Abstract
The technique of electric field induced (Stark) absorbance and fluorescence difference spectroscopy has proven to be very successful in accessing the properties of the excited states of photosynthetic complexes [1]. The framework for interpreting the Stark effect as it has been developed for the bacterial reaction center [2] has been shown to be also useful for bacterial Light Harvesting complexes[3,4]. The B850 BChl’s of LH2 complexes are all characterised by a high difference dipole moment and giant difference polarizability between ground and exited state. Also a considerable amount of loss of dipole strength has been found [3].
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References
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Frese, R.N., Gobets, B., van Stokkum, I.H.M., van Grondelle, R., van Mourik, F. (1998). Dielectric Relaxation on a Picosecond Time-scale at 77K; a time-resolved Stark fluorescence study on the LH2 B800-820 complex of Rps. acidophila. In: Garab, G. (eds) Photosynthesis: Mechanisms and Effects. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3953-3_9
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DOI: https://doi.org/10.1007/978-94-011-3953-3_9
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