Abstract
The recent interest in developing advanced rechargeable lithium batteries such as lithium-ion type cells, has stimulated investigation on high-performance positive electrodes, the so-called four-volt cathode materials [1]. The as-preparedlithiated positive electrode materials deintercalate lithium at about 4 volts vs. Li/Li+, a very high voltage. Only three lithiated systems with high operating voltage are presently known: LiCoO2 [2] and LiNiO2 [3], with the pseudo-layered α-NaFeO2 structure, and the 3-D spinel LiMn2O4 [4]. Various substitutions on the transition metal site have been tried in these structures in order to improve the electrochemical properties; only the solid solution LiNi1-yCoyO2 leads to successful results [5].
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Ohzuku, T. (1994) in G. Pistoia (ed.), Lithium Batteries, New Materials, Developments and Perspectives, Elsevier, Amsterdam, p. 239.
Mizushima, K., Jones, P.C., and Goodenough, J.B. (1980) Mater. Res. Bull. 15, 763.
Broussely, M., Perton, F., Biensan, P., Bodet, J.M., Labat, J., Lecerf, A., Delmas, C., Rougier, A., and Peres, J.P. (1995) J. Power Sources 54, 109.
Thackeray, M.M., Johnson, P., de Piciotto, L., Bruce, P.G., and Goodenough, J.B. (l984) Mater. Res. Bull., 19, 179.
Gummow, J. and Thackeray, M.M. (1992) Solid Stale Ionics 53-56, 681.
Huang, W. and Frech, R. (1996) Solid State Ionics 86-88, 395.
Inaba, M., Todzuka, Y., Yoshida, H., Grincourt, Y., Tasaka, A., Tomida, Y., and Ogumi, Z. (1995) Chem. Lett. 889.
Julien, C., Massot, M., Perez-Vicente, C., Haro-Poniatowski, E., Nazri, G.A., and Rougier, A. (1998) Mater. Res. Soc. Symp. Proc. 496, 415.
Rougier A., Nazri, G.A., and Julien, C. (1997) Ionics 3, 170.
Nazri, M., Curtis, M.D., Yebka, B., Nazri, G.A., and Julien, C. (1998) Ext. Abstr. of the 193rd Meeting of The Electrochem. Soc., San Diego, CA, vol. 98-1, Abstr. No. 48.
Castro-Garcia, S. and Julien, C. (1998) Ionics 4, 111.
Nakamoto, K. (1977) Infrared and Raman of Inorganic and Coordination Compounds, John Wiley & Sons, New York, and references herewith.
Hunter, J.C. (1981) J. Solid State Chem. 39, 142.
Preudhomme, J. and Tarte, P. (1971) Spectrochim. Acta 27 A, 845.
Moore, R.K. and White, W.B. (1970) J. Am. Ceramic Soc. 53, 679.
Orman, H.J. and Wiseman, P.J. (1984) Acta Cryst. C40, 12.
Julien, C., Rougier, A., Haro-Poniatowski, E., and Nazri, G.A. (1998) Mol. Cryst. Liq. Cryst. 311, 81.
Exarhos, G.J. and Risen, W.N. (1972) Solid State Commun. 11, 755.
Ammundsen, B., Burns, GR., Islam, M.S., Kanoh, H., and Roziere, J. (1999) J. Phys. Chem. 103, 5175.
Hope, P. and Schepers, B. (1958) Z. Anorg. Allgem. Chem. 295, 233.
Tarte, P. (1967) J. Inorg. Nucl. Chem. 29, 915.
Delmas, C. and Saadoune, I. (1992) Solid State Ionics 53, 370.
Brodsky, M.H, Lucovsky, G., Chen, M.F., and Plaskett, T.S. (1970) Phys. Rev B 2, 3303.
Julien, C. and Michael, S.S. (1998) Ionics 4, 121.
G.A. Nazri, A. Rougier, and K.F. Kia, Mater. Res. Soc. Symp. Proc. 453, 635 (1997).
Shannon, R.D. and Prewitt, C.T. (1969) Acta Cryst. B 25, 925.
Chang I.F. and Mitra S.S. (1968) Phys. Rev. 172, 924.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Julien, C. (2000). Local Environment in 4-Volt Cathode Materials for Li-Ion Batteries. In: Julien, C., Stoynov, Z. (eds) Materials for Lithium-Ion Batteries. NATO Science Series, vol 85. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4333-2_13
Download citation
DOI: https://doi.org/10.1007/978-94-011-4333-2_13
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-6651-5
Online ISBN: 978-94-011-4333-2
eBook Packages: Springer Book Archive