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The Influence of Relaxation Processes in Matrices on the Spectroscopic Properties of the Solvated Electron

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Molecular Liquids: New Perspectives in Physics and Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 379))

Abstract

The near IR and visible absorption spectra of solvated electrons in water, alcohols, amines were calculated in terms of the electron-vibron coupling. The role of the H-bond is discussed.

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References

  1. Baxendale,J.H. Wardman,P.(1971)‘Direct observation of solution of the electron in liquid alcohols by pules radiolysis’, Nature,230,449

    Article  CAS  Google Scholar 

  2. Baxendale,J.H. Wardman,P.(1973)‘ Electrons in liguid alcohols at low temperature’, J.Chem.Soc.Faraday Trans.I,69,584

    Article  CAS  Google Scholar 

  3. Buxton,G.V. Gillis,H.A. Klassen,N.V. (1976)‘Evidence for a second kind of trapped electron in some deuterated agueous glasses at low temperatures. A pulse radiolysis study’, Can.J.Chem.,54,367

    Article  CAS  Google Scholar 

  4. Buxton,G.V. Kawabata,K. Salmon,G.A. (1978) ‘Yields of trapped electrons in pulse irradiated aqueous LiCl glasses at temperatures down to 6 K’,Chem.Phys. Lett. ,60,48

    Article  CAS  Google Scholar 

  5. Kawabata,K. Buxton,G.V. Salmon,G.A.(1979)‘Temperature dependence of trapped electrons in crystalline D 0 ice from 77 to 6 K’, Chem.Phys.Lett.,64,487

    Article  CAS  Google Scholar 

  6. Ogasawara,M. Shimizu,K. Yoshida, K. Kroh,J. Yoshida,H. (1979) ‘On the spectral shift of trapped electrons in glassy alcoholos irradiated at 4.2 K’, Chem.Phys.Lett. ,64,43

    Article  CAS  Google Scholar 

  7. Ogasawara,M. Shimizu,K. Yoshida,H. (1981) ‘Evolution of the spectra of the localized electrons in glassy alcohols irradiated at 4 K’,Radiat.Phys.Chem. ,17,331

    CAS  Google Scholar 

  8. Higashimura,T.(1974)‘Electron scavening at very low temperature’ Int. J.Radiat.Phys.Chem.,6, 393

    Article  CAS  Google Scholar 

  9. Hase,H. Kawabata,K.(1976)‘Trapped electron in crystalline D2 0 ice at 4 K’,J.Chem.Phys. ,65,64

    Article  CAS  Google Scholar 

  10. Buxton,G.V. Gillis,H.A. Klassen,N.V. (1977) ‘Two types of localized excess electrons in crystalline D2 0 ice’, Can.J.Chem. ,55, 2385

    Article  CAS  Google Scholar 

  11. van Leeuwen,J.W. Heijman,M.G. J. Nauta,H.(1981)‘A study of the temperature dependence of the visible absorption band of trapped electrons in ethylene glycol-water and LiCl glasses between and 100 K’ ,Radiat.Phys.Chem.,17,367

    Google Scholar 

  12. Chase, W. J. Hunt, J. W. (1975)‘Solvation time of the electron in polar liquids. Water and alcohols’,J.Phys.Chem.,79,2835

    Article  CAS  Google Scholar 

  13. Rentzepis,P.M. Jones,R.P. Jortner,J.(1973)‘Dynamics of solvation of an excess electron’,J.Chem.Phys. ,59,766

    Article  CAS  Google Scholar 

  14. Buxton, G. V. Kroh,J. Salmon, G. A. (1981) ‘Electron trapping in glassy normal alcohols. A pulse radiolysis study at temperatures down to 6 K’,J.Phys.Chem.,85,2021

    Article  CAS  Google Scholar 

  15. Klassen,N.V Gillis,H.A. Teather,G.G Kevan,L. (1975) ‘Pulse radiolysis studies of time dependent spectral shifts of the solvated electron in ethanol glasses at 76 K’,J.Chem.Phys., 62,2474

    Article  CAS  Google Scholar 

  16. Hase,H. Noda,M. Higashimura,T. (1971) Electronic spectra of trapped electrons in organic glasses at 4 K’,J.Chem.Phys., 54,2975

    Article  CAS  Google Scholar 

  17. Shida,T. Iwata,S. Watanabe,T. (1972) ‘Electronic absorption spectra of excess electrons in molecular aggregates. I. Trapped electrons in γ-irradiated amorphous solids at 77 K’ , J. Phys.Chem.,76, 3683

    Article  CAS  Google Scholar 

  18. Klassen,N.V. Teather,G.G.(1983)’“Initial” spectra of trapped electrons in alcohol glasses from 12 to 115 K’,J.Phys.Chem., 87,3894

    Article  CAS  Google Scholar 

  19. Nguyen,T.Q. Walker,D.C. Gillis,H.A. (1978) ’Evolution of the spectrum of the solvated electron in BeF2 aqueous glasses at 76K J. Chem.Phys.,69,1038

    Article  Google Scholar 

  20. Kevan,L. (1980) ‘Current problems in the localization and solvation of excess electrons in glasses’, J.Phys.Chem.,84,1232

    Article  CAS  Google Scholar 

  21. Rossky,J. Schnitker,J, (1988) ‘The hydrated electron: quantum simulation of structure, spectroscopy and dynamics’,J.Phys.Chem. 92,4277

    Article  CAS  Google Scholar 

  22. Barnett,R.B. Landman,U. Nitzan,A. (1989) ‘Relaxation dynamics following transition of solvated electrons’, J.Chem.Phys., 90,4413

    Article  CAS  Google Scholar 

  23. Fueki,K. Feng,D. Kevan,L.(1972) ‘Application of the semicontinuum model of the effect of dipole reorientation on trapped electron spectra in glassy ethanol’,J.Chem.Phys. , 56,5351

    Article  CAS  Google Scholar 

  24. a.Migus,A. Gauduel,Y. Martin,J.L. Antonetti,A. (1987) ‘Excess electrons in liquid water: First evidence of a prehydrated state with femtosecond lifetime’,Phys.Rev.Lett.,58,1559

    Article  CAS  Google Scholar 

  25. Ogg,R.A.Jr (1946) ‘Electronic processes in liquid dielectric media. The properties of metal-ammonia solutions’J. Am. Chem.Soc., 68,155

    Article  CAS  Google Scholar 

  26. Newton,M.D. (1975) ‘The role of ab initio calculations in elucidating properties of hydrated and ammoniated electrons’,J. Phys.Chem.,79,2795

    Article  CAS  Google Scholar 

  27. Clark,T. Illing,G. (1987) ‘ Ab initio localized electron calculations on solvated electron structures’ ,J. Am. Chem.Soc.,109,1013

    Article  CAS  Google Scholar 

  28. Fueki,K. Feng,D.F. Kevan,L. Christofferson,R. E. (1971) ‘A semicontinuum model for the hydrated electron. II. Configurational stability of the ground state’, J. Phys.Chem., 75,2297

    Article  Google Scholar 

  29. Kestner,N.R. Jortner,J.(1984) ‘Studies of the stability of negatively charged water clusters’, J. Phys. Chem.,88,3818

    Article  CAS  Google Scholar 

  30. Dawes,S.B. Ward,D.L. Huang,R.H. Dye,J. L. (1986) ‘First electride crystal structure’,J.Am.Chem. Soc. , 108,353

    Article  Google Scholar 

  31. Symons,M.C.R.(1988) ‘Aquated electrons, H2 o- anions and OH-/H3 0 units’ ,J.Phys.Chem.,92,7260

    Article  CAS  Google Scholar 

  32. Webster,B. (1975) ‘Ab-initio studies into the mechanisms of formation of the hydrated electron’,J.Phys.Chem.,79,2809

    Article  CAS  Google Scholar 

  33. Tuttle,T.R.Jr Golden,S.(1979) ‘Model potentials and the optical spectra of solvated electrons’, J.Chem.Soc. Faraday Trans.2, 75,1146

    Article  CAS  Google Scholar 

  34. Tuttle,T.R.Jr. Golden,S.(1980) ‘Resolution of optical spectra of solvated electrons in water’, J.Phys.Chem.,84,2457

    Article  CAS  Google Scholar 

  35. Tuttle,T.R.Jr. Golden, S. (1981) ‘Shape stability of solvated-electron optical absorption bands’,J.Chem.Soc.Faraday Trans.2, 77, 873,889,1421

    Article  Google Scholar 

  36. Golden,S. Tuttle,T.R.Jr. (1984) ‘Limitation on determining excess-electron structures by magnetic resonance methods’, J. Phys.Chem.,88,3781

    Article  CAS  Google Scholar 

  37. Razem,D. Hamill,W. H. (1978) ‘Activated and activationless localization and impurity trapping of the electron in C2 H5 OH and C2 H5 0D’ J. Phys. Chem. ,82,488

    Google Scholar 

  38. Jortner,J. (1962)’ Mol.Phys.,5,257

    Article  CAS  Google Scholar 

  39. Jortner,J. (1959) ‘Energy levels of bound electrons in liquid ammonia’, J.Chem.Phys.,36,839

    Article  Google Scholar 

  40. Feng,D-F. Kevan,L. (1980) ‘Theoretical models for solvated electrons’, Chem.Rev. , 80,1

    Article  CAS  Google Scholar 

  41. Rao,B.K. Kestner,N.R.(1984) ‘Ab initio calculations on negatively charged water clusters’,J.Chem.Phys.,80,1587

    Article  CAS  Google Scholar 

  42. Barnett,R.N. Landman,U. Nitzan,A (1989) ‘Dynamics of excess electron migration, solvation and spectra in polar molecular clusters’,J.Chem.Phys.,91,5567

    Article  CAS  Google Scholar 

  43. Sprik,M. Klein,M.L.(1988) ‘Optimization of a distributed Gaussian basis set using simulated annealing: Application to the adiabatic dynamics of the solvated electron’J.Chem.Phys.,89,1592

    Article  CAS  Google Scholar 

  44. Sprik,M. Klein,M.L.(1989) ‘Adiabatic dynamics of the solvated electrron in liquid ammonia’,J.Chem.Phys. ,91,5665

    Article  CAS  Google Scholar 

  45. Wallqvist,A. Thirumalai, D. Berne,B.J. (1987) ‘Path integral Monte Carlo study of the hydrated electron’ ,J. Chem.Phys.,86,6404

    Article  CAS  Google Scholar 

  46. Webster,B.(1980) ‘Some new perspectives for excess electron theory and experiment. Linking the microscopic with the macroscopic’,J.Phys.Chem. , 84,1070

    Article  CAS  Google Scholar 

  47. Haberland,H. Ludwight,Ch. Schinden,H. G. Worshop,D.R. (1984) ‘Experimental observation of the negatively charged water dimer and other small (H 0)n clusters’, J.Chem.Phys.,81,3742

    Article  CAS  Google Scholar 

  48. Holton,D. Edwards,P.P McFarlane,W. Wood,B. (1983) ‘ Multinuclear NMR study of the solvated electron in lithium-methylamine solutions’,J.Am.Chem.Soc.,105,2104

    Article  CAS  Google Scholar 

  49. Kenney-Wal lace,G. A. Jonah, C.D. (1982) ‘Picosecond spectroscopy and solvation clusters. The dynamics of localizing electrons in polar fluids’,J.Phys.Chem.,86,2572

    Article  CAS  Google Scholar 

  50. Funabashi,K. Carmichael, I. Hamill,W.H. (1978) ‘ Photon-induced electron transfer transitions of the solvated electrons’, J. Chem.Phys.,69,2652

    Article  CAS  Google Scholar 

  51. Walker,D. C. (1980) ‘Dynamics of electron localization’, J.Phys.Chem. ,84,1140

    Article  CAS  Google Scholar 

  52. Callef,D.F. Wolynes,P.G.(1983)’Smoluchowski-Vlasov theory of charge solvation dynamics’, J.Chem. Phys.,78,4145

    Article  Google Scholar 

  53. Banerjee,A Simons,J.(1978)‘Excess electrons in condensed media: theory of optical absorption spectrum in molecular solutions’,J. Chem. Phys. ,68,415

    Article  CAS  Google Scholar 

  54. Copeland, D.A Kestner,N.R. Jortner,J (1970)‘Excess electrons in polar solvents’, J. Chem. Phys. ,53,1189

    Article  CAS  Google Scholar 

  55. Abramczyk,H.(1991)‘Absorption spectrum of the solvated electron. 1. Theory’ ,J.Phys.Chem.,95,6149

    Article  CAS  Google Scholar 

  56. Abramczyk,H. Kroh, J.(1991)‘Absorption spectrum of the solvated electron. 2. Numerical calculation of the profiles in water and methanol at 300 K’,J.Phys.Chem. ,95,6155

    Article  CAS  Google Scholar 

  57. Abramczyk,H. Kroh,J.(1991)‘Absorption spectrum of the solvated electron in ammonia and amines’, J.Phys.Chem.,95,5749

    Article  CAS  Google Scholar 

  58. Abramczyk,H Kroh,J. (1991‘Absorption spectra of a solvated electron in ethers’,Chem.Phys. , in press

    Google Scholar 

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Authors and Affiliations

  1. Institute of Applied Radiation Chemistry, Technical University, 93-950, Łódź, Wróblewskiego 15, Poland

    H. Abramczyk & J. Kroh

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  1. H. Abramczyk
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  2. J. Kroh
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  1. Departamento de Química, Universidade de Coimbra, Coimbra, Portugal

    José J. C. Teixeira-Dias

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© 1992 Springer Science+Business Media Dordrecht

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Abramczyk, H., Kroh, J. (1992). The Influence of Relaxation Processes in Matrices on the Spectroscopic Properties of the Solvated Electron. In: Teixeira-Dias, J.J.C. (eds) Molecular Liquids: New Perspectives in Physics and Chemistry. NATO ASI Series, vol 379. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2832-2_25

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  • DOI: https://doi.org/10.1007/978-94-011-2832-2_25

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5258-0

  • Online ISBN: 978-94-011-2832-2

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