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Dielectric Relaxation on a Picosecond Time-scale at 77K; a time-resolved Stark fluorescence study on the LH2 B800-820 complex of Rps. acidophila

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Photosynthesis: Mechanisms and Effects

Abstract

The technique of electric field induced (Stark) absorbance and fluorescence difference spectroscopy has proven to be very successful in accessing the properties of the excited states of photosynthetic complexes [1]. The framework for interpreting the Stark effect as it has been developed for the bacterial reaction center [2] has been shown to be also useful for bacterial Light Harvesting complexes[3,4]. The B850 BChl’s of LH2 complexes are all characterised by a high difference dipole moment and giant difference polarizability between ground and exited state. Also a considerable amount of loss of dipole strength has been found [3].

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References

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© 1998 Springer Science+Business Media Dordrecht

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Frese, R.N., Gobets, B., van Stokkum, I.H.M., van Grondelle, R., van Mourik, F. (1998). Dielectric Relaxation on a Picosecond Time-scale at 77K; a time-resolved Stark fluorescence study on the LH2 B800-820 complex of Rps. acidophila. In: Garab, G. (eds) Photosynthesis: Mechanisms and Effects. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3953-3_9

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  • DOI: https://doi.org/10.1007/978-94-011-3953-3_9

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-5547-2

  • Online ISBN: 978-94-011-3953-3

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