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The Morphology and Growth of Paraffin Crystals with Different Structures

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Crystallization of Polymers

Part of the book series: NATO ASI Series ((ASIC,volume 405))

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Abstract

Principles of the integrated thermal roughening — crystallographic morphological theory of Hartman and Perdok are applied to n-paraffin crystals with orthorhombic, monoclinic and triclinic structure. Theoretical predictions are confronted with the observed morphology of crystals. They agree very well. In addition, the character of the solid-fluid interface is discussed. Finally, a newly found kinetic phenomenon, rough-flat-rough transition of crystal surfaces, is presented.

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References

  1. Bennema, P. and van der Eerden, J.P. (1987) ‘Crystal graphs, connected nets, roughening transition and the morphology of crystals’, in I. Sunagawa (ed), Morphology of crystals, Terra Sci. Publ. Co., Tokyo, 1–75.

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© 1993 Springer Science+Business Media Dordrecht

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Liu, X.Y., Bennema, P. (1993). The Morphology and Growth of Paraffin Crystals with Different Structures. In: Dosière, M. (eds) Crystallization of Polymers. NATO ASI Series, vol 405. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1950-4_31

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  • DOI: https://doi.org/10.1007/978-94-011-1950-4_31

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4862-0

  • Online ISBN: 978-94-011-1950-4

  • eBook Packages: Springer Book Archive

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