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Raman and Infrared Spectroscopy

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Carbyne and Carbynoid Structures

Part of the book series: Physics and Chemistry of Materials with Low-Dimensional Structures ((PCMALS,volume 21))

Abstract

Raman and IR spectra of carbyne-like materials show a characteristic band at 2000–2300 cm−1 which was assigned to the CC stretching mode of sp-bonded carbon chain. From the Raman and IR spectra, the purity of carbynoid materials can be deduced. The length of an unperturbed sp-carbon chain (conjugation length) can be evaluated from the band position and dispersion effects. The most detailed spectroscopic data exist for carbyne-like materials prepared by chemical or electrochemical methods from perhalo-n-alkanes, either polymers or low-molecular weight precursors. Raman and IR spectra of carbynoid products are sensitive towards elevated temperatures and/or reactive environment (air oxygen, humidity). Crosslinking of carbynoid chains can be monitored by time-dependencies of both the intensity and position of the CC stretching mode. By resonance Raman scattering the first allowed electronic transition can be identified. Anisotropy, introduced by preferential orientation of carbynoid chains, can be followed by polarized Raman measurements.

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Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry, Dolejškova 3, CZ-182 23, Prague 8, Czech Republic

    L. Kavan

  2. PROFACTOR Produktionsforschung GmbH, Wehrgrabengasse 1, A-54400, Steyr, Austria

    J. Kastner

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  1. L. Kavan
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  2. J. Kastner
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Editors and Affiliations

  1. Department of Mineralogy, Freiberg University of Mining and Technology, Freiberg, Germany

    Robert B. Heimann

  2. A.N. Nesmeyanov Institute of Organo-Element Compounds, The Russian Academy of Sciences, Moscow, Russia

    Sergey E. Evsyukov

  3. J. Heyrovsky Institute of Physical Chemistry, Prague, Czech Republic

    Ladislav Kavan

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Kavan, L., Kastner, J. (1999). Raman and Infrared Spectroscopy. In: Heimann, R.B., Evsyukov, S.E., Kavan, L. (eds) Carbyne and Carbynoid Structures. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 21. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4742-2_23

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  • DOI: https://doi.org/10.1007/978-94-011-4742-2_23

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