Abstract
Membrane reactors may be divided into two broad classes according to the area of application. For many years a number of biochemical processes have used membranes as a means of gas separation, for immobilisation of enzymes in biochemical reactors or as a means of adding oxidant gases to a biochemical mass. Examples of such processes include biogas production from wastes, effluent treatment in general and a number of downstream processing operations in biochemical processing. From a reactor point of view however, the main application is in the area of membrane-fixed enzymes. Use of such membranes in which the enzyme necessary for the biochemical transformation is immobilised enables the enzymes to be retained during processing and also ensures that the enzyme purity is not substantially adulterated. The enzyme may be immobilised in the porous structure of an asymmetric ultrafiltration membrane. Such a configuration has been shown to have considerable advantages over conventional production processes in terms of high enzyme density and high space-time yields. A number of reviews are available on the application of membranes in bioreactors (see for example those of Michaels and Matson1 and Drioli et al. 2
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References
A.S. Michaels and S.L. Matson, Desalination, 53, 231 (1985).
E. Drioli, G. Iorio and G. Capatano, in Handbook of Industrial Membrane Technology, M.C. Porter (ed.) Noyes (1990) p.401.
A.S. Michaels, Chem. Eng. Progr., 64, 31 (1968).
M.E.D. Raymont, Hydroc. Proc., 54, 139 (1975).
S.T. Hwang and K. Kammermeyer, Membranes in Separations, Wiley Interscience, New York (1975).
J.N. Armor, Appl. Catalysis, 49, 1, (1989).
P. Hsieh, AIChE Symp. Ser., 85, 18 (1989).
G. Saracco and V. Specchia, Cat. Rev. Sci. Eng., 36, 305 (1994).
V.M. Gryaznov and A.N. Karavanov, Khim.-Farm. Zh., 13, 74 (1979).
V.M. Gryaznov and V.S. Smirnov, Russ. Chem. Rev., 43, 821 (1974).
V.M. Gryaznov, V.P. Polyakova, E.M. Savitsky and E.V. Khrapova, U.S. Patent 4,026,458 (1977).
V.M. Gryaznov, Platinum Metal Res., 36, 70 (1992).
Y.S. Lin, Paper 23c, presented at AIChE Annual Meeting, Miami, Florida (1992).
T.M. Gur, A. Belzner and R.A. Huggins, J. Membrane Sci., 75 151 (1992).
N. Itoh, Y. Shindo, T. Hakuta and H. Yoshitone, Int. J. Hydrogen Energy, 9, 835 (1984).
E. Kikuchi, S. Uemiya, N. Sato, H. Inowe, H. Ando and T. Matsuda, Chem. Lett., 3, 489 (1989).
H. Nagamoto and H. Inoue, Bull. Chem. Soc. Jpn, 59, 3935 (1986).
A.M. Champagnie, T.T. Tsostis, R.G. Minet and I.A. Webster, Chem. Eng. Sci. 45, 2423 (1990).
N.L. Basov and V.M. Gryaznov, Membrane Katal., 117 (1985).
N. Itoh, Stud. Surf. Sci. Catal. 59, 268 (1990).
J.W. Veldsink, R.M.J, van Damme, G.F. Versteeg and W.P.M. Van Swaaij, Chem. Eng. Sci., 47, 2939 (1992).
V.T. Zaspalis, K. Keizer, W. van Praag, J.G. van Ommen, J.R.H. Ross and A.J. Burggraaf, Paper presented at AIChE National Meeting Denver, Colorado, Aug. 21–24 (1988).
A.G. Knapton, Platinum Metal Rev., 44 (1977).
S. Ilias and R. Govind, AIChE Symp. Ser., 85, 18 (1989).
E. Gobina, R. Hughes, D. Monaghan and R.D. Arnell, Dev. Chem. Eng. Mineral Proc., 2, 105 (1994).
E. Kikuchi and S. Uemiya, Gas Sep. Purification, 5, 261 (1991).
C.J. Brinker, T.L. Ward, R. Sehgal, N.K. Raman, S.L. Hietala, D.M. Smith, D.W. Smith, G.W. Hua and T.J. Headley J. Membrane Sci., 77, 165 (1993).
V.T. Zaspalis, Ph.D. Thesis, Universitait Twente (1990).
A.F.M. Leenaars, K. Keizer and A.J. Burggraaf, J. Material Sci., 10, 1077 (1984).
A. Larbot, J.A. Alany, J.P. Fabre, G. Guizard and L. Cot, Better Ceramics through Chemistry II, C.J. Brinker, D.E. Clark and D.R. Ulrich (eds), Material Research Society, Pittsburgh, PA (1986), p.659.
M.A. Anderson, M.J. Geiselman and Q. Xu, J. Membrane Sci., 39 243 (1988).
T. Masuda, A. Sato, H. Hara, M. Kuono and K. Hashimoto, Appl. Catal. A111, 143 (1994).
G.R. Gavalas, C.E. Megris and S.W. Nam, Chem. Eng. Sci., 44, 1829 (1989).
V.M. Gryaznov and V.S. Smirnov, Kinet. Katal., 18, 485 (1977).
A. Sieverts and W. Kumbhaar, Ber. Deut. Chem. Gas., 43, 893 (1910).
F.J. Ackerman and G.J. Kokinas, J. Chem. Eng. Data, 17, 51 (1972).
J. Chabot, J. Lecomte, C. Grumet and J. Sannier, Fusion Technol., 14, 614 (1988).
V.M. Gryaznov, V.I. Vedermikov and S.G. Gul’yanova, Trans. Kinet. Katal. 27, 142 (1986).
N. Itoh, Y. Shindo, K. Haraya and T. Hakuta, J. Chem. Eng. Jpn., 21, 399 (1988).
K. Keizer, R.J.R. Ulhorn, R.J. van Vurren and A.J. Burggraaf, J. Membrane Sci., 39 285 (1988).
Y. Liu, A.G. Dixon, Y.H. Ma and W.R. Moser, Sep. Sci. Technol., 25, 1511 (1990).
R.J.R. Ulhorn, K. Keizer and A.J. Burggraaf, J. Membrane Sci., 46, 225 (1989).
R.J.R. Ulhorn, K. Keizer and A.J. Burggraaf, ACS Symp. Ser., 239 (1989).
R.J.R. Ulhorn, K. Keizer and A.J. Burggraaf, Paper presented at ICOM’90, Chicago, IL (1990) Session 25, p.451.
K. Keizer, A.F.M. Leenaars and A.J. Burggraaf, European Conference Advances Energy Technology (1982) p.367.
T. Kameyama, M. Doyika, M. Fujishige, H. Yokohawa and K. Fukuda, Ind. Eng. Chem. Fundam., 20, 97, (1981).
T. Kameyama, K. Fukuda, M. Fujishige, H. Yokohawa and M. Dokiya, Adv. Hydrogenation Energy Prog., 2, 569 (1981).
D.J. Edlund and W.A. Pledger, J. Membrane Sci., 11, 225 (1993).
J. Yeheskel, D. Leyer and P. Courvoisier, Adv. Hydrogénation Energy, 2, 569 (1979).
S. Uemiya, N. Sato, H. Ando and E. Kikuchi, Ind. Eng. Chem. Res., 30, 385 (1991).
E.B. Nazarkina and N.A. Kimchenko, Khim. Technol Topl. Masel, 3, 5 (1979).
M. Oertel, J. Schmitz, W. Weirich, D. Jendryssek-Neumann and R. Schulten, Chem. Eng. Technol., 10, 248 (1987).
S. Uemiya, N. Sato, H. Ando, T. Matsuda and E. Kikuchi, Appl. Catal., 67 223 (1991).
E. Gobina and R. Hughes, J. Membrane Sci., 90, 11 (1994).
S. Uemiya, I. Koike and E. Kikuchi, Appl Catal., 76, 171 (1991).
V.S. Smirnov, V.M. Gryaznov, V.I. Lebedeva, A.P. Mischenko, V.P. Polyakova and E.M. Saritsky, U.S. Patent 4,064,188 (1977).
B.J. Wood, J. Catal., 11, 30 (1968).
N. Itoh, AIChE J., 33, 1576 (1987).
N. Itoh, K. Miura, Y. Shindo, K. Haraya, K. Obata and K. Wakabaishi, Sekiy Gakkaishi, 32, 47 (1989).
Y. Shindo, N. Itoh and K. Haraya, AIChE Symp. Ser., 85, 80 (1989).
D.R. Seok and S.T. Hwang, Stud. Surf. Sci. Catal., 54, 248 (1990).
T.T. Tsostis, A.M. Champagnie, S.P. Vasileidias, S.D. Ziaka and R.G. Minet, Sep. Sci. Technol., 28, 397 (1993).
J.Y. Song and S.T. Hwang, ICOM’90, Chicago, (1990), p. 30–540.
V.T. Zaspalis, W. van Praag, J.G. van Ommen, J.R.H. Ross and A.J. Burggraaf, Appl Catal., 74, 205 (1991).
A.M. Champagnie, T.T. Tsostis, R.G. Minet and E. Wagner, J. Catal., 134, 713 (1992).
J.G.A. Bitter, Br. Patent Appl. 2,201,159A (1988).
V.T. Zapalis, W. van Praag, K. Keizer, J.G. van Ommen, J.H.R. Ross and A.J. Burggraaf, Appl Catal., 74, 223 (1991).
O. Shinji, M. Misono and Y. Yoneda, Bull Sco. Chem. Soc. Japan., 55, 2760 (1982).
H.L. Fleming, Paper presented at BBC Membrane Planning Conference, Cambridge, MA (October 1990).
K.C. Cannon and J.J. Hacskaylo, J. Membr. Sci., 65, 259 (1992).
F. Tiscureno-Lechuga, G.C. Hill and M.A. Anderson, Appl. Catal., 96, (1) 33 (1993).
J.C.S. Wu, T.E. Gerdes, J.L. Pszezolkowski, B.R. Bhave and P.K. Liu, Sep. Sci. Technol., 25, 1489 (1990).
E. Gobina, K. Hou and R. Hughes, Chem. Eng. Sci., 50, 2311 (1995).
R. Zaho and R. Govind, Sep. Sci. Technol., 25, 1473 (1990).
V.M. Gryaznov, V.S. Smirnov and M.G. Slin’ko, 5th International Congress Catalogue, 80, 1139 (1972).
V.M. Gryaznov, Dokl Akad. Nauk SSR, 189, 794 (1969).
A. Ishikawa, T.H. Chiang and F. Toda, J. Chem. Soc. Chem. Commun., 764 (1989).
H. Nagamoto and H. Inoue, Chem. Eng. Comm., 34, 315 (1985).
H. Nagamoto and H. Inoue, J. Chem. Eng. Japan, 14, 377 (1981).
H. Suzuki. U.S. Patent 4,699,892 (1987).
K. Suzuki, Y. Kiyozumi and T. Sekine, Chem. Express, 5, 793 (1990).
WJ.W. Bakker, G. Zheng, F. Kapleijn, M. Makke, J.A. Moulijn, E.R. Geus and H. van Bekkum, in Precision Process Technology, M.P.C. Weijren and A.A.H. Drinkenburg (eds), Kluwer Academical Publishers, The Netherlands (1993).
M.D. Jia, B. Chen, R.D. Noble and J.L. Falconer, J. Membr. Sci. (1994).
E. Gobina, K. Hou and R. Hughes, J. Membr. Sci., 105, 163 (1995).
N. Itoh, Y. Shindo, K. Haraya, K. Obata, T. Hakuta and H. Yoshitome, Int. Chem. Eng., 25, 138 (1985).
K. Mohan and R. Govind. AIChEJ., 34, D1493 (1988).
F.M. Velterop, U.S. Pat. 5,139,191 (1992).
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Hughes, R. (1996). Membrane Reactors. In: Scott, K., Hughes, R. (eds) Industrial Membrane Separation Technology. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0627-6_9
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