Abstract
The separation characteristics of microfiltration and ultrafiltration membranes depend on their physical properties such as their porosity, pore size distribution and pore structure. However, such membranes cannot be understood simply as sieves. Neither in this context can the materials to be separated, particles, colloids, microbial cells or proteins, be sufficiently characterised in terms of size or molecular weight. In particular, the electrochemical properties of the membrane surfaces and dispersed materials or solutes can have a significant influence on the nature and magnitude of the interactions between the membrane and the substances being processed. This chapter begins by describing the nature of these electrochemical properties and their influence on conventional pressure driven membrane processes. It is then shown how the application of external electric fields can make use of these properties to substantially improve the performance of membrane separations, giving a range of processes known collectively as electrofiltration or electrically enhanced membrane processes.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Bowen, W. R. & Clarke, R. A. (1984). Electro-osmosis at microporous membranes and the determination of zeta-potential. J. Colloid Interface Sci., 97, 401–9.
Bowen, W. R. & Cooke R. J. (1990). Properties of microfiltration membranes. Computer automated determination of the zeta-potential of cellulose nitrate membranes, Proceedings of the Vth World Filtration Congress, Nice, pp. 231–9.
Bowen, W. R. & Cooke, R. J. (1991) Properties of microfiltration membranes. Computer automated determination of the electrokinetic properties of polycarbonate membranes, J. Colloid Interface Sci., 141, 280–7.
Bowen, W. R. & Goenaga, X. (1989). Electrically enhanced membrane filtration. Cross-flow microfiltration and electrofiltration at aluminium oxide membranes. Proceedings of the International Congress on Inorganic membranes, ed. L. Cot. and J. Charpin,  Montpellier, pp. 411–14.
Bowen, W. R. & Goenaga, X. (1990). Properties of microfiltration membranes. Effect of physicochemical conditions on cross-flow microfiltration at aluminium oxide membranes. I. Chem. E. Symposium Series, No. 118, 8.1–8.12.
Bowen, W. R. & Hughes, D. T. (1990). Properties of microfiltration membranes. Adsorption of bovine serum albumin at aluminium oxide membranes. J. Membr. Sci., 51, 189–200.
Bowen, W. R. & Hughes D. T. (1991). Properties of microfiltration membranes. The surface electrochemistry of anodic film membranes. J. Colloid Interface Sci., 143, 252–65.
Bowen, W. R. & Jacobs, P. M. (1986). Electro-osmosis and the determination of zeta-potential: the effect of particle concentration. J. Colloid Interface Sci., 111, 223–9.
Bowen, W. R., Goenaga, X. & Sabuni, H. A. M. (1989a). Electrically enhanced membrane filtration—construction and operation of an automated laboratory test-rig. I. Chem. E. Symp. Series, No. 112, 251–62.
Bowen, W. R., Kingdon, R. S. & Sabuni, H. A. M. (1989b). Electrically enhanced separation processes: the basis of in-situ intermittent electrolytic membrane cleaning (IEMC) and in-situ electrolytic membrane restoration (IEMR). J. Membr. Sci., 40, 219–29.
Cheryan, M. (1986). Ultrafiltration handbook, Technomic Publishing Company, Lancaster.
Fane, A. G. (1986). Ultrafiltration: factors influencing flux and rejection. In Progress in Filtration and Separation, ed. R. J., Wakeman, Vol. 4, Elsevier, Amsterdam, pp. 101–79.
Henry, J. D. (1984). Novel solid-liquid separation processes. In Perry’s Chemical Engineers Handbook, 6th edn, McGraw Hill, New York, pp. 17.51–17.56.
Henry, J. D., Lawler, L. F. & Kuo, C. H. A. (1977). A solid/liquid separation process based on cross-flow and electrofiltration. AIChemE J., 23, 851–9.
Hunter, R. J. (1981). Zeta Potential in Colloid Science, Academic Press, London.
Ibanez, J. A., Forte, J., Hernandez, A. & Tejerina, F. (1988). Streaming potential and phenomenological coefficients in Nuclepore membranes. J. Membr. Sci., 36, 45-54.
James, A. E. & Williams, D. J. A. (1992). Improved calculation of electrokinetic flow parameters for porous media, AIChemE Journal, in press.
Kimura, S. & Tamano, A. (1986). Separation of amino acids by charged ultrafiltration membranes. In Membranes and Membrane Processes, ed. E. Drioli & M. Nakagaki, Plenum, New York, pp. 191–7.
Lacey, R. E. (1988). Dialysis and electrodialysis. In Handbook of Separation Techniques for Chemical Engineers, ed. P. A. Schweitzer, 2nd edn, McGraw-Hill, New York, pp. 1-479–1-495.
Lee, C. K. & Hong, J. (1988). Characterisation of electric charges in microporous membranes. J. Membr. Sci., 39, 79–88.
Levine, S., Marriott, J. R., Neale, G. & Epstein, G. (1975). Theory of electrokinetic flow in fine capillaries at high zeta-potentials. J. Colloid Interface Sci., 52, 136–49.
Masse, P., Martinez, P., Verdier, A. & Choe, T. B. (1988). Fouling in ultrafiltration of macromolecular solutions. The role of ionic environment. Stud. Environ. Sci., 34, 235–44.
Matthiasson, E. (1983). The role of macromolecular adsorption in fouling of ultrafiltration membranes. J. Membr. Sci., 16, 23–36.
McDonogh, R. M., Fane, A. G. & Fell, C. J. (1989). Charge effects in the cross-flow filtration of colloids and particulates. J. Membr. Sci., 43, 69–85.
McDonogh, R. M., Fell, C. D. & Fane, A. G. (1984). Surface charge and permeability in the ultrafiltration of non-flocculating colloids. J. Membr. Sci., 21, 285–94.
Nakao, S., Osada, H., Kurata, H., Tsura, T. & Kimura, S. (1988). Separation of proteins by charged ultrafiltration membranes. Desalination, 70, 191–205.
Nyström, M., Lindström, M. & Matthiasson, E. (1989). Streaming potential as a tool in the characterisation of microfiltration membranes. Colloids Surfaces, 36, 297–312.
Radovich, J. M. & Sparks, R. E. (1979). Electrophoretic techniques for controlling concentration polarisation in ultrafiltration. In Ultrafiltration Membranes and Applications, ed. A. R. Cooper, Plenum Press, New York, pp. 249–67.
Radovich, J. M., Mason, N. S. & Sparks, R. E. (1980). Coupling electrophoresis with ultrafiltration for improved processing of plasma proteins. Sep. Technol., 15, 1491–8.
Rios, G. M., Rakataoarisoa, H. & Tarado de la Fuente, B. (1988). Basic transport mechanisms in ultrafiltration in the presence of an electric field. J. Membr. Sci., 38, 147–59.
Smoluchowski, M. (1914). In Handbuch der Elektriziat und des Magnetismus, ed. B. Graetz, Vol. 2, Liepzig, p. 366.
Shaw, D. J. (1969). Electrophoresis, Academic Press, New York.
Spiegler, K. S. & Macleish, J. H. (1981). Molecular osmotic and electro-osmotic backwash of cellulose acetate hyperfiltration membranes. J. Membr. Sci., 8, 173–91.
Visvanathan, C. & Ben Aim, R. (1990). Enhancing electrofiltration with the aid of an electro-osmotic backwashing arrangement. Filtr. Sep., 27, 42–4.
Vivoni-Assice, D. (1989). Influence d’un champ électrique continu sur le transfert de solvant en ultrafiltration, Thèse du grade de Docteur de l’Université Paul Sabatier, Toulouse.
Wakeman, R. J. & Tarleton, E. S. (1987). Membrane fouling prevention in cross-flow microfiltration by the use of electric fields. Chem. Eng. Sci., 42, 829–42.
Wijmans, J. G., Nakao, S. & Smolders, C. A. (1984). Flux limitation in ultrafiltration: osmotic pressure model and gel layer model. J. Membr. Sci., 20, 115–24.
Yukawa, H., Shimura, K., Suda, A. & Maniwa, A. (1983). Cross-flow electro-ultrafiltration for colloidal protein solution. J. Chem. Eng. Jpn., 16, 305–11.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Bowen, W.R. (1993). Electrochemical Aspects of Microfiltration and Ultrafiltration. In: Howell, J.A., Sanchez, V., Field, R.W. (eds) Membranes in Bioprocessing: Theory and Applications. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2156-9_8
Download citation
DOI: https://doi.org/10.1007/978-94-011-2156-9_8
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4954-2
Online ISBN: 978-94-011-2156-9
eBook Packages: Springer Book Archive