Abstract
The potential for coupling the shape selectivity associated with the well-defined channels and cages of zeolites with the reactivity of metal complexes makes these molecular sieves particularly attractive as solid supports. Zeolites have a distinct advantage over conventional support materials in that a metal complex can be physically trapped in the pores and not necessarily bound to the oxide surface. A metal complex of the appropriate dimensions might be encapsulated in a zeolite yet be free to move within the confines of a cage or channel. This could be viewed as a bridge between a homogeneous and heterogeneous system. Herron et al. [1] first referred to such zeolite guest molecules as ship-in-a-bottle complexes. This term has become quite popular in describing zeoliteencapsulated metal chelates and cluster complexes. The novel reactivity that was anticipated for zeolite ship-in-a-bottle complexes is gradually being realized as efforts in this area grow. In particular, progress in the area of biomimetic chemistry such as dioxygen binding and oxidation catalysis has elicited the terms inorganic protein [2,3] and zeozyme [4] to describe certain zeolite encapsulated metal complexes. In this context, even silicon-based life has been contemplated [5].
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Balkus, K.J., Gabrielov, A.G. (1995). Zeolite Encapsulated Metal Complexes. In: Herron, N., Corbin, D.R. (eds) Inclusion Chemistry with Zeolites: Nanoscale Materials by Design. Topics in Inclusion Science, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0119-6_6
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