Abstract
Most important elementary processes governing the behaviour of the converter (chemical reactions, heat and mass transfer processes to the catalyst surface, hydrodynamic, heat conduction and heat loss) are first described. Next, published models are reviewed and main modeling problems are considered. Then, the structure of a fairly general model is proposed. The behaviour of the converter at steady state and in the transient state is reported and the sensitivity of the model to various parameters is discussed. It is concluded that the lack of accurate data (especially kinetic data) makes the predictions with available models only qualitative assessments. However, many design or operating improvements can be deduced from these models.
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Chen D.K.S., S.H. Oh, E.J. Bissett, and D.L. van Ostrom (1988) ‘A three dimensional model for the analysis of transient thermal and conversion characteristics of monolithic catalytic converters’, SAE Paper 880282.
Chen D.K.S., and C.E. Cole (1989) ‘Numerical simulation and experimental verification of conversion and thermal responses for a Pt/Rh metal monolithic converter’, SAE Paper 890798.
Chiron M. (1987) ‘Effects of motor vehicle pollutants on health’, in A. Crucq and A. Frennet (eds), Catalyst and automotive pollution control, Studies in surface science and catalysis, 30, Elsevier Sciences Publishers, Amsterdam.
Eigenberger G. (1972) ‘On the dynamic behaviour of the catalytic fixed-bed reactor in the region of multiple steady states. I -The influence of heat conduction in two phase models’, Chem. Eng. Sci., 27, 1909–1915.
Froment G.F., and K.B. Bischoff (1979) Chemical reactor analysis and design, J. Wiley, New-York.
Heck R.H., J. Wei, and J.R.Katzer (1974) ‘The transient response of a monolithic catalyst support’, in Amer. Chem. Soc. (eds), Chem. React. Eng., Adv. in Chem. Series 133, pp. 34– 45.
Heck R.H., J. Wei, and J.R. Katzer (1976) ‘Mathematical modeling of monolithic catalysts’, AIChE J., 22, 3, 477–484.
Hegedus L. (1975) ‘Temperature excursions in catalytic monoliths’, AIChE J., 21, 849–853.
Howitt J.S., and T.C. Sekella (1974) ‘Flow effects in monolithic honeycomb automotive catalytic converters’, Paper SAE 740244.
Idelick, I. E. (1979) Memento des pertes de charges, Eyrolles Ed. Paris.
Impens R. (1987) ‘Automotive traffic, risk for the environment’, in A. Crucq and A. Frennet (eds), Catalyst and automotive pollution control, Studies in surface science and catalysis, 30, Elsevier Sciences Publishers , Amsterdam.
Kuo J.C.W., C.R. Morgan, and H.G. Lassen (1971) ‘Mathematical modeling of CO and HC catalytic converter systems’, Paper SAE 710289.
Leclerc J.P., D. Schweich, and J. Villermaux (1989a) ‘Transfert de chaleur en régime transitoire dans un monolithe destiné à l’épuration des gaz d’échappement automobile’, Rencontre SFT 89, “Thermique et Génie des Procédés”, Nancy, 23/25-5-89.
Leclerc J.P., D. Schweich, and J. Villermaux (1989b) ‘Hydrodynamique et transfert de chaleur dans un monolithe destiné à l’épuration des gaz d’échappement automobile’, Colloque Génie des procédés, Toulouse, 1989. Récents progrès en génie des procédés, Lavoisier Ed., 3(8a), pp. 518–524.
Leclerc J.P., D. Schweich, and J. Villermaux (1990) ‘Flow, heat transfer and chemical reaction in race-track monolithic catalytic converters -A theoretical and experimental study’, AIChE 1990 spring national meeting, 18–22 mars 1990, Orlando, Floride, USA.
Leclerc, J.P. (1991) Contribution à l’étude du fonctionnement des pots catalytiques, PhD thesis, Institut National Polytechnique de Lorraine, Nancy, France.
Lee S.T., and R. Aris (1977) ‘On the effect of radiative heat transfer in monoliths’, Chem. Eng. Sci., 32, 827–837.
Lee S.T., and R. Aris (1978) ‘Poisoning in monolithic catalysts’, ACS Symp. Series, 65, pp. 110–121.
Lemme C.D., and W.R. Givens (1974) ‘Flow through catalytic converters. An analytical and experimental treatment’, Paper SAE 740243.
Martin H. (1978) ‘Low Peclet number particle to fluid heat and mass transfer in packed beds’, Chem. Eng. Sci. 33, 913.
Midoux, N. (1985) Mécanique et rhéologie des fluides en génie chimique, Technique et documentation, Lavoisier Ed., Paris.
Oh S.H., and J. Cavendish (1981) ‘Transients of monolithic catalytic converters: response to step changes in feedstream temperatures as related to controling automobile emissions’, Ind. Eng. Chem. Proc. Des. Devel., 21, 29–37.
Oh S.H., and J.C. Cavendish (1983) ‘Design aspects of poison-resistant automobile monolithic catalysts’, Ind. Eng. Chem. Prod. Res. Dev., 509–518.
Prigent M. (1985) ‘Aperçu sur les problèmes de catalyse dans les pots catalytiques d’automobiles’, Revue de l’institut Français du pétrole, 40, 3, 393–409.
Reid R.C., J.M. Prausnitz, and T.K. Sherwood (1977) The properties of gases and liquids, McGraw Hill, 3rd edition.
Ryan M.J., E.R. Becker, and K. Zygourakis (1991) ‘Light-off performance of catalytic converters: the effect of heat/mass transfer characteristics’, SAE Paper 910610.
Schlünder, E. U. (1986) ‘Fluid mechanics and heat transfer’, Heat design handbook 2 , VDI-Verlag, Düsseldorf.
Shah R.K., and T.C. London (1978) Flow forced convection in ducts. Advances in heat transfer-Laminar., Academic Press, New-York.
Steel M.C.F. (1990) ‘Supply and demand of precious metals for automotive and others uses’, in A. Crucq (ed), Catalyst and automotive pollution control II, Studies in surface science and catalysis, 71, Elsevier Sciences Publishers , Amsterdam, pp. 105–114.
Subramanian B, and A. Varma (1984) ‘Reactions of CO, NO, O2, and H2O on three-way and Pt/gAl2O3 catalysts’, Frontiers in chemical engineering, Proceedings of the International Chemical Engineering Conference, 1, pp. 231–240.
Subramanian B, and A. Varma (1985) ‘Reaction kinetics on a commercial three-way catalyst: the CO-NO-O2-H2O system’, Ind. Eng. Prod. Res. Dev., 24, 512–516.
Voltz S.E., C.R. Morgan, D. Liederman, and S.M. Jacob (1973) ‘Kinetic study of carbon monoxide and propylene oxidation on platinum catalysts’, Ind. Eng. Chem. Proc. Des. Devel., 12, 4, 294–301.
Votruba J., O. Mikus, Nguen K., V. Hlavacek, and J. Skrivanek (1975) ‘Heat and mass transfer in honeycomb catalyst -II’, Chem. Eng. Sci., 30, 201–206.
Wendland D.W. (1980) ‘The segmented oxidizing monolith catalytic converter’, Transactions of the ASME, Vol 102, 194–198.
Wendland D.W., and W.R. Matthes (1986) ‘Visualization of automobile catalytic converter internal flow’, Paper SAE 861554.
Young L.C., and B.A. Finlayson (1976a) ‘Mathematical models of the monolith catalytic converter, Part 1, development of model and application of orthogonal collocation’, AIChE J., 22, 2, 331–343.
Young L.C., and B.A. Finlayson (1976b) ‘Mathematical models of the monolith catalytic converter, Part 2, Application to automobile exhaust’, AIChE J., 22, 2, 343–353.
Zygourakis K. (1989) ‘Transient operation of monolith catalytic converters: a two-dimensional reactor model and the effect of radially nonuniform flow distributions’, Chem. Eng. Sci., 44, 9, 2075–2086.
Zygourakis K, and R. Aris (1983) ‘Multiple oxidation reactions and diffusion in the catalytic layer of monolith reactors’, Chem. Eng. Sci., 38, 733–744.
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© 1992 Springer Science+Business Media Dordrecht
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Leclerc, J.P., Schweich, D. (1992). Modeling Catalytic Monoliths for Automobile Emission Control. In: de Lasa, H.I., Doğu, G., Ravella, A. (eds) Chemical Reactor Technology for Environmentally Safe Reactors and Products. NATO ASI Series, vol 225. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2747-9_23
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DOI: https://doi.org/10.1007/978-94-011-2747-9_23
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