Skip to main content
SpringerLink
Log in

The Parameterisation of Metal Centred Redox Couples

  • Chapter
Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

Part of the book series: NATO ASI Series ((ASIC,volume 385))

Abstract

Crystal field theory played a dominant role, from the 1950s, in the renaissance of inorganic chemistry. Its ability to reproduce the d-d (crystal field) spectra of almost any metal complex, through combination of geometry and the use of simple equations involving the crystal field parameter, Dq, made a major impact on the field [1].

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Bibliography

  1. A. B. P. Lever, “Inorganic Electronic Spectroscopy”, Elsevier, Amsterdam, 1st Edn 1968, 2nd Edn. 1984.

    Google Scholar 

  2. P. M. Treichel, G. E. Dureen, and H. J. Mueh, J. Organomet. Chem.. 1972, 44, 339.

    Article  CAS  Google Scholar 

  3. P. M. Treichel, H. J. Mueh, and B. E. Bursten, IsrJ. Chem.. 1976,15, 253–257.

    Google Scholar 

  4. A. Sarapu, and R. F. Fenske, Inorg.Chem.. 1975,14, 247–253.

    Article  CAS  Google Scholar 

  5. C. J. Pickett, and D. Pletcher, J. Organomet. Chem.. 1975,102,327–333.

    Article  CAS  Google Scholar 

  6. J. Chatt, C. T. Kan, G. J. Leigh, C. J. Pickett, and D. R. Stanley, J. Chem. Soc. Dalton. 1980, 2032.

    Google Scholar 

  7. P. M. Treichel, and G. J. Essenmacher, Inorg. Chem.. 1976,15,146–150.

    Article  CAS  Google Scholar 

  8. P. M. Treichel, H. J. Mueh, and B. E. Bursten, J. Organomet. Chem.. 1976,110, C49.

    Article  CAS  Google Scholar 

  9. B. E. Bursten, and M. R. Green, Progress Inorg.Chem.. 1988,36,474.

    Google Scholar 

  10. J. Chatt, Coord. Chem. Rev., 1982,43, 337–348.

    Article  CAS  Google Scholar 

  11. A. J. L. Pombeiro, Portug. Electrochim. Acta. 1985,3,41–66; A. J. L. Pombeiro, Inorg. Chim. Acta. 1985,103, 95–103; A. J. L. Pombeiro; C. J. Pickett, and R. L. Richards, R.L. J. Organomet. Chem., 1982, 224, 285–294; M. Fernanda, N. N. Carvalho, and A. J. L. Pombeiro, J. Chem. Soc. Dalton, 1989,1209 12. J. Chatt, W. Hussain, G. J. Leigh, H. M. Ali, C. J. Pickett, and D. A. Rankin, J. Chem. Soc. Dalton, 1985, 1131–1136.

    CAS  Google Scholar 

  12. G. Hussain, G. J. Leigh, H. M. Ali, C. J. Pickett, and D. A. Rankin, J. Chem. Soc. Dalton. 1984, 1703.

    Google Scholar 

  13. S. Goswami, R. Mukherjee and A. Chakravorty, Inorg. Chem. 1983,22,2825.

    Article  CAS  Google Scholar 

  14. A. B. P. Lever, Inorg. Chem.. 1990, 29,1271

    Article  CAS  Google Scholar 

  15. Note that Eqs.(10) and (11) in ref.[15a] were incorrectly set in print; they should appear as Eqs. (7) and (8) in this version.

    Google Scholar 

  16. D. D. Perin, Rev. Pure Appl. Chem. 1959,9, 257.

    Google Scholar 

  17. A. A. Vlcek, Progr. Inorg. Chem.. 1963, 5, 211.

    Article  CAS  Google Scholar 

  18. D. E. Richardson, Inorg. Chem.. 1990,30, 3213.

    Article  Google Scholar 

  19. C. M. Duff and G. A. Heath, J. Chem. Soc. Dalton Trans., 1990, 2401.

    Google Scholar 

  20. J. Lu, A. Yaman and M. Clarke, Inorg. Chem. 1990,29, 3483.

    Article  CAS  Google Scholar 

  21. A. B. P. Lever, Inorg. Chem. 1991, 30,1980.

    Article  CAS  Google Scholar 

  22. V. V. Strelets and S. V. Kukharenko, Dokl. Akad. Nauk. SSSR. 1984, 275, 894; V. V. Strelets, Coord. Chem. Rev.. 1992,000,0000.

    CAS  Google Scholar 

  23. S. K. Mandai and A. R. Chakravarty, Ind. J. Chem., 1990,29A, 18.

    Google Scholar 

  24. L. F. Szczepura and K. J. Takeuchi, Inorg. Chem., 1990,29, 1772.

    Article  CAS  Google Scholar 

  25. N. G. Connelly and M. D. Kitchen, J. Chem. Soc. Dalton. 1977, 931.

    Google Scholar 

  26. J. W. Hershberger and J. K. Kochi, Polyhedron. 1983, 2, 929.

    Article  CAS  Google Scholar 

  27. C. A. Tolman, Chem. Rev.. 1977, 77, 313.

    Article  CAS  Google Scholar 

  28. T. Bartik, T. Himmler, H-G. Schulte and K. Seevogel, J. Electroanal. Chem.. 1984, 272, 29.

    CAS  Google Scholar 

  29. A. B. P. Lever, work in progress.

    Google Scholar 

  30. H. Masui and A. B. P. Lever, Inorg. Chem. to be submitted shortly.

    Google Scholar 

  31. D. E. Wigley and R. A. Walton, Inorg. Chem., 1983, 22, 3138.

    Article  CAS  Google Scholar 

  32. W. E. Robinson, D. E. Wigley and R. A. Walton, Inora. Chem.. 1985, 24, 918.

    Article  CAS  Google Scholar 

  33. M. J. Clarke, personal communication 1991.

    Google Scholar 

  34. E. S. Dodsworth and A. B. P. Lever, Chem. Phys. Lett., 1986,124, 152.

    Article  CAS  Google Scholar 

  35. A. J. Lees, Chem. Revs., 1987,87, 711.

    Article  CAS  Google Scholar 

  36. J. W. Caspar, B. P. Sullivan and T. J. Meyer, Inorg. Chem.. 1984,23, 2104.

    Article  CAS  Google Scholar 

  37. L. A. Stacksteder, A. P. Zipp, E. A. Brown, J. Streich, J. N. Demas and B. A. De Graff, Inorg. Chem., 1990,29, 4335.

    Article  Google Scholar 

  38. V. Y. Kukushkin, V. E. Konovalov, N. S. Panina and V. N. Yakovlev, personal communication, 1991.

    Google Scholar 

  39. J. Lu and M. J. Clarke, J. Chem. Soc. Dalton. 1992, 000, and personal communication.

    Google Scholar 

  40. G. Jia and R. H. Morris, J. Am. Chem. Soc. 1991,113, 875.

    Article  CAS  Google Scholar 

  41. R. H. Morris, Inorg. Chem. 1992, 31, 0000.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dept. of Chemistry, York University, North York (Toronto), Ontario, Canada, M3J IP3

    A. B. P. Lever

Authors
  1. A. B. P. Lever
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Instituto Superior Técnico, Lisboa, Portugal

    A. J. L. Pombeiro

  2. School of Chemistry, University of Bristol, Bristol, UK

    J. A. McCleverty

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Lever, A.B.P. (1993). The Parameterisation of Metal Centred Redox Couples. In: Pombeiro, A.J.L., McCleverty, J.A. (eds) Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds. NATO ASI Series, vol 385. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1628-2_4

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-1628-2_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4710-4

  • Online ISBN: 978-94-011-1628-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation