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Photochemistry of Organic Molecules Within Zeolites: Role of Cations

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Inclusion Chemistry with Zeolites: Nanoscale Materials by Design

Part of the book series: Topics in Inclusion Science ((TISC,volume 6))

Abstract

Photochemistry in organized media has attracted considerable attention during the last decade [1]. A number of materials have been utilized to “hold” molecules in a fixed orientation so as to initiate reactions. Often, such media do not remain “passive” and they themselves interact with the guest molecules and influence their photobehavior. When this occurs the material is considered to be “active” [2]. In this chapter, we are concerned with zeolites, which depending on the guest and the reaction remain either active or passive. Zeolites have been known for over two centuries and have been actively investigated by chemists with interest in their catalytic behavior for over three decades. However, photochemists’ interest in such systems is only recent and can be traced to a few classic papers published in the 1980’s [3]. In recent years, increasing interest in utilizing zeolites to influence the photobehavior of molecules has become evident. This chapter provides a brief summary of the work carried out in our laboratories in the area of photochemistry and photophysics of organic molecules included within X and Y zeolites. Work carried out in other zeolites is not part of this review. Although our work has been placed in a proper context with reference to the publications of others, no attempt has been made in this article to provide an exhaustive, in depth, and critical coverage of the literature [4].

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Authors
  1. V. Ramamurthy
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  2. Nicholas J. Turro
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Editors and Affiliations

  1. Central Research and Development Experimental Station, DuPont Company, Wilmington, DE, USA

    Norman Herron  & David R. Corbin  & 

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Ramamurthy, V., Turro, N.J. (1995). Photochemistry of Organic Molecules Within Zeolites: Role of Cations. In: Herron, N., Corbin, D.R. (eds) Inclusion Chemistry with Zeolites: Nanoscale Materials by Design. Topics in Inclusion Science, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0119-6_9

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  • DOI: https://doi.org/10.1007/978-94-011-0119-6_9

  • Publisher Name: Springer, Dordrecht

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  • Online ISBN: 978-94-011-0119-6

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