Abstract
It happens quite often during chemical preparation work that products of chemical reactions are obtained in the form of “solvates” (or “adducts”, etc.) in which solvent and/or other foreign molecules co-crystallize with the “main” component. The large amount of structural information which has been accumulated over the last decades provides interesting data on the role played by inclusion of molecular species in the crystalline state.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Jeffrey G.A. (1984), Hydrate inclusion compounds, in J.L. Atwood, J.E.D. Davies and D.D. MacNicol (eds.) Inclusion Compounds, Academic Press, London, vol. 1, ch. 5, pp. 135–190, and references therein.
Davidson D.W. (1973), Clathrate hydrates, in F. Franks (ed.) Water: A Comprehensive Treatise, Plenum Press, New York, vol. 2, ch. 3, pp. 115–203.
K.A. Udachin, J. Lipkowski — “Channel polyhydrate (C2H5)4NF·11H2O” — Mendeleev Commun. (1996), 3, 92–93
Lipkowski J., Luboradzki R., Udachin K. and Dyadin Yu. (1992), A layered clathrate hydrate structure of tetrapropylammonium fluoride, J. Inclusion Phenomena and Molecular Recognition in Chem. 13, 295.
K.A. Udachin, J. Lipkowski — unpublished data.
K.A. Udachin, J. Lipkowski — “Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O” — Mendeleev Commun. (1995), 3, 237–238
Lipkowski J., Kulikov O.V. and Zielenkiewicz W. (1992) Complexation of peptides with crown ethers. Structure and thermal behaviour of ternary compounds: 18-crown-6/glycylglycine/water and 18-crown-6/ L-α-alanyl-L-α-alanine/water, Supramolecular Chem. 1, 73–79.
K.A. Udachin, J. Lipkowski — “Layered polyhydrate 18-crown-6·C3H7NH3F·10H2O” — Mendeleev Commun. (1996), 195–196
Yu. A. Simonov, M.S. Fonari, J. Lipkowski, V.O. Gelmboldt, E.V. Ganin — “Inclusion Compounds: the Products of the Interaction of Silicon, Germanium and Boron Fluorides with Crown Ethers” — J. Incl. Phenom. Mol. Recogn. Chem., 24, (1996), 149–161
J. Lipkowski, K. Udachin, J. Narbutt and P. Staszewski — “On supramolecular architecture water molecules form in hydrophobic hydrates”, XVII lUCr Congress, Seattle, Washington, USA, C-275 (1966)
Lipkowski J., Werner Clathrates, in J.L. Atwood, J.E.D. Davies, D.D. MacNicol and F. Voegtle (eds.) Comprehensive Supramolecular Chemistry, Pergamon, vol. 6, ch. 20, pp. 691–714.
K. Kislykh, Yu. A. Dyadin, D.V. Soldatov, J. Lipkowski — unpublished data
D. V. Soldatov, Yu. A. Dyadin, J. Lipkowski, K. Suwiñska — “Structure and supramolecular nature of the compounds [MPy4(NCO)2]·2Py (M = Mn, Fe, Co, Ni, Cu, Zn, Cd)” — Mendeleev Commun. (1997), 3, 00–102
Starzewski P. (1982), Calorimetric study of clathration phenomena (Pol.), PhD thesis, Warszawa.
Lipkowski J., Zielenkiewicz A., Hatt J. and Zielenkiewicz W. (1989), Calorimetric and thermogravimetric study of competitive clathration in the ß-Ni(NCS)2(4-MePy)4 host, J. Inclusion Phenomena and Molecular Recognition in Chem. 7, 519–527.
A. Yu. Manakov, J. Lipkowski, K. Suwiñska, M. Kitamura — “New Crystal Structures of ß-[Ni(NCS)2(4-methylpyridine)4] Clathrates with Furan, Tetrahydrofuran, Methylene Chloride, Benzene + Ethanol and Methylcellosolve as Guest Molecules” — J. Incl. Phenom. Mol. Recogn. Chem. 26 (1–3), (1996), 1–20
J. Lipkowski — “Clathration and Solvation of Molecules” — in G, Tsoucaris, J.L. Atwood and J. Lipkowski (Eds.) Crystallography of Supramolecular Compounds, NATO ASI Series, Series C: Mathematical and Physical Sciences — vol. 480, Kluwer Academic Publishers, Dordrecht/Boston/London, 1996, pp. 265–283
Yu.A. Dyadin, D.V. Soldatov, V.A. Logvinenko, J. Lipkowski — “Contact Stabilization of Host Molecules During Clathrate Formation: The Pyridine-Zinc Nitrate and the Pyridine-Cadmium Nitrate Systems” — J. Coord. Chem., 37 (1–4), (1996), 63–75
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Lipkowski, J., Udachin, K., Simonov, Y., Soldatov, D. (1999). The Structure of Solvates in the Solid State — Systems Model for Heteromolecular Association?. In: Tsoucaris, G. (eds) Current Challenges on Large Supramolecular Assemblies. NATO Science Series, vol 519. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5284-6_12
Download citation
DOI: https://doi.org/10.1007/978-94-011-5284-6_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6224-4
Online ISBN: 978-94-011-5284-6
eBook Packages: Springer Book Archive