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Determination of Binding Energies Between Cyclodextrins and Aromatic Guest Molecules by Microcalorimetry

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Abstract

The inclusion of substituted benzoic acids in β-CD or selectively methylated β-CDs was investigated by titration microcalorimetry. All thermodynamic functions of the inclusion process ΔG°, ΔH° and ΔS° could be obtained very accurately within one experiment. A very strong influence of the substitution pattern at both the host and the guest on the stability of the inclusion compounds was found.

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References

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© 1996 Springer Science+Business Media Dordrecht

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Höfler, T., Wenz, G. (1996). Determination of Binding Energies Between Cyclodextrins and Aromatic Guest Molecules by Microcalorimetry. In: Szejtli, J., Szente, L. (eds) Proceedings of the Eighth International Symposium on Cyclodextrins. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5448-2_38

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  • DOI: https://doi.org/10.1007/978-94-011-5448-2_38

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6291-6

  • Online ISBN: 978-94-011-5448-2

  • eBook Packages: Springer Book Archive

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