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Electrochemical Generation of Substrate-Binding Sites in Organometallic Complexes with the {Mo2(μ-SR)n Core. Electrosynthesis of Cyanide and Isocyanide Derivatives.

  • F. Gloaguen
  • C. Le Floc’h
  • F. Y. Pétillon
  • P. Schollhammer
  • J. Talarmin
  • M. El Khalifa
  • J. Y. Saillard
Part of the NATO ASI Series book series (ASIC, volume 385)

Abstract

The electrochemical activation of dinuclear molybdenum thiolate complexes and the reactivity of electrogenerated intermediates toward CO, RNC and RCN are described.

Keywords

Cyclic Voltammetry Reductive Cleavage Chimie Analytique Radical Cation Intermediate Isocyanide Ligand 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1-.
    M. Guéguen, J.E. Guerchais, F.Y. Pétillon, and J. Talarmin, J. Chem. Soc, Chem.Commun., 1987, 557.Google Scholar
  2. 2-.
    M. El Khalifa, M. Guéguen, R. Mercier, F.Y. Pétillon, J.Y. Saillard and J. Talarmin, Organometallics, 1989,8,140.CrossRefGoogle Scholar
  3. 3-.
    M. El Khalifa, F.Y. Pétillon, J.Y. Saillard and J. Talarmin, Inorg.Chem., 1989,28, 3849.CrossRefGoogle Scholar
  4. 4-.
    M. Guéguen, F.Y. Pétillon, and J. Talarmin, Organometallics, 1989,8,148.CrossRefGoogle Scholar
  5. 5-.
    C. Le Floc’h, F.Y. Pétillon, C.J. Pickett, and J. Talarmin, J. Organomet. Chem., 1990,390,C39.CrossRefGoogle Scholar
  6. 6-.
    F. Gloaguen, C. Le Floc’h, F.Y. Pétillon, J. Talarmin, M. El Khalifa, and J.Y. Saillard, Organometallics, 1991,70,2004.CrossRefGoogle Scholar
  7. 7-.
    M. El Khalifa, F. Gloaguen, C. Le Floc’h, F.Y. Pétillon, J.Y. Saillard, and J. Talarmin, manuscript in preparation.Google Scholar
  8. 8-.
    J. Courtot-Coupez, M. Guéguen, J.E. Guerchais, F.Y. Pétillon, J. Talarmin, and R. Mercier, J. Organomet. Chem., 1986,31, 81.CrossRefGoogle Scholar
  9. 9-.
    M. Guéguen, F.Y. Pétillon, J. Talarmin, P. Jaitner, and W. Winder, Inorg.ChimActa, 1988, 144, 5.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1993

Authors and Affiliations

  • F. Gloaguen
    • 1
  • C. Le Floc’h
    • 1
  • F. Y. Pétillon
    • 1
  • P. Schollhammer
    • 1
  • J. Talarmin
    • 1
  • M. El Khalifa
    • 2
  • J. Y. Saillard
    • 2
  1. 1.URA CNRS 322, “Chimie, Electrochimie Moleculaires et Chimie Analytique”Université de Bretagne OccidentaleBrest-cedexFrance
  2. 2.URA CNRS 254, “Chimie du Solid et Inorganic Moleculaire”Université de Rennes IRennes-cedexFrance

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