Abstract
Electrochemical methods of detection are used for process analysis in a number of important areas, such as in the control of industrial processes, the monitoring of effluents and toxic gases in the environment and also in medicine [1]. The nature of the electrochemical parameter measured (i.e. a potential or a flow of charge) means that the signal can be easily processed by modern digital electronics for data collection and analysis so that any subsequent remedial feedback can be rapidly effected. In addition, some sensors will detect the presence of one particular species in the presence of other species found in the same solution, even at very reduced concentrations and the signal can be proportional to the concentration or activity of that species over several decades, down to, in some cases, the nanomolar level.
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References
H. V. Venkatasetty, Chem. Eng. Prog. 88 (1992) 63.
P. Debye and E. Huckel, Physikal. Z. 24 (1923) 185.
M. L. Hitchman and F. W. M. Nyasulu, Talanta 40 (1993) 1449.
J. B. Roos, Analyst 87 (1962) 832.
M. Dole, The Glass Electrode. Wiley, New York, USA, 1941.
IUPAC, Pure Appl. Chem. 51 (1979) 1913.
J. N. Harman, Process Instruments and Controls Handbook (3rd edn), ed. D. M. Considine. McGraw Hill, New York, USA, 1985.
J. Grigsby, J. Am. Soc. Brewing Chem. 38 (1980) 96.
D. Midgley and K. Torrance, Potentiometrie Water Analysis (2nd edn). Wiley, Chichester, UK, 1991.
J. Koryta, Ion Selective Electrodes. CUP, Cambridge, UK, 1975.
K. J. Clevett, Process Analyzer Technology. Wiley & Sons, New York, USA, 1986.
J. M. Coulson and J. F. Richardson, Chemical Engineering (Vol. 3). Pergamon, Oxford, UK, 1979, Ch. 5.
J. Vesely, D. Weiss and K. Stulik, Analysis with Ion Selective Electrodes. Ellis Horwood, Chichester, UK, 1978.
H. Freiser (ed.), Ion Selective Electrodes in Analytical Chemistry. Plenum, New York, USA, 1978.
W. E. Morf and W. Simon, In: Ion Selective Electrodes in Analytical Chemistry, ed. H. Freiser. Plenum, New York, USA, 1978, p. 211.
H. Wohltjon, Anal. Chem. 56 (1984) 87A.
A. P. F. Turner, I. Karube and G. S. Wilson, Biosensors, Fundamentals and Applications. OUP, Oxford, UK, 1989.
J. Haggin, C &E News June 4 (1984) 7.
W. J. Albery and M. L. Hitchman, Ring-Disc Electrodes. Clarendon Press, Oxford, UK, 1971.
B. Fleet and C. J. Little, Chromatogr. Sci. 12 (1947) 747.
A. J. Bard and L. R. Faulkner, Electrochemical Methods. Wiley, New York, USA. 1980.
J. Wang and H. D. Dewald, Anal. Chem. 56 (1984) 156.
H. Gunasingham and B. Fleet, In: Electroanalytical Chemistry (Vol. 16), ed. A. J. Bard, Marcel Dekker, New York, USA, 1989.
M. L. Hitchman, Measurement of Dissolved Oxygen. Wiley, New York, USA, 1978.
J. M. Hale and M. L. Hitchman, J. Electroanal Chem. 107 (1980) 281.
M. L. Hitchman and E. Gnaiger, In: Polarographic Oxygen Sensors, ed. E. Gnaiger and H. Forstner. Springer-Verlag, Berlin, Germany, 1983.
V. Linek, V. Vacek, J. Sinkule and P. Benes, Measurement of Oxygen by Membrane-Covered Probes. Ellis Horwood, Chichester, UK, 1988.
C. Excell and I. Rowland, Water and Waste Treatment, July (1991).
Neotronics Ltd, Portable Multi-Gas Monitors (Application Notes 058–0050, 058–0071). Takeley, 1993.
Orbisphere Laboratories, O 2, O 3, CO 2 or N 2 Analysis in Beer, Wine, Soft Drinks and Mineral Waters (Beverage Training Manual BTM 9403). Geneva, Switzerland, 1991.
J. M. Hale, Technical Note TN 179409, Orbisphere Laboratories, Geneva, Switzerland, 1991.
R. Mitchell, J. Hobson, N. Turner and J. M. Hale, Am. Soc. Brew. Chem. J. 41 (1983) 68.
M. L. Hitchman, results to be published.
S. Srinivasan and E. Gileadi, In: Handbook of Fuel Cell Technology, ed. C. Berger. Prentice Hall, New Jersey, USA, 1968, p 219.
M. W. Breiter, Electrochemical Processes in Fuel Cells. Springer-Verlag, Berlin, Germany, 1969, p. 238.
H. A. Liebhafsky and E. J. Cairns, Fuel Cells and Fuel Batteries. Wiley, New York, USA, 1969, Ch. 7, p. 245.
T. K. Sherwood, R. L. Pigford and C. R. Wilke, Mass Transfer. McGraw Hill, New York, USA, 1975, Ch. 2, p. 8.
L. W. Niedrach and H. R. Alford, J. Electrochem. Soc. 112 (1965) 117.
J. P. Hoare, The Electrochemistry of Oxygen. Interscience, New York, USA, 1968, p. 188.
L. G. Austin, In: Handbook of Fuel Cell Technology, ed. C. Berger. Prentice Hall, New Jersey, USA. 1968, p. 1.
M. L. Hitchman, N. J. Cade, T. K. Gibbs and N. J. M. Hedley, results to be published.
M. L. Hitchman and H. A. O. Hill, Chem. Brit. 22 (1986) 1118.
K. Ito, S. Ikeda, K. Asai, H. Naruse, K. Ohkura, H. Ichihashi, H. Kamei and T. Kondo, In: Fundamentals and Applications of Chemical Sensors, ed. D. Schuetzle and R. Hammerle. ACS Symposium Series 309, Washington, DC, USA, 1986, Ch. 23.
W. J. Albery and C. M. A. Brett, J. Electroanal, Chem. 148 (1983) 201.
W. J. Albery, L. R. Svanberg and P. Wood, J. Electroanal. Chem. 162 (1984) 29.
W. J. Albery, M. S. Appleton, T. R. D. Pragnell, M. J. Pritchard, M. Uttamlal, L. E. Fieldgate, D. R. Lawrence and F. R. Sharpe, J. Appl. Electrochem. 24 (1994) 521.
W. J. Albery, P. N. Bartlett and D. H. Craston, J. Electroanal. Chem. 194 (1985) 223.
M. L. Hitchman and S. Ramanthan, Analyst 113 (1988) 35.
W. J. Albery, M. Uttamlal, M. S. Appleton, N. J. Freeman, B. B. Kebbekus and M. D. Neville, J. Appl. Electrochem. 24 (1994) 14.
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Hitchman, M.L., Berlouis, L.E.A. (1995). Electrochemical methods. In: McLennan, F., Kowalski, B.R. (eds) Process Analytical Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0591-0_7
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DOI: https://doi.org/10.1007/978-94-011-0591-0_7
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