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The Use of Calorimetric and Sublimation techniques to study Bond Properties in Organometallic Compounds

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Energetics of Organometallic Species

Part of the book series: NATO ASI Series ((ASIC,volume 367))

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Abstract

Rotating, aneroid combustion calorimetry combined with mass-loss, torsion Knudsen effusion is used to study the energetics of some organic compounds of Hg, Sn and Ge. Structural effects in some Cr, Mo and Cu compounds are also considered.

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References

  1. Cox, J. D. and Pilcher, G. (1970) Thermochemistry of Organometallic Compounds, Academic Press, London.

    Google Scholar 

  2. Mortimer, C. T. (1984) ‘Differential Scanning Calorimetry’ in Ribeiro da Silva, M. A. V. (ed), Thermochemistry and its Applications to Chemical and Biochemical Systems, NATO ASI Series C, Vol 119, Reidei, Dordrecht.

    Google Scholar 

  3. Pilcher, G. and Skinner, H. A. (1982) ‘Thermochemistry of Organometallic Compounds’ in Hartley, F. R. and Patai, S. (eds) the Chemistry of the Metal-Carbon Bond, John Wiley and Sons, Ltd, London.

    Google Scholar 

  4. Marks, Tobin J. (1990) ‘Importance of Metal-Ligand Energies’, in Marks, Tobin J. (ed) Organometallic Chemistry, J. Amer. Chem. Soc. Symposium Series 428, Washington.

    Google Scholar 

  5. Burkinshaw, P. M. and Mortimer, C. T. (1983) Coordination Chemistry Review 48, 10

    Article  Google Scholar 

  6. Mortimer, C. T. (1984) Rev. Organic Chemistry, 6, 233.

    CAS  Google Scholar 

  7. Adams, G. P., Carson, A. S. and Laye, P. G. (1969), Trans. Faraday Soc. 65, 113

    Article  CAS  Google Scholar 

  8. Carson, A. S., Carson, E. M., Laye, P. G., Spencer, J. A. and Steele, W. V. (1970) Trans. Faraday Soc. 66, 2459.

    Google Scholar 

  9. Majer, V. and Svoboda, V. (1985) Enthalpies of Vaporization of Organic Compounds’ in IUP AC Chemical Data Series No. 32, Blackwell Scientific Publications, Oxford.

    Google Scholar 

  10. Carson, A. S. (1984) ‘The Measurement of Vapour Pressures’, in Ribeiro da Silva, M. A. V. (ed) Thermochemistry and its Applications to Chemical and Biochemical Systems, NATO ASI Series C, Vol. 119, Reidel, Dordrecht.

    Google Scholar 

  11. Edwards, J. W. and Kington, G. L. (1962) Trans. Faraday Soc. 58, 1323

    Google Scholar 

  12. Ribeiro da Silva, M. A. V., Ribeiro da Silva, Maria D. M. C., Rangel, Maria C. S. S., Pilcher, G. Akello, Margaret J., Carson, A. S. and Jamea, E. H. (1990) Thermochim Acta 160, 267

    Article  CAS  Google Scholar 

  13. Cavell, K. J., Garner, C. D., Pilcher, G. and Parkes, S. (1979) J. Chem. Soc. Dalton, 1714

    Google Scholar 

  14. Carson, A. S. (1984) J. Chem. Thermodynamics, 16, 855.

    Google Scholar 

  15. Cotton, F. A., Rice, C. E. and Rice, G. W. (1977) J. Am. Chem. Soc. 99, 4704.

    Google Scholar 

  16. Cotton, F. A., Deboer, B. G., Laprade, M. D., Pipai, J. R. and Ucko, D. A. (1971) Acta Ciyst. B27, 1664.

    Article  CAS  Google Scholar 

  17. Pilcher, G. (1989) Pure and Appl. Chem. 61, 855.

    Article  CAS  Google Scholar 

  18. Dias, A. R., Diogo, H. P., Minas da Piedade, M.E., Martinho Simões, J. A., Carson, A. S. and Jamea, E. H. (1990) J. Organometallic Chem. 391, 361.

    Article  CAS  Google Scholar 

  19. Carson, A. S. and Spencer, J. A. (1984) J. Chem. Thermodynamics, 16, 423.

    Google Scholar 

  20. Carson, A. S., Laye, P. G. and Spencer, J. A. (1985) J. Chem. Thermodynamics, 17, 277.

    Google Scholar 

  21. Carson, A. S., Franklin, J., Laye, P. G. and Morris, H. (1975) J. Chem. Thermodynamics, 7, 763.

    Google Scholar 

  22. Chambers, D. B. and Glockling, F. J. (1968) J. Chem. Soc.(A), 735.

    Google Scholar 

  23. Carson, A. S., Jamea, E. H., Laye, P. G. and Spencer, J. A. (1988) J. Chem. Thermodynamics, 20, 1223.

    Google Scholar 

  24. Carson, A. S., Laye, P.G., Spencer, J. A. and Steele, W. V. (1970) J. Chem. Thermodynamics, 2, 659.

    Google Scholar 

  25. Adams, G. P., Carson, A. S. and Laye, P. G. (1969) J. Chem. Thermodynamics, 1, 393.

    Google Scholar 

  26. Long, L. H. and Pulford, C. I. (1986) J. Chem. Soc. Faraday Trans. 2, 82, 567.

    Google Scholar 

  27. Carson, A. S., Dyson, J., Laye, P. G. and Spencer, J. A. (1988) J. Chem. Thermodynamics, 20, 1423.

    Google Scholar 

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Author information

Authors and Affiliations

  1. School of Chemistry the University of Leeds, Leeds, LS2 9JT, UK

    A. S. Carson

Authors
  1. A. S. Carson
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Editor information

Editors and Affiliations

  1. Departmento de Engenharia Química, Instituto Superior Técnico, Lisbon, Portugal

    J. A. Martinho Simões

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© 1992 Springer Science+Business Media Dordrecht

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Carson, A.S. (1992). The Use of Calorimetric and Sublimation techniques to study Bond Properties in Organometallic Compounds. In: Martinho Simões, J.A. (eds) Energetics of Organometallic Species. NATO ASI Series, vol 367. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2466-9_9

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  • DOI: https://doi.org/10.1007/978-94-011-2466-9_9

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5088-3

  • Online ISBN: 978-94-011-2466-9

  • eBook Packages: Springer Book Archive

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