Abstract
In this work a phenomenological model of 18O transport in a growing oxide film with parallel grain boundaries is proposed. The mathematical analysis for the three grain boundary transport regimes (A, B and C) is carried out. The analytical solution of the model, which describes both B and C type regimes as particular cases, permits to calculate tracer penetration profiles along grain boundaries depending on the drift velocity and time. The results of the profile analysis are presented as kinetic diagrams allowing to predict kinetic regimes of 18O transport under various conditions. The analytical solution obtained and the kinetic diagrams constructed can be used for the treatment of experimental profiles measured in two-stage oxidation experiments.
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© 1994 Springer Science+Business Media New York
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Mishin, Y.M., Borchardt, G., Wegener, W., Jedlinski, J. (1994). Evaluation of Oxygen Tracer Diffusion Profiles in Two-Stage Oxidation Experiments. In: Nickel, K.G. (eds) Corrosion of Advanced Ceramics. NATO Science Series E: (closed), vol 267. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1182-9_25
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DOI: https://doi.org/10.1007/978-94-011-1182-9_25
Publisher Name: Springer, Dordrecht
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