Abstract
The matrix isolation technique is particularly well-suited for the study of reactive species, including free radicals, molecular ions and molecular complexes, which react rapidly or decompose under normal chemical conditions. Matrix studies provide a valuable complement to gas phase work: band positions located in the matrix provide a guide for high resolution measurements and more information can often be obtained from a complete low resolution spectrum than from high resolution measurements on one band system.
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Andrews, L. (1991). Infrared and Optical Absorption Spectroscopy of Molecular Ions in Solid Argon. In: Lund, A., Shiotani, M. (eds) Radical Ionic Systems. Topics in Molecular Organization and Engineering, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3750-8_2
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