Abstract
High pressure Raman and neutron scattering study of carbon blacks and HOPG graphite is reported. Carbon black particles are composed of graphitic nanocrystallites and amorphous carbon. Relative concentration of amorphous carbon decreases slightly with increased pressure. This non-reversible process differs from temperature induced transformations of amorphous carbon into ordered carbon. Post-production treatment at high temperatures results in the growth of graphitic crystallites whereas no such effect was observed when the pressure was applied to carbon black.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
1. Xu W., Zerda T. W., Raab H. and Goritz D. (1997) Three dimensional morphological characterization of carbon black aggregates using atomic force microscopy, Carbon 35, 471–474.
2. Xu W., Zerda T. W., Yang H., and Gerspacher M (1996) Surface fractal dimension of graphitized carbon black particles, Carbon 34, 165–171.
3. Gruber T., Zerda T. W., and Gerspacher M. (1994) Raman studies of heat treated carbon blacks, Carbon 32, 1377–1382.
4. Zerda T. W., Xu W., and Yang H. (1998) The effect of heating and cooling rates on the structure of carbon black particles, Rubber Chem. Technol., 71, 26–37.
5. Tuingstra F and Koenig J. L. (1970) Raman spectrum of graphite, J. Chem. Phys., 53, 1126–1130.
6. Richter H., Wang, Z. P., and Ley L. (1981) The one phonon Raman spectrum in microcrystalline silicon, Solid State Communications. 39, 625–629.
7. Besson J.M., S. Klotz, G. Hamel, I. Makarenko, J.S. Loveday, R.M. Wilson, and W. G. Marshall (1995) High pressure neutron diffraction: present and future possibilities using the Paris-Edinburgh cell, High Pressure Research, 14, 1–6.
8. Von Dreele (1995) High pressure neutron powder diffraction at LANSCE, High Pressure Research, 14, 13–20, (1995).
9. Zhao, Y., R. B. Von Dreele, D. J. Weidner (1998) Correction of P-V-T data and diffraction optics using thermoelastic equations of state of multiple phases, High Pressure Research, (in press).
10. Larson, A.C., and R.B. Von Dreele, (1994) GSAS manual, Report LAUR 86-748, Los Alamos National Laboratory.
11. Zhao, Y. X., and I. L. Spain (1989) X-ray diffraction data for graphite to 20 GPa, Phys. Rev., B40, 993–997.
12. Zhao, Y., R. B. Von Dreele, D. J. Weidner, and D. Schiferl (1997) P-V-T data of hexagonal boron-nitride and determination of pressure and temperature using thermoelastic equation of state of multiple phases,” High Pressure Research, 16, 1–18.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Zerda, T.W., Zerda, A., Zhao, Y., Von Dreele, R.B. (1999). Structure of Carbon Black Particles. In: Winter, R., Jonas, J. (eds) High Pressure Molecular Science. NATO Science Series, vol 358. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4669-2_13
Download citation
DOI: https://doi.org/10.1007/978-94-011-4669-2_13
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-5807-7
Online ISBN: 978-94-011-4669-2
eBook Packages: Springer Book Archive