Skip to main content

Abstract

New polymeric thin films containing nonlinear optical chromophores aligned by corona poling for χ (2) experiments have been monitored by spectroscopic and optical waveguiding techniques, as well as by second harmonic generation and electrooptic measurements. Stability has been improved considerably in various crosslinked epoxy polymers by attaching the chromophores at several molecular positions to inhibit relaxation. With increased chromophore concentration and improved alignment, films exhibiting nonlinearities exceeding lithium niobate have now been demonstrated. Several electrooptic phase modulators have been constructed with these new materials and some preliminary results are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Singer, K. D., Lalama, S. L, Sohn, J. E. and Small, R. D. (1987) ‘Electro-Optic Organic Materials’, ‘Nonlinear Optical Properties of Organic Molecules and Crystals’, D. S. Chemla and J. Zyss, (eds.), Academic Press, Orlando, 1, pp. 437–468.

    Google Scholar 

  2. Williams, D. J. (1987) ‘Nonlinear Optical Properties of Guest-Host Polyme Structures’, ‘Nonlinear Optical Properties of Organic Molecules and Crystals’, D. S. Chemla and J. Zyss, (eds.), Academic Press, Orlando, 1, pp. 405–435.

    Google Scholar 

  3. Singer, K. D., Kuzyk, M. G. and Sohn, J. E. (1987) J. Opt. Soc. Am. B4, p. 968.

    ADS  Google Scholar 

  4. Eich, M., Sen, A., Looser, H. Bjorklund, G. C., Swalen, J. D., Twieg, R. J. Yoon, D. Y. (1989) J. Appl Phys., 66, p. 2559.

    Article  ADS  Google Scholar 

  5. Mortazavi, M. A., Knoesen, A., Kowel, S. T., Higgins, B. G. and Dienes, A. (1989) J. Opt. Soc. Am. B6, p. 733.

    ADS  Google Scholar 

  6. Page, R H., Jurich, M. C., Reck, B., Sen, A., Twieg, R. J., Swalen, J. D., Bjorklund, G. C. and Willson. C. G. (1990) J. Opt. Soc. Am. B7, p. 1239.

    ADS  Google Scholar 

  7. Eich, M., Reck, B., Yoon, D. Y., Willson, C. G. and Bjorklund, G. C. J. Appl. Phys. 66, p. 3241.

    Google Scholar 

  8. Reck, B., Eich, M., Jungbauer, D., Twieg, R. J., Willson, C. G., Yoon, D. Y. and Bjorklund, G. C. (1989) Proc. SPIE, 1147 p. 74.

    Article  ADS  Google Scholar 

  9. Jungbauer, D., Reck, B., Twieg, R. J., Yoon, D. Y., Willson, C. G. and Swalen, J. D. (1990) Appl. Phys. Lett. 56 p. 2610.

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Swalen, J.D. et al. (1991). Poled Epoxy Polymers for Optoelectronics. In: Messier, J., Kajzar, F., Prasad, P. (eds) Organic Molecules for Nonlinear Optics and Photonics. NATO ASI Series, vol 194. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3370-8_31

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-3370-8_31

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5490-4

  • Online ISBN: 978-94-011-3370-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics