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Molecular-Ionic Halogenoantimonates and Bismuthates - a Rich Family of Crystals Showing Attractive Properties

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Crystal Engineering: From Molecules and Crystals to Materials

Part of the book series: NATO Science Series ((ASIC,volume 538))

Abstract

The halogenoantimonate and bismuthate crystals containing organic cations seem to be interesting from a point of view of the crystals engineering for several reasons. The most important feature consists in that the halocoordinated Sb and Bi octahedra (Sb and Bi on the 3rd oxidation stage) can be easily joined via corners, edges or faces. These octaedra form varieties of polyanionic sublattices, which the organic cations of varying size and symmetry can be incorporated to. The cations are able to form weak hydrogen bonds. Simultaneously in many cases these cations show a freedom of reorientations. Their dynamics is a main factor ruling transitions to interesting phases such like pyroelectric, ferroelectric, ferrielectric or ferroelastic. Some of crystals from this family seem to be interesting from a point of view of the non-linear optical properties.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw, 50-383, Poland

    G. Bator, R. Jakubas & L. Sobczyk

Authors
  1. G. Bator
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  2. R. Jakubas
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  3. L. Sobczyk
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Editor information

Editors and Affiliations

  1. Dipartimento di Chimica, Università di Bologna, Bologna, Italy

    Dario Braga

  2. Dipartimento di Chimica, Università di Sassari, Sassari, Italy

    Fabrizia Grepioni

  3. School of Chemistry, University of Bristol, Bristol, UK

    A. Guy Orpen

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© 1999 Springer Science+Business Media Dordrecht

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Bator, G., Jakubas, R., Sobczyk, L. (1999). Molecular-Ionic Halogenoantimonates and Bismuthates - a Rich Family of Crystals Showing Attractive Properties. In: Braga, D., Grepioni, F., Orpen, A.G. (eds) Crystal Engineering: From Molecules and Crystals to Materials. NATO Science Series, vol 538. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4505-3_26

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  • DOI: https://doi.org/10.1007/978-94-011-4505-3_26

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-5899-2

  • Online ISBN: 978-94-011-4505-3

  • eBook Packages: Springer Book Archive

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