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VOC: Volatile Organic Compounds

Formation and Emission

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Pollutants from Combustion

Part of the book series: NATO Science Series ((ASIC,volume 547))

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Abstract

Volatile Organic Compounds (VOC) are implicated in different problems of air pollution. Some of these compounds are toxic and dangerous for health. But, they all contribute to ozone formation in the lower troposphere. VOC emissions can come from various sources: road traffic, aircraft transports, combustion plants, solvent use, industry and vegetation. Each source can emit more than about ten different compounds. The purpose of this paper is not to describe in detail each VOC source but to focus on some of them. The road traffic emissions is very important for ozone formation and can generate toxic air pollutants (benzene, formaldehyde, etc.) in the cities. The VOC formation in the different engines (diesel or spark ignition) will be presented. The aircraft emissions can be very intense locally, on the airport area and they can inject pollutants directly in the free troposphere. We will also consider biogenic emissions (or vegetation emissions) in more details for their important contribution to ozone formation.

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References

  1. R. Bouscaren, (1985) “Que sont les composés organiques volatils ?” CITEPA, Report 4 p.

    Google Scholar 

  2. CORINAIR: http:/www.aeat.co.uk/netcen/corinair/94/

  3. GENEMIS: http://www.gsf.de/eurotrac/sp-gen-f.htm

  4. J.C. Guibet and B. Martin (1987), Carburants et Moteurs, ed. Technip, Paris

    Google Scholar 

  5. R. Atkinson (1990) “Kinetics and mechanisms of the gaz-phase reactions of the hydroxyl radical with organic compounds”, J. Phys. Chem. Ref. Data, Monograph n°1

    Google Scholar 

  6. R. Atkinson (1994) “Gas-phase tropospheric chemistry of organic compounds”, J. Phys. Chem. Ref. Data, Monograph n°2

    Google Scholar 

  7. Derwent R.G., Jenkin M.E. and Saunders S.M., (1996),“Photochemical ozone creation potentials for a large number of reactive hydrocarbons under European conditions”, Atmospheric Environment, 30, 181–199

    Article  CAS  Google Scholar 

  8. Carter W.P.L., (1995) Computer modeling of environmental chamber measurements of maximum incremental reactivities of volatile organic compounds”, Atmospheric Environment., 29, 2513–2527.

    Article  CAS  Google Scholar 

  9. Carter W.P.L., Pierce, J.A., Luo, D., Malkina, I.L. (1995), “Environmental chamber study of maximum incremental reactivities of volatile organic compounds”, Atmospheric Environment, 29, 2499–2511.

    Article  CAS  Google Scholar 

  10. Carter W. (1994), “Development of ozone reactivity scales for volatile organic compounds”, J. of Air & Waste Management Association, 84, p 881–899

    Google Scholar 

  11. SAE Recommended Practice (1978) «Constant volume sampler system for exhaust emission measurement » SAE J1094a.

    Google Scholar 

  12. Degobert, P. ( 1995) « Automobiles and pollution », ed. Technip Paris

    Google Scholar 

  13. Guibet J.C. and Faure E. ( 1997), Carburants et Moteurs, ed. Technip, Paris, English version in press.

    Google Scholar 

  14. Daniel, W.A. ( 1970) « Why engine variables affect exhaust hydrocarbon emission », SAE paper n° 700108.

    Google Scholar 

  15. Namazian, M. and Heywood, J.B. (1982) « Flow in the piston cylinder ring crevices of a spark ignition engine, effect on hydrocarbon emissions, efficiency and power », SAE paper n° 820088

    Google Scholar 

  16. Gatellier B., Trapy J., Herrier D., Quelin J.M., and Galliot F. (1992)“Hydrocabon emission of SI engines as influenced by fuel absorption-desorption in oil films” SAE 920095

    Google Scholar 

  17. Heywood J.B. (1988), Internal combustion engines fundamentals, McGraw Hill, New York.

    Google Scholar 

  18. Samaras Z., Kyrialis N., Joumard R., André M., Serié E., Hassel D., Weber J.F., Hickman A.J., Rijkeboer R., Sturm P., Sorenson S., Lewis CA., Beckman E., Trozzi C., Vaccaro R., Kaivoda M.: (1998) “Methodologies for estimating air pollutant emissions from transport. Emisson factors and trafic characteristics data set”, LAT report n° 9802

    Google Scholar 

  19. Ahlvik P., Eggleston S., Goriβen N., Hassel D., Hickman AJ., Joumard R., Ntziachritos L., Rijkeboer R., Samaras Z. and Zierock K.H.: (1997)“COPERT II: Computer programme to calculate emissons from road transport: Methodology & emissions factors”, EEA technical report n°6

    Google Scholar 

  20. http:/vergina.eng.auth.gr/mech/lat/copert/copdown.htm

    Google Scholar 

  21. CONCAWE ( 1990),“The effects of temperature and fuel volatility on vehicle evaporative emissions”, report n°90/51

    Google Scholar 

  22. CONCAWE ( 1992), “ VOC running losses from canister-equipped vehicles”, report n° 92/53

    Google Scholar 

  23. U.S. E.P.A. (1991), supplement A to compilation of air pollutant emission factors (AP-42) Volume II Mobile sources. Test and evaluation branch, office of air and radiation

    Google Scholar 

  24. Schumann U. (1994) “On the effect of emissions from aircraft engines on the state of the atmosphere”, Ann. Geophys. 12, 365–384

    Article  CAS  Google Scholar 

  25. Schumann U. (1997) « The impact of nitrogen oxides emissions from aircraft upon the atmosphere at flight altitudes — results from the AERONOX project », Atmospheric Environment, 31, 1723–1733.

    Article  CAS  Google Scholar 

  26. Herz O. (1991) « Transport aérien et pollution de l’air », Air Environnement, October, 14, p.3.

    Google Scholar 

  27. Fontelle J.P., Chang J.P., Audoux N., Levy C, Riviere E.: (1997) “Inventaires d’émissions dans l’atmosphere dans le cadre des plans régionaux pour la qualité de l’air, Region Ile de France”: CITEPA Report

    Google Scholar 

  28. Archer L.J. (1993) “Aircraft emissions and the environment: COx,SOx,HOx and NOx”, O.I.E.S. Papers

    Google Scholar 

  29. http://www. dera. gov.uk/aviation-emissions-databank.htm

    Google Scholar 

  30. Seufert G. ( 1997), BEM A A European commission project on biogenic emission in the Mediterranean area, Atmospheric Environment, 31, S1

    Article  Google Scholar 

  31. Winer et al. ( 1992),Emission rates of organics from vegetation in California’ s Central Valley, Atmospheric Environment Vol. 26A, No 14

    Google Scholar 

  32. Guenther, A., Monson R. and Fall R. (1991), “Isoprene and monoterpene emission rate variability: observations with eucalyptus and emission rate algorithm development”, J. Geophys.Res., 96, 10799–10808

    Article  Google Scholar 

  33. Guenther A., Zimmerman P., Harley R., Monson R. and Fall R. (1993), “Isoprene and monoterpene emission rate variability: model evaluation and sensitivity analysis, J. Geophys. Res., 98D, 12609–12617.

    Article  Google Scholar 

  34. Guenther A., Hewitt N.C., Erickson D., Fall R., Geron C, Graedel T., Harley P., Klinger L. Lerdau M., McKay W.A., Pierce T., Scholes B., Steinbrecher R., Tallamraju R., Taylor J. and Zimmeerman P. (1995) “A global model of natural volatile organic compound emissions”, J. Geophys. Res., 100, 8873–8892

    Article  CAS  Google Scholar 

  35. Kesselmeier J., Kode K., Hofmann U, Müller H., Schäfer L., Wolf A., Ciccioli P., Brancaleoni E., Cecinato A., Frattoni M., Foster P., Ferrari C, Jacob V., Fugit J.L., Dutaur L., Simons V. and Torres L., (1997), “Emission of short chained organic acids, aldehydes and monoterpenes from Quercus Ilex and Pinus Pinea L; in relatio to physiological activities, carbon budget and emission algorithms”, atmospheric Environment, 31, 119–133

    Article  CAS  Google Scholar 

  36. König G., Brunda M., Puxbaum H., Hewitt C.N., Duckham S.C., and Rudolph J., (1995): “Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid european agricultural and natural plant species, Atmospheric Environmrent, 29, 861–874

    Article  Google Scholar 

  37. Simpson D., Guenther A., Hewitt C.N., and Steinbrecher R., (1995), »Biogenic emissions in Europe: 1. Estimates and uncertainties »., J. Geophys. Res., 100D, 22875–22890

    Article  Google Scholar 

  38. Simpson D., (1995) «Biogenic emissions in Europe: 2.Implications for ozone control strategies», J. Geophys. Res., 100D, 22891–22906.

    Article  Google Scholar 

  39. AP-42 (1995) “Compilation of air pollutant emission factors” fifth edition

    Google Scholar 

  40. http://www.federalregister.com/ap42/

  41. Jaecker-Voirol A., Lipphardt M., Martin B., Quandalle Ph., Salles J., Musson-Genon L., Dupont E., Riboud P.M., Aumont B., Bergametti G., Bey I., Toupance G., (1996) “A 3D Regional Scale Photochemical Air Quality Simulator: Application to a 3 Day Summertime Episode Over Paris Area”, Air Pollution.

    Google Scholar 

  42. Jaecker-Voirol A, Jouve B., Quandalle Ph., Sallès J. (1988) “VOCs speciation for vehicle emissions: which impact on air quality modelling” International journal of Vehicle Design 20, 115–124.

    Article  Google Scholar 

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© 2000 Springer Science+Business Media Dordrecht

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Jaecker-Voirol, A. (2000). VOC: Volatile Organic Compounds. In: Vovelle, C. (eds) Pollutants from Combustion. NATO Science Series, vol 547. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4249-6_12

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  • DOI: https://doi.org/10.1007/978-94-011-4249-6_12

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6135-0

  • Online ISBN: 978-94-011-4249-6

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