Abstract
Crystal moduli of high polymers and their temperature dependence were investigated by X-ray diffraction. Relationship among the crystal modulus, molecular conformation and intermolecular forces were discussed. On the basis of these informations, we propose three conditions which need to be fulfilled to obtain the high modulus polymers. The temperature dependence of the crystal modulus is also discussed in relation to both the thermal molecular motion in the crystal lattice and the heat resistance of the polymers.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
I. Sakurada, Y.Nukushina, and T. Ito, J.Polym.Sci., 62, 57, 651 (1962).
I. Sakurada, T. Ito, and K. Nakamae, J.Polym. Sci., C15,75 (1970).
I. Sakurada, K. Kaji, J.Polym.Sci., C31, 57 (1970).
K. Nakamae, T. Nishino, Y. Shimizu, and T. Matsumoto, Polym.J., 19,451 (1987).
W.J. Dulmage,_ L.E. Contois, J.Polym.Sci.,28, 275 (1958).
K. Nakamae, T. Nishino, and H.Ohkubo, J.Macromol.Sci.,to be published.
K. Nakamae, T. Nishino, and S. Takagi, Kobe Annual Meeting of Polymer Science, Prepr.,34,83 (1988).
K. Nakamae, T. Nishino, F. Yokoyama, and T. Matsumoto, J.Macromol.Sci.,-Phys., B27,407 (1988).
K. Nakamae, M. Kamayama, M. Yoshikawa, and T. Matsumoto, J.Polym. Sci.Polym.Phys. Ed., 20,319 (1982).
K. Nakamae, T. Nishino, K. Hata, and T. Matsumoto, Jpn.J.Polym.Sci., 42,361 (1985).
K. Nakamae, T. Nishino, K. Hata, F. Yokoyama, and T. Matsumoto, Jpn.J.Materials Sci., 35, 106 (1986).
K. Nakamae, T. Nishino, and K. Tada, Kobe Annual Meeting of Polym. Sci., Prepr., 35, 29 (1989).
K. Nakamae, T. Nishino, Polym.News, 14,179 (1989).
K. Nakamae, T. Nishino, H. Ohkubo, Polym.Prepr.Jpn., 36,2438 (1987).
W. Pechhold, Kolloid-Z., 189, 14 (1963), 228,1 (1968), 241, 955 (1970).
K. Nakamae, T. Nishino, Y. Shimizu, K. Hata, and T. Matsumoto, Jpn. J.Polym. Sci., 43, 499 (1986).
K. Haraguchi, T. Kajiyama, M. Takayanagi, Sen’i Gakkaishi, 33,T-535 (1977).
K. Nakamae, T. Nishino, K. Hata, H. Ohkubo, and T. Matsumoto, 2nd SPSJ Int. Polym. Conference, Prepr.,p.98 (1986).
K. Nakamae, T. Nishino, H. Ohkubo, S. Matsuzawa, and K. Yamaura, Report of Poval Committee,92,99 (1988).
N. Nagura, S. Matsuzawa, K. Yamaura, and H. Ishikawa, Polym.J., 14,69 (1982).
K. Nakamae, T. Nishino, et al., it.PP, Jpn.J.Polym.Sci.,42,241 (1985); POM, Polymer, in press., K.Tashiro, G.Wu, and K.Kobayashi, Polymer,29,1768 (1988); PTHF, Jpn.J.Polym.Sci.,45, 979 (1988); Nylon 6, ibid,44, 421 (1987)(E 1 at low temperature is reported by K.Miyasaka, T.Isomoto, H.Koganeya, K.Uehara, and K.Ishikawa, J.Polym.Sci., Polym. Phys.,18,1047 (1980)); PTMT,ibid,40,357 (1983); PEOB, ibid.,42,361 (1985), Cellulose, Polym.Prepr.Jpn.,39 (1990).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Elsevier Science Publishers Ltd
About this chapter
Cite this chapter
Nakamae, K., Nishino, T. (1991). Crystal Moduli of High Polymers and Their Temperature Dependence. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3890-1_16
Download citation
DOI: https://doi.org/10.1007/978-94-011-3890-1_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-85166-587-7
Online ISBN: 978-94-011-3890-1
eBook Packages: Springer Book Archive