Phase Diagrams — Heat of Mixing and Interfacial Energy

  • J. Ansorg
  • I. Müller
Conference paper
Part of the Solid Mechanics and Its Applications book series (SMIA, volume 66)


The form of phase diagrams is affected by intermolecular energies and by interfacial energies. The former result in phenomena like azeotropy and miscibility gaps, while the latter deform the domains of the phase diagram, — in particular the miscibility gap.


Phase Diagram Interfacial Energy Penalty Term Penalty Factor Phase Mixture 
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  1. [1]
    Cahn, J.W. and Lärche, F., ‘A simple model for coherent equilibrium’, Acta Metall 32 (1984) pp. 1915–1923CrossRefGoogle Scholar
  2. [2]
    Müller, I., ‘Boiling and condensation with interfacial energy’, Meccanica 31 (1996) pp. 489–494CrossRefzbMATHGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1999

Authors and Affiliations

  • J. Ansorg
    • 1
  • I. Müller
    • 1
  1. 1.TU Berlin, ThermodynamikBerlinGermany

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