Abstract
The nature of grain boundaries in pressureless sintered SiC with and without sintering aids is presented in connection with the absence and presence of strength loss at high temperatures. The absence of strength loss may be attributed to the occurrence of an ‘extended grain boundary’, whereas the remarkable loss in strength is due to the existence of an amorphous-like second phase at the grain boundaries. This extended grain boundary is not of a special phase but simply of a relaxed structure with some extension, and is most likely composed mainly of SiC itself It is shown that the concept of extended grain boundaries can explain the observed behaviour in SiC.
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References
Tsuge, A. & Nishida, K., High-strength hot-pressed Si3N4 with concurrent Y2O3 and A12O3 additives. Bull. Am. Ceram. Soc, 57(4) (1978), 424–431.
For example, Kamigaito, O., Structural ceramics. Bull. Japan Inst. Metals, 24(6) (1985), 480–485.
Ogbuji, L. U., Grain boundaries in carbon-and boron-densified SiC: examination by high resolution transmission electron microscopy. In Materials Science Research, Vol. 14, Surface and Interfaces in Ceramics and Ceramics Metal Systems, ed. J. Pask & A. Evans, Plenum Press, New York, 1981, pp. 713–723.
Verma, A. R. & Krishna, P., Polymorphism and Polytypism in Crystals. John Wiley, New York, 1967.
Inomata, Y., Uemura, Y., Inoue, Z. & Tanaka, H., Energy stored in a grain boundary formed by a rotation along a hexagonal lattice plane in SiC crystals. Yogyo-Kyokai-Shi, 88(10) (1980), 628–633.
Uemura, Y., Inomata, Y. & Inoue, Z., A grain boundary of α-SiC bicrystals. J. Mater. Sci., 16(8) (1981), 2333–5233.
Tanaka, H. & Inomata, Y., Observations of holes around dislocation core in SiC crystal. J. Cryst. Growth, 53(3) (1981), 630–632.
Inomata, Y., Grain boundaries of high performance ceramics for structural uses. Bull. Japan Inst. Metals, 22(2) (1983), 128–129.
Ikuhara, Y., Kurishita, H. & Yoshinaga, H., Grain boundary and high-temperature strength of sintered SiC. Yogyo-Kyokai-Shi, 95(6) (1987), 638–645.
Ikuhara, Y., Miyazaki, H., Kurishita, H. & Yoshinaga, H., Grain boundaries in SiC with no additives. Proceedings of the’ 87 International Symposium & Exhibition on Science and Technology of Sintering, Tokyo, Japan.
Soeta, A. & Maeda, K., Study on sintering process of SiC ceramics with BeO or A1N addition by analytical electron microscopy. Yogyo-Kyokai-Shi, 93(10) (1985), 636–648.
Yajima, S., Hayashi, J. & Omori, M., Continuous silicon carbide fiber of high tensile strength. Chem. Lett., 45(9) (1975), 931.
Prochazka, S. & Charles, R. J., Strength of boron-doped, hot-pressed silicon carbide. Am. Ceram. Soc. Bull., 52(12) (1973), 885–891.
Hase, T., Suzuki, H. & Tomizuka, L., Microstructure development of undoped compact of β-SiC during heating. Yogyo-Kyokai-Shi, 87(6) (1979), 317–321.
Gulden, T. D., Mechanical properties of polycrystalline β-SiC. J. Am. Ceram. Soc., 52(11) (1969), 585–590.
Tanaka, H., Inomata, Y. & Kawabata, H., Strength of hot-pressed SiC from Al doped α-SiC powder. Yogyo-Kyokai-Shi, 88(3) (1980), 158–160.
Tanaka, H., Inomata, Y. & Kawabata, H., Strength of hot-pressed SiC by the addition of Al and B. Yogyo-Kyokai-Shi, 88(9) (1980), 570–574.
Fujita, S., Maeda, K. & Hyodo, S., Dislocation glide motion in 6HSiC single crystals subjected to high-temperature deformation. Phil. Mag., 55(2) (1987), 203–215.
Maeda, K., Dislocation glide induced plasticity of 6H SiC single crystals. Yogyo-Kyokai-Shi, 94(8) (1986), 784–789.
Iseki, T., Arakawa, K., Matsuzaki, H. & Suzuki, H., Joining of dense silicon carbide by hot-pressing. Yogyo-Kyokai-Shi, 91(8) (1983), 349–354.
Inomata, Y., Tanaka, H., Inoue, Z. & Kawabata, H., Phase relation in SiC-Al4C3-B4C system at 1800°C. Yogyo-Kyokai-Shi, 88(6) (1980), 353–355.
Suzuki, H. & Hase, T., Boron transport and change of lattice parameter during sintering of β-SiC. J. Am. Ceram. Soc, 63(5–6) (1980), 349–350.
Suzuki, H., Recent trend and theoretical background in sintering process of silicon carbide ceramics. Ceramics, 18(1) (1983), 3–9.
Ikuhara, Y., Ueno, H. & Yoshinaga, H., Mechanical properties of newly developed Si3N4-SiC composite material with relatively high flexibility. Yogyo-Kyokai-Shi, 93(8) (1985), 409–417.
For example, Abe, H., Kawai, M., Sugano, T. & Suzuki, K., In Engineering Ceramics, Ceramics Science Series No. 5, ed T. Yamaguchi & H. Yanagida. Gihodo, 1984, p. 133.
Hiraga, K., Application of high resolution electron microscopy to the study of structure defect and grain boundaries in Si3N4 and SiC—a brief review. Sci. Rep. Ritu, A-32(l) (1984), 1–20.
Niihara, K., Mechanical properties of CVD non-oxide ceramics. Bull. Am. Ceram. Soc., 63(9) (1984), 1160–1164.
Ichinose, H., Inomata, Y. & Ishida, Y., HREM analysis of SiC grain boundary structure. Yogyo-Kyokai-Shi, 94(4) (1986), 415–418.
Ikuhara, Y. & Yoshinaga, H., Change in grain boundary structure of AIN-polytype Sialon by electron irradiation. J. Electron Microsc, 36(6) (1987), 408–410.
Inomata, Y., Joined crystal of silicon carbide. Yogyo-Kyokai-Shi, 90(5) (1982), 242–247.
Greskovich, C. & Rosolowski, J. H., Sintering of covalent solids. J. Am. Ceram. Soc, 59(7–8) (1976), 336–343.
Kurishita, H., Kuba, S., Kubo, H. & Yoshinaga, H., Grain boundary strength of molybdenum bicrystals with a (110) twist boundary. Trans. JIM, 26(5) (1985), 332–340.
Kurishita, H., Oishi, A., Kubo, H. & Yoshinaga, H., Grain boundary fracture in molybdenum bicrystals with a (110) symmetric tilt boundary. Trans. JIM, 26(5) (1985), 341–352.
Kurishita, H. & Yoshinaga, H., Effects of interstitial impurities on intergranular brittleness of molybdenum. Bull. Japan Inst. Metals, 22(11), (1983), 944–952.
Kurishita, H., Yoshinaga, H., Abiko, K., Suzuki, S. & Kimura, H., Grain boundary fracture in molybdenum bicrystals. In Grain Boundary Structure and Related Phenomena, Supplement to Trans. JIM, 27 (1986), 739–746.
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Kurishita, H., Yoshinaga, H., Ikuhara, Y. (1991). Grain Boundary and High-Temperature Strength in SiC. In: Sömiya, S., Inomata, Y. (eds) Silicon Carbide Ceramics—1. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3842-0_9
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DOI: https://doi.org/10.1007/978-94-011-3842-0_9
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-85166-560-0
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