Abstract
Photochemically generated 17-valence electron metal radicals react with ligands to form 19-electron complexes, e.g., reaction 1 [1]. The 19-electron complexes are versatile reducing agents and we reported that they can be used to reduce a variety or organic, organometallic, and inorganic complexes, e.g., reaction 2. In addition to their versatility, two other features make the 19-electron complexes ideal choices as reducing agents for many applications. First, the complexes are easy to generate: the metal-metal bonded dimers are convenient precursors and the wavelength of irradiation (λ > 500 nm) generally precludes substrate absorption. Second, the 19-electron complexes are powerful reducing agents. In some cases, we estimate their oxidation potential to be 2 V or higher.
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© 1995 Springer Science+Business Media Dordrecht
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Tyler, D.R. (1995). Organometallic Radical Chemistry in Aqueous Solution. In: Horváth, I.T., Joó, F. (eds) Aqueous Organometallic Chemistry and Catalysis. NATO ASI Series, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0355-8_5
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DOI: https://doi.org/10.1007/978-94-011-0355-8_5
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