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γ-MnO2 Compounds as Insertion Hosts for Li+ and H+

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Materials for Lithium-Ion Batteries

Part of the book series: NATO Science Series ((ASHT,volume 85))

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Abstract

γ-MnO2 compounds (EMD: Electrolytic Manganese Dioxides, CMD: Chemical Manganese Dioxides, and HTMD: heat Treated Manganese Dioxides) are positive electrode materials of both rechargeable alkaline and lithium batteries. Their structure consists of a random inlergrovvth of blocks of the pyrolusite structure (De Wolff defects with a Pr rate) within the ramsdellile structure, and contains microtwinning defects(with Mt rate). Consequently, their structural characterization by diffraction techniques is complex and requires simulation of the pou der patterns [ 1 ].

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References

  1. Chabre, Y. and Pannetier, J. (1995) Prog. Solid State Chem. 23, 1.

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  2. Sarciaux, S., Le Gal I.a Salle, A., Pillard, Y., and Guyomard, D. (1999) J. Power Sources, in press.

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© 2000 Springer Science+Business Media Dordrecht

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Jouanneau, S., Sarciaux, S., Le Gal La Salle, A., Piffard, Y., Guyomard, D. (2000). γ-MnO2 Compounds as Insertion Hosts for Li+ and H+ . In: Julien, C., Stoynov, Z. (eds) Materials for Lithium-Ion Batteries. NATO Science Series, vol 85. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4333-2_47

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  • DOI: https://doi.org/10.1007/978-94-011-4333-2_47

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6651-5

  • Online ISBN: 978-94-011-4333-2

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