. Scl., Polym. Phys. Edn, 27, 993–1007.

    CAS  Google Scholar 

  157. Pae, K.D., Tang, C.L. and Shin, E.S. (1984) J. Appl. Phys., 56, 2426–2432.

    CAS  Google Scholar 

  158. Singh, H. and Nolle, A.W. (1959) J. Appl. Phys., 30, 337–341.

    CAS  Google Scholar 

  159. Nolle, A.W. and Billings, J.J. (1959) J. Chem. Phys., 30, 84–90.

    CAS  Google Scholar 

  160. Anderson, J.E, Davis, D.D. and Slichter, W.P. (1969) Macromolecules, 2, 166–169.

    CAS  Google Scholar 

  161. Payne, A.R. (1958) in Rheology of Elastomers (eds P. Mason and N. Wookey), Pergamon, London, p. 86.

    Google Scholar 

  162. McKinney, J.E, Belcher, H.V. and Marvin, R.S. (1960) Trans. Soc. Rheol., 4, 347–362.

    CAS  Google Scholar 

  163. Sasuga, T. and Takehisa, M. (1977) J. Macromol. Sci. B: Phvs., 13, 215–229.

    Google Scholar 

  164. Dalai, E.N. and Philips, P.J. (1983) Macromolecules, 16, 890–897.

    Google Scholar 

  165. Pae, K.D. and Questad, D.L. (1983) J. Polym. Sci., Polym. Phys. Edn, 21, 1195–1203.

    CAS  Google Scholar 

  166. Pappin, A.J., Ingram, M.D, Hutchinson, J.M. et al. (1995) Phvs. Chem. Glasses, 36, 164–171.

    CAS  Google Scholar 

  167. Hutchinson, J.M, Ingram, M.D. and Robertson, A.H.J. (1992) Phil. Mag., 66, 449–461.

    CAS  Google Scholar 

  168. Price, C, Williams, R.C. and Ayerst, R.C. (1972) in Amorphous Materials (eds R.N. Douglas and B. Ellis), Wiley-Interscience, London, pp. 117–124.

    Google Scholar 

  169. Yourtree, J.B. and Cooper, S.L. (1974) J. Appl. Polym. Sci., 18, 897–912.

    Google Scholar 

  170. Brown, I.G, Wetton, R.E, Richardson, M.J. and Savill, N.G. (1978) Polymer, 19, 659–663.

    CAS  Google Scholar 

  171. Kogowski, GJ. and Filisko, F.E. (1986) Macromolecules, 19, 828–833.

    CAS  Google Scholar 

  172. Price, C. (1975) Polymer, 16, 585–589.

    CAS  Google Scholar 

  173. Bree, H.W, Heijboer, J, Struik, L.C.E. and Tak, A.G.M. (1974) J. Polym. Sci., Polym. Phys. Edn, 12, 1857–1864.

    CAS  Google Scholar 

  174. Allen, G, Ayerst, R.C, Cleveland, J.R. et al. (1968) J. Polym. Sci. C, 23, 127–129.

    Google Scholar 

  175. Ichihara, S, Komatsu, A. and Hata, T. (1971) Polym. J., 2, 644–649.

    CAS  Google Scholar 

  176. Kimmel, R.M. and Uhlmann, D.R. (1970) J. Appl. Phys., 41, 2917–2927.

    CAS  Google Scholar 

  177. Kimmel, R.M. and Uhlmann, D.R. (1971) J. Appl. Phys., 42, 4917–4925.

    CAS  Google Scholar 

  178. Prest, W.M. Jr and Roberts, F.J. Jr (1981) Ann. NY Acad. Sci., 371, 67–86.

    CAS  Google Scholar 

  179. Prest, W.M. Jr, O’Reilly, J.M, Roberts, F.J. Jr and Mosher, R.A. (1981) Polym. Eng. Sci., 21, 1181–1187.

    CAS  Google Scholar 

  180. Mackenzie, J.D. (1964) J. Am. Ceram. Soc., 47, 76–80.

    CAS  Google Scholar 

  181. O’Reilly, J.M. and Mosher, R.A. (1980) J. Appl. Phys., 51, 5137–5139.

    Google Scholar 

  182. O’Reilly, J.M. and Mosher, R.A. (1981) J. Polym. Sci., Polym. Phys. Edn, 19, 1187–1198.

    Google Scholar 

  183. Destruel, P, Ai, B. and Hoang-The-Giam (1984) J. Appl. Phys., 55, 2726–2732.

    CAS  Google Scholar 

  184. Heijboer, J. (1977) Intern. J. Polym. Mat., 6, 11–37.

    CAS  Google Scholar 

  185. Illers, K.H. and Breuer, J. (1961) Koll. Z., 176, 110–119.

    Google Scholar 

  186. Jho, J.Y. and Yee, A.F. (1991) Macromolecules, 24, 1905–1913.

    CAS  Google Scholar 

  187. Yee, A.F. and Smith, S.A. (1981) Macromolecules, 14, 54–64.

    CAS  Google Scholar 

  188. Schaefer, J., Stejskal, E.O., Perchak, D. et al. (1985) Macromolecules, 18, 368–373.

    CAS  Google Scholar 

  189. Yee, A.F. (1977) Polymer Eng. Sci., 17, 213–219.

    CAS  Google Scholar 

  190. Floudas, G., Higgins, J.S., Meier, G., Kremer, F. and Fischer, E.W. (1993) Macromolecules, 26, 1676–1682.

    CAS  Google Scholar 

  191. Schartel, B. and Wendorff, J.H. (1995) Polymer, 36, 899–904.

    CAS  Google Scholar 

  192. Jones, A.A. (1985) Macromolecules, 18, 902–906.

    CAS  Google Scholar 

  193. Hoff, E.A.W, Robinson, D.W. and Willbourn, A.H. (1955) J. Polym. Sci., 18, 161–176.

    CAS  Google Scholar 

  194. Heijboer, J. (1969) Br. Polym. J., 1, 3–14.

    CAS  Google Scholar 

  195. Williams, G. (1966) Trans. Faraday Soc., 62, 2091.

    CAS  Google Scholar 

  196. Dionisio, M.S., Mouro-Ramos, JJ. and Williams, G. (1994) Polymer, 35, 1705–1713.

    Google Scholar 

  197. Diaz-Calleja, R., Devine, I., Gargallo, L. and Radie, D. (1994) Polymer, 35, 151–156.

    CAS  Google Scholar 

  198. Heijboer, J., Baas, J.M.A., van de Graaf, B. and Hoefragel, M.A. (1992) Polymer, 33, 1359–1362.

    CAS  Google Scholar 

  199. Heijboer, J. (1968) J. Polym. Sci. C, 16, 3413–3422.

    Google Scholar 

  200. Illers, K.H. and Jenckel, E. (1958) Rheol. Acta, 1, 322.

    CAS  Google Scholar 

  201. Illers, K.H. and Jenckel, E. (1959) J. Polym. Sci., 41, 528–531.

    CAS  Google Scholar 

  202. Yano, O. and Wada, Y. (1971) J. Polym. Sci., Polym. Phys. Edn, 9, 669–686.

    CAS  Google Scholar 

  203. Yano, O. and Wada, Y. (1974) J. Polym. Sci., Polym. Phys. Edn, 12, 665–683.

    CAS  Google Scholar 

  204. Sinnott, K.M. (1962) SPE Trans., 2, 65.

    Google Scholar 

  205. McCammon, R.D., Saba, R.G. and Work, R.N. (1969) J. Polym. Sci., Polym. Phys. Edn, 7, 1721–1733.

    CAS  Google Scholar 

  206. Irvine, J.D. and Work, R.N. (1972) J. Polym. Sci., Polym. Phys. Edn, 11, 175–191.

    Google Scholar 

  207. Reich, S. and Eisenberg, A. (1972) J. Polym. Sci., Polym. Phys. Edn, 10, 1397–1400.

    CAS  Google Scholar 

  208. Wall, R.A., Sauer, J.A. and Woodward, A.E. (1959) J. Polym. Sci., Polym. Phys. Edn, 35, 281–284.

    CAS  Google Scholar 

  209. Shimizu, K, Yano, O. and Wada, Y. (1973) Polym. J., 5, 107–109.

    CAS  Google Scholar 

  210. Abe, Y., Tonelli, A.E. and Flory, P.J. (1970) Macromolecules, 3, 294–303.

    CAS  Google Scholar 

  211. Tonelli, A.E. (1973) Macromolecules, 6, 682–683.

    CAS  Google Scholar 

  212. Hägele, P.C. and Beck, L. (1977) Macromolecules, 10, 213–215.

    Google Scholar 

  213. Tanabe, Y. (1985) J. Polym. Sci., Polym. Phys. Edn, 23, 601–606.

    CAS  Google Scholar 

  214. Vol’kenshtein, M.V., Kol’tsov, A.I. and Khachaturov, A.S. (1965) Vysokomol. Soedin., 7, 296.

    CAS  Google Scholar 

  215. Alexandrovich, P.S., Karasz, F.E. and MacKnight, W.J. (1980) Polymer, 21, 488–494.

    CAS  Google Scholar 

  216. Kulik, A.S. and Prins, K.O. (1993) Polymer, 34, 4635–4641.

    CAS  Google Scholar 

  217. Mitchell, G.R. and Windle, A.H. (1984) Polymer, 25, 906–920.

    CAS  Google Scholar 

  218. Khare, R., Paulitis, M.E. and Lustig, S.R. (1993) Macromolecules, 26, 7203–7209.

    CAS  Google Scholar 

  219. Golden, J.H., Hammant, B.L. and Hazell, E.A. (1967) J. Appl. Polym. Sci., 11, 1571–1579.

    CAS  Google Scholar 

  220. Allen, G., Morley, D.C.W. and Williams, T. (1973) J. Mater. Sci., 8, 1449–1452.

    CAS  Google Scholar 

  221. Watts, D.C. and Perry, E.P. (1978) Polymer, 19, 248–254.

    CAS  Google Scholar 

  222. Johari, G.P. and Goldstein, M. (1970) J. Chem. Phys., 53, 2372–2388.

    CAS  Google Scholar 

  223. Johari, G.P. (1973) J. Chem. Phys., 58, 1766–1770.

    CAS  Google Scholar 

  224. Johari, G.P. (1982) J. Chem. Phys., 77, 4619–4626.

    CAS  Google Scholar 

  225. Diaz-Calleja, R, Ribes-Greus, A. and Gomez-Ribelles, J.L. (1989) Polymer, 30, 1433–1438.

    CAS  Google Scholar 

  226. Guerdoux, L. and Marchai, E. (1981) Polymer, 22, 1199–1204.

    CAS  Google Scholar 

  227. Dean, G.D., Read, B.E. and Small, G.D. (1988) Plast. Rubb. Comp. Proc. Appl., 9, 173–179.

    CAS  Google Scholar 

  228. Read, B.E., Tomlins, P.E. and Dean, G.D. (1990) Polymer, 31, 1204–1215.

    CAS  Google Scholar 

  229. Beiner, M, Garwe, F, Schröter, K. and Donth, E. (1994) Polymer, 35, 4127–4132.

    CAS  Google Scholar 

  230. Heijboer, J. (1978) in Molecular Basis of Transitions and Relaxations (ed. DJ. Meier), Gordon and Breach, London, p. 75.

    Google Scholar 

  231. Perez, J, Muzeau, E. and Cavaillé, J.Y. (1992) Plast. Rubb. Comp. Proc. Appl., 18, 139–148.

    CAS  Google Scholar 

  232. Muzeau, E, Cavaillé, J.Y., Vassoille, R. et al. (1992) Macromolecules, 25, 5108–5110.

    CAS  Google Scholar 

  233. Muzeau, E., Vigier, B., Vassoille, R. and Perez, J. (1995) Polymer, 36, 611–620.

    CAS  Google Scholar 

  234. Struik, L.C.E. (1987) Polymer, 28, 57–68.

    CAS  Google Scholar 

  235. Muzeau, E. and Johari, G.P. (1990) Chem. Phys., 149, 173–183.

    CAS  Google Scholar 

  236. Muzeau, E, Perez, J. and Johari, G.P. (1991) Macromolecules, 24, 4713–4723.

    CAS  Google Scholar 

  237. Ruddy, M. and Hutchinson, J.M. (1988) Polym. Commun., 29, 132–134.

    CAS  Google Scholar 

  238. Pappin, A.J., Hutchinson, J.M. and Ingram, M.D. (1994) J. Non-Cryst. Solids, 172-174, 584–591.

    CAS  Google Scholar 

  239. McLoughlin, J.R. and Tobolsky, A.V. (1951) J. Polym. Sci., 7, 658.

    CAS  Google Scholar 

  240. Chai, C.K. and McCrum, N.G. (1980) Polymer, 21, 706–712.

    CAS  Google Scholar 

  241. Read, B.E. (1991) J. Non-Cryst. Solids, 131-133, 408–419.

    CAS  Google Scholar 

  242. Hutchinson, J.M. and Kriesten, U. (1993) in Macromolecules 1992 (ed. J. Kahovec), VSP International Publishers, Zeist, The Netherlands, pp. 45–54.

    Google Scholar 

  243. Kovacs, A.J., Stratton, R.A. and Ferry, J.D. (1963) J. Phys. Chem., 67, 152–161.

    CAS  Google Scholar 

  244. Perez, J, Cavaillé, J.Y., Diaz-Calleja, R. et al. (1991) Makromol. Chem., 192, 2141–2161.

    CAS  Google Scholar 

  245. Cavaillé, J.Y, Etienne, S, Perez, J, et al. (1986) Polymer, 27, 686–692.

    Google Scholar 

  246. Haidar, B. and Smith, T.L. (1990) Macromolecules, 23, 3710–3712.

    CAS  Google Scholar 

  247. Struik, L.C.E. (1988) Polymer, 29, 1347–1353.

    CAS  Google Scholar 

  248. Petrie, S.E.B. (1972) J. Polym. Sci., Polym. Phys. Edn, 10, 1255–1272.

    CAS  Google Scholar 

  249. Roe, R.J. and Millman, G.M. (1983) Polym. Eng. Sci., 23, 318–322.

    CAS  Google Scholar 

  250. Hutchinson, J.M, Singh, J, Rychwalski, R.W. et al. (1995) Proceedings of 1st International Conference on Mechanics of Time-Dependent Materials (eds I. Emri and G. Knauss), Ljubljana, Society for Experimental Mechanics, Inc., Connecticut, USA, pp. 67–72.

    Google Scholar 

  251. Delin, M, Rychwalski, R.W, Kubát, J. et al. (1996) Polym. Eng. Sci., 36, 2955–2967.

    CAS  Google Scholar 

  252. McKenna, G.B. (1994) J. Non-Cryst. Solids, 172-174, 756–764.

    CAS  Google Scholar 

  253. McKenna, G.B, Leterrier, Y. and Schultheisz, C.R. (1995) Polym. Eng. Sci., 35, 403–410.

    CAS  Google Scholar 

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  1. Department of Chemistry, UMIST, UK

    R. N. Haward (Visiting Professor) (Visiting Professor)

  2. Manchester Materials Science Centre, University of Manchester/UMIST, UK

    R. J. Young (Royal Society Wolfson Research Professor of Materials Science) (Royal Society Wolfson Research Professor of Materials Science)

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Hutchinson, J.M. (1997). Relaxation processes and physical aging. In: Haward, R.N., Young, R.J. (eds) The Physics of Glassy Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5850-3_3

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