Abstract
This contribution is a short resume of the lectures given in the ASI course. It was felt by the author that the interested reader would be better served with such a resume and a list of central references giving access to the field, than with a lengthy tutorial text.
It has been known for a long time that polymers may adsorb on the particles of a colloidal dispersion and, if they do so, affect the stability of the dispersion. We will discuss here physisorption (i.e. attachment by weak forces, no chemical bonds) of polymers. Accounts of chemisorption and its effects can be found in a monograph by Napper [1].
The forces generated by the adsorbed polymers can be either attractive, namely when the chains form bridges between two neighbouring particles, or repulsive when the polymer forms a protective sheath around the particles which precludes any bridge formation [2].
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References
D.H. Napper. Polymeric Stabilisation of Colloidal Dispersions, AC Press, London (1983)
B. Vincent, Adv. Colloid Interface Sci. 4, 193 (1974).
E. Jenkel, B.Rumbach, Z. Electrochem. 55, 612 (1951).
C.A.J. Hoeve, J. Chem. Phys. 42, 2558 (1965)
C.A.J. Hoeve, J. Chem. Phys. 43, 3007 (1965)
C.A.J. Hoeve, J. Chem. Phys. 44, 1505 (1966).
A. Silberberg, J. Chem. Phys. 46, 1105 (1967)
A. Silberberg, J. Chem. Phys. 48, 2835 (1968).
E.A. DiMarzio, R.J. Rubin, J. Chem. Phys. 55, 4318 (1971).
R.J. Roe, J. Chem. Phys. 60, 4192 (1974).
J.M.H.M. Scheutjens, G.J. Fleer, J. Phys. Chem. 83, 1619 (1979)
J.M.H.M. Scheutjens, G.J. Fleer, J. Phys. Chem. 84, 178 (1980).
P.G. de Gennes, Macromolecules 14, 1637 (1981).
G.J. Fleer, J.M.H.M. Scheutjens, M.A. Cohen Stuart, Colloids Surfaces 31,1 (1988).
M.A. Cohen Stuart, T. Cosgrove, B. Vincent, Adv. Colloid Interface Sci. 24, 143 (1986).
M.A. Cohen Stuart, G.J. Fleer, J.M.H.M. Scheutjens, J. Colloid Interface Sci. 97, 515 (1984)
M.A. Cohen Stuart, G.J. Fleer, J.M.H.M. Scheutjens, J. Colloid Interface Sci. 97, 526 (1984).
J.M.H.M. Scheutjens, G.J. Fleer in ‘The Effect of Polymers on Dispersion Properties’, Tadros T.F., Ed. Ac. Press, London (1982), 145.
M.A. Cohen Stuart, J.M.H.M. Scheutjens, G.J. Fleer, J. Pol. Sci. Pol. Phys. Ed. 18, 559 (1980).
M.A. Cohen Stuart, in ‘Future Directions in Polymer Colloids’, M.S. El-Aasser, R. Fitch, Eds., NATO ASI Series, E 138, p. 229 (1987).
J.M.H.M. Scheutjens, G.J. Fleer, M.A. Cohen Stuart, Colloids Surfaces 21, 285 (1986).
H.J. Ploehn, W.B. Russel, Macromolecules 22, 266 (1989).
J.M.H.M. Scheutjens, G.J. Fleer, Macromolecules 18,1882 (1985).
E.G.M. Pelssers, M.A. Cohen Stuart, G.J. Fleer, Colloids Surfaces 38, 15 (1989).
E.G.M. Pelssers, M.A. Cohen Stuart, G.J. Fleer, J. Chem. Soc. Faraday Transaction I (1990, in press).
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Stuart, M.A.C. (1990). Polymers at Interfaces: Statics, Dynamics and Effects on Colloidal Stability. In: Bloor, D.M., Wyn-Jones, E. (eds) The Structure, Dynamics and Equilibrium Properties of Colloidal Systems. NATO ASI Series, vol 324. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3746-1_40
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DOI: https://doi.org/10.1007/978-94-011-3746-1_40
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