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New Cyanine Dyes Absorbing in the NIR Region

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Book cover Near-Infrared Dyes for High Technology Applications

Part of the book series: NATO ASI Series ((ASHT,volume 52))

Abstract

Basic approaches to deeply coloured polymethine dyes are considered. Synthetic methods, stability, and chemical properties are treated for polymethines containing bridge groups in the chromophore. Colour regularities for these dyes are generalized, taking into account bridge group structures and positions in the chromophore. Special attention is paid to the ability of dyes with bridged chromophores to form associates absorbing light in the near IR region. Comparison analysis is presented for dyes of various constitution with respect to changes in their absorption band shapes, Stokes shift, and fluorescent properties. Effects caused on these characteristics by vibronic and intermolecular interactions are elucidated. The application of near IR dyes (1000-1800 nm) in quantum electronics is covered.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences, Murmanskaya 5, Kiev-94, 253660, Ukraine

    A. I. Tolmachev, Yu L. Slominskii & A. A. Ishchenko

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  1. A. I. Tolmachev
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  2. Yu L. Slominskii
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  3. A. A. Ishchenko
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    Siegfried Daehne  & Ute Resch-Genger  & 

  2. Institute of Analytical Chemistry, Chemo-and Biosensors, University of Regensburg, Regensburg, Germany

    Otto S. Wolfbeis

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Tolmachev, A.I., Slominskii, Y.L., Ishchenko, A.A. (1998). New Cyanine Dyes Absorbing in the NIR Region. In: Daehne, S., Resch-Genger, U., Wolfbeis, O.S. (eds) Near-Infrared Dyes for High Technology Applications. NATO ASI Series, vol 52. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5102-3_19

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  • DOI: https://doi.org/10.1007/978-94-011-5102-3_19

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