Abstract
This chapter deals with the study of the molecular factors that affect the reactivity of organic model compounds over sulfided hydrotreating catalysts. For the foreseeable future, hydrotreating will remain a major processing for any modern refinery. However, it is difficult to determine how the use of hydrotreating will grow. The major reason for this uncertainty arises from the many alternate processes being considered for converting residual fractions and heavy fuels to clean liquid fuels. Another major factor affecting the growth of hydrotreating is the future of the synthetic fuels industry, particularly the upgrading of liquids from coal, shale, and tar sands, where the levels of oxygen and nitrogen are much higher than those of conventional crude oils; consequently, relatively more hydrotreating will be required.1
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References
McCulloch, D.C., Applied Industrial Catalysis (B.E. Leach, ed.). New York: Academic Press, 1983, p. 70.
News Brief, Appl. Catal. 14: 394 (1985).
Stinson, S.C., Chem. Eng. News 64(7): 27 (1986).
Weisser, O., Landa, S., Sulphide Catalysts, Their Properties and Applications. Oxford: Pergamon Press, 1973.
Le Page, J.F., Catalyse de Contact. Paris: Technip, 1978.
Acheson, R.M., The Chemistry of Heterocyclic Compounds—Acridines. New York: Interscience, 1953, p. 53.
Wheland, G.W., Resonance in Organic Chemistry. New York: Wiley, 1955, p. 75.
Cook, M.J., Katritzky, A.R., Linda, P., Adv. Heterocycl. Chem. 17: 255 (1974).
Gilchrist, T.L., Heterocyclic Chemistry. New York: Wiley, 1985, p. 5.
March, J., Advanced Organic Chemistry. New York: Wiley, 1985, p. 37.
See Ref. 7, Table 3.7, pp. 98-100.
Albert, A., Serjeant, E.P., The Determination of lonization Constants. London: Chapman and Hall, 1971.
Taft, R.W., Prog. Phys. Org. Chem. 14: 247 (1983).
Headley, A.D., J. Am. Chem. Soc. 109: 2347 (1987).
Headley, A.D., J. Org. Chem. 53: 312 (1988).
Moreau, C., Aubert, C., Durand, R., Zmimita, N., Geneste, P., Catalysis Today 4: 117 (1988).
See Ref. 7, p. 104.
Moyano, A., Paniagua, J.C., J. Org. Chem. 51: 2250 (1986).
Structure Reports19: 583 (1955).
Moreau, C., Durand, R., Zmimita, N., Geneste, P., J. Catal. 112: 411 (1988).
Breysse, M., Bachelier, J., Bonnelle, J.P., Cattenot, M., Cornet, D., Décamp, T., Duchet, J.C., Durand, R., Englehard, P., Frety, R., Gachet, C., Geneste, P., Grimblot, J., Gueguen, C., Kasztelan, S., Lacroix, M., Lavalley, J.C., Leclercq, C., Moreau, C., De Mourgues, L., Olivé, J.L., Payen, E., Portefaix, J.L., Toulhoat, H., Vrinat, M., Bull. Soc. Chim. Belg. 96: 829 (1987).
See Ref. 4, Table 27, pp. 126-127.
Sapre, A.V., Gates, B.C., Ind. Eng. Chem., Process Des. Dev. 20: 68 (1981).
Broderick, D.H., Sapre, A.V., Gates, B.C., Katzer, H., Schuit, G.C.A., J. Catal. 73: 45 (1982).
Wilson, M.F., Fisher, I.P., Kriz, J.F., J. Catal. 95: 155 (1985).
See Ref. 4, pp. 132-133.
Furimsky, E. Erdöl, Erdgas, Petrochem. Brennst. Chem. 36: 518 (1983).
Aubert, C., Durand, R., Geneste, P., Moreau, C., Zmimita, N., Actas Simp. Iberoam. Catal. (Soc. Iberoam. Catal., ed.). Venezuela: Merida, 1986, p. 1153.
Aubert, C., Doctorat Thesis, Montpellier, 1986.
Zmimita, N., Doctorat Thesis, Montpellier, 1987.
See Ref. 10, p. 39.
See Ref. 10, p. 40.
Toulhoat, H., Kessas, R., Rev. Fr. I.F.P. 41: 511 (1986).
Schulz, H., Schon, M., Rahman, N.M., Stud. Surf. Sci. Catal. 27: 201 (1986).
Bhinde, M.V., Shih, S., Zawadski, R., Katzer, J.R., Kwart, H. Proceedings of the Third International Conference on Chemistry and Uses of Molybdenum (H.F. Barry and P.C.H. Mitchell, eds.). Ann Arbor, MI: Climax Molybdenum Company, 1979, p. 184.
Jei, T., Doctorat Thesis, Montpellier, 1984.
Normant, H. Chimie Organique, Paris: Masson, 1963, p. 407.
Olivé, J.L., Biyoko, S., Moulinas, C., Geneste, P., Appl. Catal. 19: 165 (1985).
Stern, E.W., J. Catal. 57: 390 (1979).
Aubert, C., Durand, R., Geneste, P., Moreau, C., J. Catal. 97: 169 (1986).
Biyoko, S., Doctorat Thesis, Montpellier, 1984.
Mensah, J.B. Doctorat Thesis, Montpellier, 1987.
De Beer, V.H.J., Dahlmans, J.G.J., Smeets, J.G.M., J. Catal. 42: 467 (1976).
Structure Reports35B: 225 (1970).
Structure Reports39B: 230 (1973).
Structure Reports 39B: 240 (1973).
Aroney, M.J., Hoskins, G.M., Le Fèvre, R.J.W., J. Chem. Soc. (B) 980 (1969).
Rollmann, L.D., J. Catal. 46: 243 (1977).
Topsoe, H., Clausen, B.S., Appl. Catal. 25: 273 (1986), and references therein.
Aubert, C., Durand, R., Geneste, P., Moreau, C., J. Catal. 112: 12 (1988).
Cerny, M., Collect. Czech. Chem. Commun. 47: 1465 (1982).
La Vopa, V., Satterfield, C.N., J. Catal. 110: 375 (1986).
Nagai, M., Masunaga, T., Hana-Oka, N., J. Catal. 101: 284 (1986).
Geneste, P., Olivé, J.L., Biyoko, S., J. Catal. 83: 245 (1983).
Aubert, C., Durand, R., Geneste, P., Moreau, C.,Bull. Soc. Chim. Belg. 93: 653 (1984).
Hosoya, S., Acta Crystallogr. 16: 310 (1963).
Structure Reports20: 628 (1956).
Moreau, C., Bachelier, J., Bonnelle, J.P., Breysse, M., Cattenot, M., Cornet, D., Décamp, T., Duchet, J.C., Durand, R., Englehard, P., Fréty, R., Gachet, C., Geneste, P., Grimblot, J., Gueguen, C., Kasztelan, S., Lacroix, M., Lavalley, J.C., Leclercq, C., De Mourgues, L., Olivé, J.L., Payen, E., Portefaix, J.L., Toulhoat, H., Vrinat, M., Amer. Chem., Prepr. 32: 298 (1987).
Gevert, B.S., Otterstedt, J.E., Massoth, F.E., Appl. Catal. 31: 119 (1987).
Charton, M., Prog. Phys. Org. Chem. 13: 119 (1981).
See Ref. 10, p. 447.
Shabtai, J., Nag, N.K., Massoth, F.E., J. Catal. 104: 413 (1987).
Yang, S.H., Satterfield, C.N., J. Catal. 81: 168 (1983).
Kwart, H., Katzer, J., Horgan, J., J. Phys. Chem. 86: 2641 (1982).
Moreau, C., Bekakra, L., Olivé, J.L., Geneste, P., Proceedings of the Ninth International Congress on Catalysis (M.J. Phillips and M. Ternan, eds.). Calgary, Canada: Chemical Institute of Canada, 1988, Vol. 1, p. 58.
Finiels, A., Geneste, P., Moulinas, C., Olivé, J.L., Appl. Catal. 22: 257 (1986).
Saunders, W.H., Jr., Cockerill, A.F., Mechanisms of Elimination Reactions, New York: Wiley, 1973.
See Ref. 67, p. 221.
Satterfield, C.N., Smith, CM., Ingalis, M., Ind. Eng. Chem., Process. Des. Dev. 24: 1000(1985).
Moreau, C., Bekakra, L., Messahli, A., Olivé, J.L., Geneste, P., Stud. Surf Sci. Catal. 50: 115 (1989).
See Ref. 67, p. 1.
Gould, E.S., Mechanism and Structure in Organic Chemistry. London: Holt, Rinehart and Winston, 1969, p. 472.
Moreau, C., Durand, R., Geneste, P. (unpublished results).
See Ref. 67, p. 29.
Laine, R.M., Catal. Rev.-Sci. Eng. 25: 459 (1983).
Laine, R.M., New. J. Chem. 11: 543 (1987).
Duchet, J.C., Lavalley, J.C., Ouafi, D., Bachelier, J., Cornet, D., Aubert, C., Moreau, C., Geneste, P., Houari, M., Grimblot, J., Bonnelle, J.P., Catalysis Today 4: 97 (1988).
Kasztelan, S., Jalowiecki, L., Wambecke, A., Grimblot, J., Bonnelle, J.P., Bull. Soc. Chim. Belg. 96: 1003 (1987).
Roberts, J.T., Friend, CM., J. Am. Chem. Soc. 108: 7204 (1986).
Bussell, M.E., Somorjai, G.A., J. Catal. 106: 93 (1987).
Joffre, J., Geneste, P., Lerner, D.A., J. Catal. 97: 543 (1986).
Zdrazil, M., Sedlacek, J., Collect. Czech. Chem. Commun. 42: 3133 (1977).
Nikishenko, S.B., Slinkin, A.A., Antoshin, G.V., Minachev, Kh.M., Nefedofk, B.K., Proceedings of the Fourth International Conference on the Chemistry and Uses of Molybdenum (H.F. Barry and P.C.H. Mitchell, eds.,). Ann Arbor, MI: Climax Molybdenum Company, 1982, p. 51.
Hoffmann, R., J. Chem. Phys. 39: 1937 (1963).
Joffre, J., Lerner, D.A., Geneste, P., Bull. Soc. Chim. Belg. 93: 831 (1984).
Boudart, M., Kinetics of Chemical Processes. Englewood Cliffs, NJ: Prentice-Hall, 1968.
Massoth, F.E., Muralidhar, G., Proceedings of the Fourth International Conference on the Chemistry and Uses of Molybdenum (H.F. Barry and P.C.H. Mitchell, eds.). Ann Arbor, MI: Climax Molybdenum Company, 1982, p. 343.
Moreau, C., Bekakra, L., Durand, R., Zmimita, N., Geneste, P., Stud. Surf. Sci. Catal. 50: 115 (1989).
Kasztelan, S., Toulhoat, H., Grimblot, J., Bonnelle, J.P., Appl. Catal. 13: 127 (1984).
Massoth, F.E., Muralidhar, G., Shabtai, J., J. Catal. 85: 53 (1984).
Blekkan, E.A., Mitchell, P.C.H., Bull. Soc. Chim. Belg. 96: 961 (1987).
Wambeke, A., Jalowiecki, L., Kasztelan, S., Grimblot, J., Bonnelle, J.P., J. Catal. 109: 320 (1988).
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Moreau, C., Geneste, P. (1990). Factors Affecting the Reactivity of Organic Model Compounds in Hydrotreating Reactions. In: Theoretical Aspects of Heterogeneous Catalysis. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9882-3_7
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