Abstract
N-Fluoresceinyl-N’-(mono-6-desoxy-6-β-cyclodextrinyl)-thiourea 2 was synthesized from mono-6-amino-6-desoxy-β-CD 1 and fluorescein isothiocyanaté. The fluorescent CD derivative 2 was threaded on a water soluble polymer, poly(N, N-dimethyl-ammoniumhexamethylene-N’,N’-dimethylammoniumdecamethylene dibromide) 3. The existence of the molecular necklace was visualized by gel electrophoresis.
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References
Ueno, A., Moriwaki F., Azuma A., Osa T., Exciton coupling, intramolecular self-complexation and host-guest complex formation of 6A, 6X-bis(anthracene-9-carbonyl) derivatives of cyclomaltooctaose, Carbohydr. Res. 192, 173–180(1989).
Ueno, A., Minato, S., Suzuki, I., Fukushima, M., Ohkubo M., Osa T., Hamada F. Murai K., Host-guest sensory system of dansyl-modifies β-cyclodextrin for detecting steroidal compounds by dansyl fluorescence, Chem. Lett. 4, 605–608 (1990).
Ueno, A., Suzuki, I. Osa, T., Host-guest sensory systems for detecting compounds by pyrene excimer fluorescence, Anal. Chem. 62, 2461–2466 (1990).
Ueno, A., Minato, S. Osa, T., Host-guest sensors of 6A, 6B-, 6A, 6C-, 6A, 6D-, and 6A, 6E-bis(2-naphthalinylsulfenyl)-γ-cyclodextrins for detecting organic compounds by fluorescence enhancements, Anal. Chem. 64, 1154–1157(1992).
Harada, A. Kamachi, M., Complex formation between poly(ethylene glycol) and α-cyclodextrin, Macromolecules 23, 2821–2823 (1990).
Harada, A. Kamachi, M., Complex formation between cyclodextrin and poly(propylene glycol), J. Chem. Soc., Chem. Commun. 19, 1322–1323 (1990).
Harada, A., Li, J. Kamachi, M., Complex formation between poly(methyl vinyl ether) and γ-cyclodextrin, Chem. Lett., 237–240 (1993).
Harada, A., Li, J., Kamachi, M., Formation of inclusion complexes of monodisperse oligo(ethylene glycol)s with α-cyclodextrin, Macromolecules 27, 4538–4543 (1994).
Wenz, G., Keller, B., Threading cyclodextrin rings on polymer chains, Angew. Chem. Int. Ed. Engl., 31, 197–199(1992).
Wenz, G., Cyclodextrins as building blocks for supramolecular structures and functional units, Angew. Chem. Int. Ed. Engl., 33, 803–822 (1994).
Keller, B., Wenz, G., Synthesis of polyrotaxanes from cyclodextrins in: Minutes of the 6th International Symposium on Cyclodextrins (Ed. A. R. Hedges), Editions de Santé Paris, 1992, 62.
Wenz, G., Keller, B., Synthesis of polyrotaxanes or how to thread many cyclodextrin rings on a polymer chain, Polym. Prep. (Am. Chem. Soc., Div. Polym. Chem.) 34, 62–64 (1993).
Wenz, G., Keller, B., Speed control for cyclodextrin rings on polymer chains, Macromol. Symp. 87, 11–16(1994).
Parrot-Lopez, H., Djedaini, F., Perly, B., Coleman, A. W., Galons, H., Micoque, M., An approach to vectorisation of pharmacologically active molecules: the covalent binding of Leu-enkephalin to a modified β-cyclodextrin, Tetrahedron Lett. 31, 1999–2002 (1990).
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© 1996 Springer Science+Business Media Dordrecht
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Kräuter, I., Herrmann, W., Wenz, G. (1996). Self Organization of Fluorescent Molecular Necklaces In Aqueous Solution. In: Szejtli, J., Szente, L. (eds) Proceedings of the Eighth International Symposium on Cyclodextrins. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5448-2_44
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DOI: https://doi.org/10.1007/978-94-011-5448-2_44
Publisher Name: Springer, Dordrecht
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