Abstract
The phenomenon of solidification of a binary alloy (water and ammonium chloride) saturating a packed bed of spheres is investigated experimentally. The system is cooled through its top surface. The effect of heating the bottom surface of the system simultaneously with cooling its top surface is also examined. Three distinct regions were observed in the bed of spheres during the freezing process. A solid region adjacent to the cold top surface, a mixed phase region (commonly termed the “mush” or “mushy zone”) consisting of a mixture of solidified alloy and liquid, and a liquid region. The mixed phase region separated the solid and liquid regions and was of significant extent. The temperature distribution in the solid and in the mixed phase regions was practically linear. Increasing the initial concentration of the system or heating the bottom wall had the effect to retard the rate of solidification. Interestingly, remelting was observed at the solid/mush and mush/liquid interfaces.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
M.G. O’Callaghan, E.G. Gravalho and C.E. Huggins (1982) An analysis of heat and solute transport during solidification of an aqueous binary solution, Int’l J. Heat Mass Transfer 25, 553–573.
L.J. Fang, F.B. Cheung, J.H. Linehan and D.R. Pederson (1984) Selective freezing of a dilute salt solution on a cold ice surface, J. of Heat Transfer, 106, 385–393.
M.G. Worster (1986) Solidification of an alloy from a cooled boundary, J. Fluid Mech., 167, 481–501.
D. Poulikakos (1988) On the growth of a solid from a line heat sink in a binary alloy, Numerical Heat Transfer, 14, 113–126.
D. Poulikakos and W.Z. Cao (1989) Solidification of a binary alloy from a cold wire or pipe: modelling of the mixed phase region, Numerical Heat Transfer, Part A, 15, 197–219.
W.D. Bennon and F.P. Incropera (1987) A continuum model for momentum heat and species transport in binary solid-liquid phase change systems-I. Model formulation, Int’l Journal of Heat and Mass Transfer 30, 2165–2170.
W.D. Bennon and F.P. Incropera (1987) A continuum model for momentum, heat and species transport in binary solid-liquid phase change systems-II. Application to solidification in a rectangular cavity, Int’l J. Heat Mass Transfer, 30, 2171–2187.
Y. Hayashi and T. Komori (1979) Investigation of freezing of a salt solution in cells, J. Heat Transfer, 101, 459–464.
T. Fujii, D.R. Pourier and M.C. Flemings (1979) Monosegregation in multicomponent low alloy steel, Met. Trans., B. 10B, 313–319.
S.D. Ridder, F.C. Reyes, S. Chakravotry, R. Mehrabian, J.D. Nauman, J.H. Chen and H.J. Klein (1978) Steady state segregation and heat flow in ESR, Met. Trans., B 9R, 415–425.
R.N. Hills, D.E. Loper and P.H. Roberts (1983) A thermodynamically consistent model for a mushy zone, Q.J. Mech. Appl. Math., 36, 505–539.
J.P. Gupta and S.W. Churchill (1971) Heat and moisture transfer in sand during freezing, Environmental geophysical heat transfer WAM of ASME, Washington, D.C. Nov. 30, HTD-4.
P.E. Frivik and G. Comini (1982) Seepage and heat flow in soil freezing, J. of Heat Transfer, 104, 323–328.
M.E. Goldstein and R.L. Reid (1978) Effect of fluid on freezing and thawing of saturated porous media, Proceedings of Royal Society of London, Series A, 364, 45–73.
M. Sugawara, H. Imaba and N. Seki (1988) Effect on maximum density of water on freezing of a water-saturated horizontal porous layer J. of Heat Transfer, 110, 155–159.
J.A. Weaver and R. Viskanta (1986) Freezing of liquid-saturated porous media, J. of Heat Transfer, 108, 654–659.
J.A. Weaver and R. Viskanta (1986) Freezing of water saturated porous media in a rectangular cavity, Int. Comm. Heat Mass Transfer, 13, 245–252.
W.-Z. Cao and D. Poulikakos, Freezing of a Binary Alloy Saturating a Packed Bed of Spheres, AIAA Journal of Thermophysics and Heat Transfer, in press.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Cao, WZ., Poulikakos, D. (1991). Solidification of A Binary Mixture Saturating A Bed of Glass Spheres. In: Kakaç, S., Kilkiş, B., Kulacki, F.A., Arinç, F. (eds) Convective Heat and Mass Transfer in Porous Media. NATO ASI Series, vol 196. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3220-6_24
Download citation
DOI: https://doi.org/10.1007/978-94-011-3220-6_24
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-5419-5
Online ISBN: 978-94-011-3220-6
eBook Packages: Springer Book Archive