Skip to main content
SpringerLink
Log in

Study of Radical Cations by Time-Resolved Magnetic Resonance

  • Chapter
Radical Ionic Systems

Part of the book series: Topics in Molecular Organization and Engineering ((MOOE,volume 6))

Abstract

This review focuses on the study of hydrocarbon radical cations by time-resolved magnetic resonance methods. These studies attempt to elucidate the early chemical events induced by ionizing or photoionizing radiation. The development of specialized time-resolved magnetic resonance tools has allowed us to dispense with a key element that has been vital to a wide range of radical cation studies using static EPR, i.e., a stabilizing (rigid, chemically inert, electron capturing) matrix (e.g., frozen halocarbons, inert gases). The time-resolution and sensitivity achieved with the methods described in this chapter allow observations of very reactive radical cations in essentially neat systems (pure hydrocarbons) and in fluids up to room temperature. These methods open the way for the study of chemical intermediates such as hexamethyl(Dewar benzene)+ where implications and insights provided by theory are in need of further experimental data on radical cation structure and behavior under conditions less influenced by solvent/matrix interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Shiotani, M., Mag. Reson. Rev. 12, 333–381 (1987).

    CAS  Google Scholar 

  2. Shida, T., Haselbach, E., and T. Bally, Acc. Chem. Res. 17, 180–186, (1984).

    Article  CAS  Google Scholar 

  3. Knight, Jr., L. B., Acc. Chem. Res. 19, 313–321 (1986).

    Article  CAS  Google Scholar 

  4. Klassen, N. V. and Teather, G. G., J. Phys. Chem. 83, 326–329 (1979); Teather, G. G. and Klassen, N.V., J. Phys. Chem. 85, 3044-3046 (1981); Klassen, N. V. and Teather, G. G., J. Phys. Chem. 89, 2048-2053 (1985).

    Article  CAS  Google Scholar 

  5. Mehnert, R., Brede, O. and Naumann, W., Ber. Bunsenges. Physik. Chem. 88, 71–80 (1984); Mehnert, R., Brede, O. and Cserep, G., Radiat. Phys. Chem. 26, 353-363 (1985).

    Article  CAS  Google Scholar 

  6. LeMotais, B. C. and Jonah, C. D., Radiat. Phys. Chem. 33, 505–517, (1989).

    CAS  Google Scholar 

  7. Tagawa, S., Hayashi, N., Yoshida, Y., Washio, M. and Tabata, Y., Radiat. Phys. Chem. 34, 503–511 (1989).

    Google Scholar 

  8. Sauer, Jr., M. C., Romero, C. and Schmidt, K. H., Radial Phys. Chem. 29, 261–273 (1987).

    CAS  Google Scholar 

  9. de Haas, M. P., Warman, J. M., Infelta, P. P. and Hummel, A., Chem. Phys. Letters 31, 382–386 (1975); de Haas, M. P., Hummel, A., Infelta, P. and Warman, J. M., J. Chem. Phys. 65, 5019-5020 (1976).

    Article  Google Scholar 

  10. Sauer, Jr., M. C., Schmidt, K. H., and Liu, A., J. Phys. Chem. 91, 4836–4839 (1987); Sauer, Jr., M.C. and Schmidt, K. H., Radiat. Phys. Chem. 32, 281-285 (1988).

    Article  CAS  Google Scholar 

  11. Anisimov, O. A., Grigoryants, V. M., Molchanov, V. K. and Molin, Yu. N., Chem. Phys. Lett. 66, 265–268 (1979).

    Article  CAS  Google Scholar 

  12. Molin, O. A., Anisimov, Yu. N., Grigoryants, V. M., Molchanov, V. K. and Salikhov, K.M., J. Phys. Chem. 84, 1853–1856 (1980).

    Article  CAS  Google Scholar 

  13. Trifunac, A. D. and Smith, J.P., Chem. Phys. Lett. 73, 94–97 (1980).

    Article  CAS  Google Scholar 

  14. Smith, J. P. and Trifunac, A. D. J. Phys. Chem. 85, 1645–1653 (1981).

    Article  CAS  Google Scholar 

  15. Percy, L. T., Bakker, M. G. and Trifunac, A. D., J. Phys. Chem. 93, 4393–4396 (1989).

    Article  CAS  Google Scholar 

  16. Klassen, N. V. in “Radiation Chemistry”, Farhataziz and M. A. J. Rodgers (eds.), VCH Publishers, New York, pp. 29–64 (1987).

    Google Scholar 

  17. Fessenden, R. W., J. Chem. Phys. 58, 2489–2500 (1973); McLauchlan, K. A. and Stevens, D. G., Molecular Phys. 57, 223-239 (1986).

    Article  CAS  Google Scholar 

  18. Trifunac, A. D., Norris, J. R. and Lawler, R. G., J. Chem. Phys. 71, 4380–4390 (1979); b) Mims, W.B., in “Electron Paramagnetic Resonance” G. Geshwind (ed.), Plenum, New York, pp. 263-351 (1972).

    Article  CAS  Google Scholar 

  19. Freed, J. H. and Pedersen, J. B., Adv. Magn. Reson. 8, 1–84 (1976).

    CAS  Google Scholar 

  20. Trifunac, A. D., Lawler, R. G., Bartels, D. M. and Thurnauer, M. C., Prog. Reaction Kinetics 14, 43–156 (1986).

    CAS  Google Scholar 

  21. Bartels, D. M. and Lawler, R. G., J. Chcm. Phys. 86, 4843–4855 (1987); Bartels, D. M., Lawler, R.G. and Trifunac, A. D., J. Chcm. Phys. 83, 2686-2707 (1985); Han, P. and Bartels, D.M., Chem. Phys. Letters 159, 538-542 (1989).

    Article  CAS  Google Scholar 

  22. Warman, J. M., Infelta, P. P., de Haas, M. P. and Hummel, A., Chem. Phys. Letters 43, 321–325 (1976).

    Article  CAS  Google Scholar 

  23. Rothman, W., Hirayama, F. and Lipsky, S., J. Chem. Phys. 58, 1300–1317 (1973).

    Article  CAS  Google Scholar 

  24. Schmidt, K. H., Sauer, Jr., M. C., Lu, Y. and Liu, A., J. Phys. Chem., 94, 244–251 (1990).

    Article  CAS  Google Scholar 

  25. Werst, D. W., Percy, L. T. and Trifunac, A. D., J. Magn. Reson. 82, 588–591 (1989).

    CAS  Google Scholar 

  26. Wang. J. T. and Williams, F., Chem. Phys. Letters 82, 177–181 (1981); Nunome, K., Toriyama, K. and Iwasaki, M., J. Chem. Phys. 79, 2499-2503 (1983).

    Article  CAS  Google Scholar 

  27. Tabata, M. and Lund, A., Chem. Phys. 75, 379–388 (1983); Iwasaki, M, Toriyama, K., Nunome, K., Faraday Discuss. Chem. Soc. 78, 1-15 (1984).

    Article  CAS  Google Scholar 

  28. a) Toriyama, K., Nunome, K. and Iwasaki, M., J. Phys. Chem. 85, 2149–2152 (1981); b) Toriyama, K., Nunome, K., and Iwasaki, M., J. Chem. Phys. 77, 5891-5912 (1982).

    Article  CAS  Google Scholar 

  29. Shida, T. and Takemura, Y., Radiat. Phys. Chem. 21, 157–166 (1983).

    CAS  Google Scholar 

  30. “Radical Ions”, E. T. Kaiser and L. Kevan (eds.), Interscience, New York (1968). “Magnetic Properties of Free Radicals”, Landolt-Bornstein, Vol. 9, H. Fischer and K.-H. Hellwege (eds.), Springer-Verlag, Berlin, part d (1985).

    Google Scholar 

  31. Shida, T., Nosaka, Y. and Kato, T., J. Phys. Chem. 82, 695–698 (1978).

    Article  CAS  Google Scholar 

  32. Qin, X.-Z. and Trifunac, A. D., J. Phys. Chem, in press.

    Google Scholar 

  33. Qin, X.-Z. and Trifunac, A. D., J. Phys. Chem, in press.

    Google Scholar 

  34. Jacob, S. L., Craw, M. T., Depew, M. C. and Wan, J. K. S., Research on Chemical Intermediates 11, 271–279 (1989).

    Article  CAS  Google Scholar 

  35. Ichikawa, T. and Ohta, N., J. Phys. Chem. 91, 3244–3248 (1987); Ichikawa, T., Shiotani, M., Ohta, N. and Katsumata, S., J. Phys. Chem. 93, 3826-3831 (1989).

    Article  CAS  Google Scholar 

  36. Werst, D. W., Desrosiers, M. F. and Trifunac, A. D., Chem. Phys. Letters 133, 201–206 (1987).

    Article  CAS  Google Scholar 

  37. Werst, D. W. and Trifunac, A. D., J. Phys. Chem. 92, 1093–1103 (1988).

    Article  CAS  Google Scholar 

  38. Werst, D. W., Bakker, M. G. and Trifunac, A. D., J. Am. Chem. Soc., 113, 40–50 (1990).

    Article  Google Scholar 

  39. Werst, D. W., Desrosiers, M. F. and Trifunac, A. D. unpublished results.

    Google Scholar 

  40. Melekhov, V. I., Anisimov, O. A., Veselov, A. V. and Molin, Yu. N., Chem. Phys. Letters 127, 97–100 (1986).

    Article  CAS  Google Scholar 

  41. Werst, D. W., Percy, L. T. and Trifunac, A. D., Chem. Phys. Letters 153, 45–51 (1988).

    Article  CAS  Google Scholar 

  42. Warman, J. M. in “The Study of Fast Processes and Transient Species by Electron Pulse Radiolysis” J. H. Baxendale and F. Busi (eds.), Reidel, Boston, pp. 433–534 (1981).

    Google Scholar 

  43. Iwasaki, M., Toriyama, K., Fukaya, M., Muto, H. and Nunome, K., J. Phys. Chem. 89, 5278–5284 (1985).

    Article  CAS  Google Scholar 

  44. Nunome, K., Toriyama, K. and Iwasaki, M., Tetrahedron 42, 6315–6323 (1986).

    Article  CAS  Google Scholar 

  45. Toriyama, K., Nunome, K. and Iwasaki, M., J. Am. Chem. Soc. 109, 4496–4500 (1987).

    Article  CAS  Google Scholar 

  46. Toriyama, K., Nunome, K. and Iwasaki, M., J. Phys. Chem. 90, 6836–6842 (1986).

    Article  CAS  Google Scholar 

  47. Werst, D. W. and Trifunac, A. D., Chem. Phys. Letters 137, 475–481 (1987).

    Article  CAS  Google Scholar 

  48. Desrosiers, M. F. and Trifunac, A. D., J. Phys. Chem. 90, 1560–1564 (1986).

    Article  CAS  Google Scholar 

  49. Badger, B. and Brocklehurst, B., Trans. Faraday Soc. 65, 2576–2581 (1969).

    Article  CAS  Google Scholar 

  50. Ichikawa, T., Ohta, N. and Kajioka, H., J. Phys. Chem. 83, 284–294 (1979).

    Article  CAS  Google Scholar 

  51. Mehnert, R., Brede, O. and Cserep, G., Radiochem. Radioanal. Lett. 47, 173–188 (1981).

    CAS  Google Scholar 

  52. Saik, V., Anisimov, O., Lozovoy, V. and Molin, Y., Z. Naturforsch A 40, 239–245 (1985).

    Google Scholar 

  53. Williams, F. and Qin, X.-Z., Radiat. Phys. Chem. 32, 299–308 (1988).

    CAS  Google Scholar 

  54. Desrosiers, M. F. and Trifunac, A. D., Chem. Phys. Letters 121, 382–385 (1985).

    Article  CAS  Google Scholar 

  55. Smith, J. P. and Trifunac, A. D., Chem. Phys. Letters 83, 195–198 (1981).

    Article  CAS  Google Scholar 

  56. Kira, A., Arai, S. and Imamura, M., J. Phys. Chem. 76, 1119–1124 (1972).

    Article  CAS  Google Scholar 

  57. Baxendale, J. H., Beaumond, D. and Rodgers, M. A. J., Chem. Phys. Letters 4, 3–4 (1969).

    Article  CAS  Google Scholar 

  58. Fowles, P., Trans. Faraday Soc. 67, 428–439 (1971).

    Article  CAS  Google Scholar 

  59. Percy, L. T., Werst, D. W.and Trifunac, A. D., Radiat. Phys. Chem. 32, 209–213 (1988).

    CAS  Google Scholar 

  60. Shirashi, H., Ishigure, K. and Morokuma, K., J. Chem. Phys. 88, 4637–4649 (1988).

    Article  Google Scholar 

  61. Knolle, W. R. PhD. Thesis, University of Minnesota, (1970). As reported in: Wertz, J. E., Bolton, J. R. (1986), “Electron Spin Resonance”, Chapman and Hall, New York, pp. 466.

    Google Scholar 

  62. Taylor, G. N., Z. Phys. Chem. N. F. 101, 237–254 (1976).

    Article  CAS  Google Scholar 

  63. Evans, T. R., Wake, R. W. and Sifain, M. M., Tetrahedron Letters, 701–704 (1973)

    Google Scholar 

  64. Peacock, N. J. and Schuster, G. B., J. Am. Chem. Soc. 105, 3632–3638 (1983).

    Article  CAS  Google Scholar 

  65. Al-Ekabi, H. and de Mayo, P. J., J. Phys. Chem. 90, 4075–4080 (1986).

    Article  CAS  Google Scholar 

  66. Roth, H. D., Schilling, M. L. M. and Raghavachari, K., J. Am. Chem. Soc. 106, 253–255 (1984).

    Article  CAS  Google Scholar 

  67. Bien, G., Heilbronner, E., Kobayashi, T., Schmelzer, A., Goldstein, M. J., Leight, R. S. and Lipton, M. S., Helv. Chim. Acta 59, 2657–2673 (1976).

    Article  Google Scholar 

  68. Bews, J. R. and Glidewell, C., J. Mol. Struct. (THEOCHEM.) 86, 197–204 (1982).

    Article  Google Scholar 

  69. Rhodes, C. J., J. Am. Chem. Soc. 110, 446–4447 (1988). Rhodes, C. J., J. Am. Chem. Soc. 110, 8567-8568 (1988).

    Article  Google Scholar 

  70. Williams, F., Guo, Q.-X. and Nelson, S. F., J. Am. Chem. Soc, in press.

    Google Scholar 

  71. Shiotani, M., Yano, A., Ohta, N. and Ichikawa, M., Chem. Phys. Letters 147, 38–42 (1988).

    Article  CAS  Google Scholar 

  72. Qin, X.-Z., Werst, D. W. and Trifunac, A. D., J. Am. Chem. Soc, in press.

    Google Scholar 

  73. Qin, X.-Z., Werst, D. W. and Trifunac, A. D., unpublished results.

    Google Scholar 

  74. Hulme, R. and Symons, M. C., J. Chem. Soc, 1120–1126 (1965).

    Google Scholar 

  75. Goldstein, M. J. and Leight, R. S., J. Am. Chem. Soc. 99, 8112–8114 (1977).

    Article  CAS  Google Scholar 

  76. Haselbach, E., Bally, T., Lanyiova, Z. and Baertschi, P., Helv. Chim. Acta 62, 583–592 (1979); Raghavachari, K., Haddon, R. C. and Roth, H. D., J. Am. Chem. Soc. 105, 3110-3114 (1983); Gebicki, J.L., Gebicki, J. and Mayer, J., Radiat. Phys. Chem. 30, 165-167 (1987).

    Article  CAS  Google Scholar 

  77. Sauer, M. C. Jr., Jonah, C. D. and Naleway, C. A. to be submitted.

    Google Scholar 

  78. Choi, H. T., Haglund, J. A.; Lipsky, S. J. Phys. Chem. 87, 1583 (1985)

    Article  Google Scholar 

  79. Sauer, M. C., Jr.; Jonah, C. D.; Le Motais, B. D.; Chernovitz, A. C., J. Phys. Chem. 92, 4099 (1988).

    Article  CAS  Google Scholar 

  80. Baxendale, J. H. and Rasburn, E. J., J. Chem. Soc. Faraday Trans. I 70, 705–717 (1974).

    Article  CAS  Google Scholar 

  81. Zador, E., Warman, J. M. and Hummel, A., Chem. Phys. Lett 23, 363–366 (1973).

    Article  CAS  Google Scholar 

  82. Desrosiers, M. F. and Trifunac, A. D., Chem. Phys. Lett 118, 441–443 (1985).

    Article  CAS  Google Scholar 

  83. Lefkowitz, S. M. and Trifunac, A. D., J. Phys. Chem. 88, 77–81 (1984).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL, 60439, USA

    A. D. Trifunac & D. W. Werst

Authors
  1. A. D. Trifunac
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. W. Werst
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Linköping, Sweden

    A. Lund

  2. Hiroshima University, Japan

    M. Shiotani

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Trifunac, A.D., Werst, D.W. (1991). Study of Radical Cations by Time-Resolved Magnetic Resonance. In: Lund, A., Shiotani, M. (eds) Radical Ionic Systems. Topics in Molecular Organization and Engineering, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3750-8_8

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-3750-8_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5668-7

  • Online ISBN: 978-94-011-3750-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation