Abstract
Structural and optical properties of siloxene (Si6O3H6) and its derivates obtained by chemical substitution or annealing are reviewed. The preparation of siloxene is briefly described and results of x-ray diffraction and infrared absorption are shown. The equilibrium structures of stoichiometric siloxene and the electronic properties of the corresponding two-, one-, and zero-dimensional Si-clusters are obtained from quantum chemical calculations. Experimental results concerning luminescence, luminescence excitation, absorption coefficients, magnetic resonance, and stability are discussed.
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References
L.T. Canham, Appl. Phys. Lett. 57, 1046 (1990).
A. Richter, P. Steiner, F. Kozlowski, and W. Lang, IEEE Electron Dev. Lett. 12, 691 (1991).
M.S. Brandt, H.D. Fuchs, M. Stutzmann, J. Weber, and M. Cardona, Solid State Commun. 81, 307 (1992).
M. Stutzmann, J. Weber, M.S. Brandt, H.D. Fuchs, M. Rosenbauer, P. Deak, A. Höpner, and A. Breitschwerdt, Adv. Solid State Phys. 32, 179 (1992).
F. Wöhler, Lieb. Ann. 127, 257 (1863).
N. Matsumoto, K. Takeda, H. Teramae, and M. Fujino, Adv. in Chem., Vol. 224 (Amer. Chem. Soc, Washington, 1990). p. 515.
A. Weiss, G. Beil, and H. Meyer,Z. Naturforschung 35b, 25 (1980).
H. Ubara, T. Imura, A. Hiraki, I. Hirabayashi, and K. Morigaki, J. Non-Cryst. Solids 59&60, 641 (1983).
J.F. Morar and M. Wittner, J. Vac. Sci. Technol. A 6, 1340 (1988).
H. Kautsky, Z. Anorg. Chem. 117, 209 (1921).
M.S. Brandt, A. Breitschwerdt, H.D. Fuchs, A. Höpner, M. Rosenbauer, M. Stutzmann, and J. Weber, Appl. Phys. A 54, 567 (1992).
P. Deak, M. Rosenbauer, M. Stutzmann, J. Weber, and M.S. Brandt, Phys. Rev. Lett. 69, 2531 (1992).
K. Takeda and K. Shiraishi, Phys. Rev. B 39, 11028 (1989).
H. Kautsky and G. Herzberg, Z. Anorg. Chem. 139, 135 (1924).
E. Hengge, Chem. Ber. 95, 648 (1962).
G. Schott, Z. Chem. (Leipzig) 3, 41 (1963).
I. Hirabayashi, K. Morigaki, and S. Yamanaka, J. Non-Cryst. Solids 59&60, 645 (1983).
I. Hirabayashi, K. Morigaki, and S. Yamanaka, J. Phys. Soc. Japan 52, 671 (1983).
K. Morigaki, I. Hirabayashi, M. Nakayama, S. Nitta, and K. Shimakawa, Solid State Commun. 33, 851 (1980).
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© 1993 Springer Science+Business Media Dordrecht
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Stutzmann, M. et al. (1993). Optical Properties of Siloxene and Siloxene Derivates. In: Lockwood, D.J., Pinczuk, A. (eds) Optical Phenomena in Semiconductor Structures of Reduced Dimensions. NATO ASI Series, vol 248. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1912-2_37
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DOI: https://doi.org/10.1007/978-94-011-1912-2_37
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