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Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory pp 49–88Cite as

Theory of Electron Transfer Reactions and Comparison with Experiments

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Part of the NATO ASI Series book series (ASIC,volume 376)

Abstract

In these lectures, reaction rate theory and the theory of electron transfer (ET) reactions are outlined. The topics discussed include the relation of the potential energy surfaces to free energy curves for ET reactions, classical ET theory for reactions in solution and at interfaces, quantum corrections, the inverted effect, relation to charge transfer spectra. the cross-relation, adiabatic and nonadiabatic ET reactions, electronic matrix elements, relation to other transfer reactions, predictions of and comparison with experiments, and miscellaneous questions.

Keywords

  • Electron Transfer
  • Potential Energy Surface
  • Separation Distance
  • Electron Transfer Reaction
  • Intersection Surface

These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

From lectures given by RAM at the NATO Summer School at Aussois, 1991.

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Authors and Affiliations

  1. Noyes Laboratory of Chemical Physics 127-72, California Institute of Technology, Pasadena, USA, CA, 91125

    R. A. Marcus & Prabha Siddarth

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  1. R. A. Marcus
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  2. Prabha Siddarth
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Editors and Affiliations

  1. Director, Laboratoire de Chimie Théorique Institut de Chimie, Université Louis Pasteur, 1, rue Blaise Pascal, BP 296, 67008, Strasbourg, France

    Elise Kochanski

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Marcus, R.A., Siddarth, P. (1992). Theory of Electron Transfer Reactions and Comparison with Experiments. In: Kochanski, E. (eds) Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory. NATO ASI Series, vol 376. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2698-4_2

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