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The Role of Next Nearest Neighbors in Zeolite Acidity and Activity

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Theoretical Aspects of Heterogeneous Catalysis

Part of the book series: Van Nostrand Reinhold Catalysis Series ((NRECSES))

Abstract

Knowledge of the acid chemistry and catalysis in zeolites has grown dramatically in the last 20 years. Early work described zeolites in terms of “strong” acidity and “superactivity.” Today, better understanding has made the amazing commonplace, and the chemistry has been placed in the context of well-established solution chemistry.

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References

  1. Benesi, H.A., Winquist, B.H.C., Adv. Catal. 27: 97–182 (1978).

    Article  CAS  Google Scholar 

  2. Atkinson, D., Curthoys, G., Chem. Soc. Revs. 8: 475–497 (1979).

    Article  CAS  Google Scholar 

  3. Forni, F., Catal. Rev. 8: 69 (1973).

    Google Scholar 

  4. Miale, J.N., Chen, N.Y., Weisz, P.B., J. Catal. 6: 278–287 (1966).

    Article  CAS  Google Scholar 

  5. Olson, D.H., Lago, R.M., Haag, W.O., J. Catal. 61: 390 (1980).

    Article  CAS  Google Scholar 

  6. Namba, S., Sato, K., Fujita, K. Kim, J.H., Yashima, T., Studies in Surface Science and Catalysis, Proceedings of the 7th International Zeolite Conference, Tokyo, Aug. 17–22, 1986. New York: Elsevier, 1986. Vol. 28, pp. 661–668.

    Google Scholar 

  7. Bremer, H., Wendlandt, K.-P., Chuong, T.K., Lohse, U., Stach, H., Becker, K., Proceedings of the Vth International Symposium on Heterogeneous Catalysis, Part I. Varna, 1983. pp. 435–439.

    Google Scholar 

  8. Sohn, J.R., DeCanio, S.J., Fritz, P.O., Lunsford, J.H., J. Phys. Chem. 90: 4847–4851 (1986).

    Article  CAS  Google Scholar 

  9. Beyerlein, R.A., McVicker, G.B., Yacullo, L.N., Ziemiak, J.J., J. Phys. Chem. 92: 1967–1970 (1988).

    Article  CAS  Google Scholar 

  10. Beaumont, R., Barthomeuf, D., J. Catal. 30: 288–297 (1973).

    Article  Google Scholar 

  11. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry and Use. New York: John Wiley and Sons, 1974.

    Google Scholar 

  12. Barrer, R.M., Zeolites and Clay Minerals as Sorbents and Molecular Sieves. New York: Academic Press, 1978.

    Google Scholar 

  13. van Olphen, H., Fripiat, J.J., Data Handbook for Clay Materials and Other Nonmetallic Minerals. New York: Pergamon, 1979.

    Google Scholar 

  14. Roy, R., Brindley, G.W., Natl. Acad. Sci. Publ. 456: 125–132 (1956).

    Google Scholar 

  15. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry and Use. New York: John Wiley and Sons, 1974, p. 495.

    Google Scholar 

  16. Stishov, S.M., Popova, S.V., Geokhimiya 10: 837 (1961).

    Google Scholar 

  17. Liebau, F., Bissert, G., Koppen, N., Z. Anorg. Allgem. Chem. 359: 113–134 (1968).

    Article  CAS  Google Scholar 

  18. Bissert, G., Liebau, F., Acta Cryst. 26: 233–240 (1970).

    Article  CAS  Google Scholar 

  19. Rosenheim, A., Raibmann, B., Schendel, G., Z. Anorg. Allgem. Chem. 196: 160–176 (1931).

    Article  CAS  Google Scholar 

  20. Wells, A.F., Structural Inorganic Chemistry, 5th ed. Oxford: Clarendon Press, 1984.

    Google Scholar 

  21. Barrer, R.M., Hydrothermal Chemistry of Zeolites. New York: Academic Press, 1982, p. 79.

    Google Scholar 

  22. Weisz, P.B., Ind. Eng. Chem. Fundam. 25: 53–58 (1986).

    Article  CAS  Google Scholar 

  23. Haag, W.O., Lago, R.M., Weisz, P.B., Nature 309: 589–591 (1984).

    Article  CAS  Google Scholar 

  24. Klinowski, J., Thomas, J.M., Fyfe, CA., Gobbi, G.C., Nature 296: 533 (1982).

    Article  CAS  Google Scholar 

  25. Klinowski, J., Thomas, J.M., Fyfe, C.A., Gobbi, G.C., Hartman, J.S., Inorg. Chem. 22: 63 (1983).

    Article  CAS  Google Scholar 

  26. Fyfe, C.A., Thomas, J.M., Klinowski, J., Gobbi, G.C., Angew. Chemie, Int. Edn. 22: 259 (1983).

    Article  Google Scholar 

  27. Gilson, J.P., Edwards, G.C., Peters, A.W., Rajagopalan, K., Wormsbecher, R.F., Roberie, T.G., Shatlock, M.P., J. Chem. Soc, Chem. Commun., 91–92 (1987).

    Google Scholar 

  28. Hey, J.S., Taylor, W.H., Zeit. Krist. 80: 428 (1931).

    CAS  Google Scholar 

  29. Vaughn, M.T., Weidner, D.J., Phys. Chem. Minerals 3: 133–144 (1978).

    Article  Google Scholar 

  30. Cruickshank, M.C., Dent-Glasser, L.S., Barri, S.A.I., Poplett, I.J.F., J. Chem. Soc, Chem. Commun., 23–24 (1986).

    Google Scholar 

  31. Maher, P.K., Baker, R.W., McDaniel, C.V., U.S. Patent 3, 423, 332 (January 21, 1969).

    Google Scholar 

  32. Eberly, P.E., U.S. Patent 3, 631, 120 (December 28, 1971).

    Google Scholar 

  33. Liu, X., Klinowski, J., Thomas, J.M., J. Chem. Soc, Chem. Commun., 582–584 (1986).

    Google Scholar 

  34. Man, P., Klinowski, J., Chem. Phys. Lett. 147: 581–584 (1988).

    Article  CAS  Google Scholar 

  35. Field, F.H., Head, H.H., Franklin, J.L., J. Amer. Chem. Soc. 84: 1118 (1962).

    Article  CAS  Google Scholar 

  36. Hertel, G.R., Koski, W.S., J. Amer. Chem. Soc. 87: 1686 (1965).

    Article  CAS  Google Scholar 

  37. Wexler, S., J. Amer. Chem. Soc. 85: 272 (1963).

    Article  CAS  Google Scholar 

  38. Olah, G.A., Surya Prakash, G.K., Sommer, J., Superacids. New York: John Wiley and Sons, 1985.

    Google Scholar 

  39. Bruckenstein, S., Kolthoff, I.M., Treatise on Analytical Chemistry (I.M. Kolthoff and P.J. Elving, eds.). New York: John Wiley and Sons, 1964. Part I, Vol. 5, pp. 2707–2838.

    Google Scholar 

  40. Simmons, V.E., Ph.D. Dissertation, Boston University, 1963.

    Google Scholar 

  41. Lowenstein, W., Am. Mineral. 39: 92 (1954).

    Google Scholar 

  42. Meier, W.M., Moeck, H.J., J. Solid State Chem. 27: 349–355 (1979). (b) Brunner, G.O., J. Solid State Chem. 29: 41-45 (1979). (c) Brunner, G.O., Nature 337: 146-147 (1989).

    Article  CAS  Google Scholar 

  43. Sato, M., Ogura, T., Anal. Chim. Acta 133: 759–764 (1981).

    Article  CAS  Google Scholar 

  44. Engelhardt, G., Michel, D., High Resolution Solid State NMR of Silicates and Zeolites. New York: John Wiley and Sons, 1987, pp. 222–238.

    Google Scholar 

  45. Meier, W.M., Olson, D.H., Atlas of Zeolite Structure Types, 2nd ed. Stoneham: Butterworths, 1988.

    Google Scholar 

  46. Smith, J.V., Chem. Rev. 88: 149–182 (1988).

    Article  CAS  Google Scholar 

  47. Beaumont, R., Barthomeuf, D., J. Catal. 26: 218–225 (1972).

    Article  CAS  Google Scholar 

  48. Beaumont, R., Barthomeuf, D., J. Catal. 27: 45–51 (1972).

    Article  CAS  Google Scholar 

  49. Beaumont, R., Barthomeuf, D., J. Catal. 30: 288–297 (1973).

    Article  Google Scholar 

  50. Drushel, H.V., Sommers, A.L., Anal. Chem. 38: 1723–1731 (1966).

    Article  CAS  Google Scholar 

  51. Deeba, M., Hall, W.K., J. Catal. 60: 417–429 (1979).

    Article  CAS  Google Scholar 

  52. Bezman, R., J. Catal. 68: 242–244 (1981).

    Article  CAS  Google Scholar 

  53. Ghosh, A.K., Curthoys, G., J. Chem. Soc, Faraday Trans. 1(79): 147–153 (1983).

    Google Scholar 

  54. Beaumont, R., Barthomeuf, D., Trambouze, Y., “Molecular Sieve Zeolites,” ACS Advances in Chemistry Series, 101 (EM. Flanigen and L.B. Sand, eds.). Washington, D.C.: American Chemical Society, 1971, pp. 327–336.

    Google Scholar 

  55. Barthomeuf, D., J. Phys. Chem. 83: 249–256 (1979).

    Article  CAS  Google Scholar 

  56. Barthomeuf, D. Materials Chemistry and Physics 17: 49 (1987).

    Article  CAS  Google Scholar 

  57. Mortier, W.J., J. Catal. 55: 138–145 (1978).

    Article  CAS  Google Scholar 

  58. Van Genechten, K.A., Mortier, W.J., Zeolites 8: 273–283 (1988).

    Article  Google Scholar 

  59. Jacobs, P.H., Catal. Rev.-Sci. Eng. 24: 415–440 (1982).

    Article  CAS  Google Scholar 

  60. Hocevar, S., Drzaj, B., J. Catal. 73: 205–215 (1982).

    Article  CAS  Google Scholar 

  61. Mikovsky, R.J., Marshall, J.F., J. Catal. 44: 170–173 (1976).

    Article  CAS  Google Scholar 

  62. Mikovsky, R.J., Marshall, J.F., J. Catal. 49: 120–121 (1977).

    Article  CAS  Google Scholar 

  63. Mikovsky, R.J., Marshall, J.F., Burgess, W.P., J. Catal. 58: 489–492 (1979).

    Article  CAS  Google Scholar 

  64. Dempsey, E., J. Catal. 33: 497–499 (1974).

    Article  CAS  Google Scholar 

  65. Dempsey, E., J. Catal. 39: 155–157 (1975).

    Article  CAS  Google Scholar 

  66. Dempsey, E., J. Catal. 49: 115–119 (1977).

    Article  CAS  Google Scholar 

  67. Peters, A.W., Symposium on Advances in Zeolite Chemistry, ACS Las Vegas Meeting, March 28-April 2, 1982, pp. 482–486.

    Google Scholar 

  68. Peters, A.W., J. Phys. Chem. 86: 3489–3491 (1982).

    Article  CAS  Google Scholar 

  69. Mikovsky, R.J., Zeolites 3: 90–92 (1983).

    Article  CAS  Google Scholar 

  70. Melchior, M.T., ACS Symp. Ser. 218, Intrazeolite Chem. 243–265 (1983).

    Google Scholar 

  71. Dwyer, J., Fitch, F.R., Nkang, E.E., J. Phys. Chem. 87: 5402–5404 (1983).

    Article  CAS  Google Scholar 

  72. Beagley, B., Dwyer, J., Fitch, F.R., Mann, R., Walters, J., J. Phys. Chem. 88: 1744–1751 (1984).

    Article  CAS  Google Scholar 

  73. Wachter, W.A., Proceedings of the 6th International Zeolite Conference, Reno, July 1983. England: Butterworths, 1983. pp. 141–150.

    Google Scholar 

  74. Ramdas, S., Thomas, J.M., Klinowski, J., Fyffe, CA., Hartman, J.S., Nature 292: 228–230 (1981).

    Article  CAS  Google Scholar 

  75. Cattanach, J., Wu, E.L., Venuto, P.B., J. Catal. 11: 342–347 (1968).

    Article  CAS  Google Scholar 

  76. Masuda, T., Taniguchi, H., Tsutsumi, K., Takahishi, H., Bull. Chem. Soc. Japan 52: 2849–2852 (1979). (b) Stach, H., Wendt, R., Lohse, U., Jaenchen, J., Spindler, H. Catalysis Today 3: 431-436 (1988). (c) Magnoux, P., Cartraud, P., Mignard, S., Guisnet, M., J. Catal. 106, 235-241 (1987).

    Article  CAS  Google Scholar 

  77. Klyachko, A.L., Kapustin, G.I., Brueva, T.R., Rubinstein, A.M., Zeolites 7: 119–122 (1987).

    Article  CAS  Google Scholar 

  78. Parra, C.F., Ballivet, D., Barthomeuf, D., J. Catal. 40: 52–60 (1975).

    Article  CAS  Google Scholar 

  79. Bankos, I., Valyon, J., Kapustin, G.I., Kallo, D., Klyachko, A.L., Brueva, T.R., Zeolites 8: 189–195 (1988).

    Article  CAS  Google Scholar 

  80. Kiovsky, J.R., Goyette, W.J., Notermann, T.M., J. Catal. 52: 25–31 (1978).

    Article  CAS  Google Scholar 

  81. Ratnaswamy, P., Sivasankar, S., Vishnoi, S., J. Catal. 69: 428–433 (1981).

    Article  Google Scholar 

  82. Bapu, G.P., Hegde, S.G., Kulkarni, S.B., Ratnasamy, P., J. Catal. 81: 471–477 (1983).

    Article  Google Scholar 

  83. Aurox, A., Gravelle, P.C., Vedrine, J.C., Rekas, M., in Proceedings of the 5th International Conference on Catalysis, Naples, 1980. (L.V. Rees, ed.). London: Heyden, 1980, pp. 433–439.

    Google Scholar 

  84. Fyfe, CA., et al., Zeolites 5: 179 (1985).

    Article  CAS  Google Scholar 

  85. Klinowski, J., Anderson, M.W., J. Chem. Soc, Faraday Trans. 1(82): 569 (1986).

    Google Scholar 

  86. Massiani, P., Fajula, F., Figueras, F., Sanz, J., Zeolites 8: 332–337 (1988).

    Article  CAS  Google Scholar 

  87. Gabelica, Z., Nagy, J.B., Bodart, P., Debras, G., Derouane, E.G., Jacobs, P.A., in Zeolites: Science and Technology, F.R. Ribeiro, A.E. Rodrigues, L.D. Rollmann, and C Naccache, eds.). NATO ASI Series, Series E: Applied Sciences, No. 80, 1984, pp. 193–210.

    Google Scholar 

  88. Debras, G., Nagy, J.B., Gabelica, Z., Bodart, P., Jacobs, P.A., Chem. Lett., 199 (1983).

    Google Scholar 

  89. Itabashi, K., Okada, T., Igawa, K., Studies in Surface Science and Catalysis, Proceedings of the 7th International Zeolite Conference, Tokyo, Aug. 17–22, 1986. New York: Elsevier, 1986. Vol. 28, pp. 369–376.

    Google Scholar 

  90. Derouane, E.G., Fripiat, J.G., Zeolites 5: 165 (1985).

    Article  CAS  Google Scholar 

  91. Derouane, E.G., Fripiat, J.G., Proceedings of the 6th International Zeolite Conference, Reno, July 1983. England: Butterworths, 1983, pp. 717–726.

    Google Scholar 

  92. Fripiat, J.G., et al., J. Phys. Chem. 89: 1932 (1985).

    Article  CAS  Google Scholar 

  93. O’Malley, P.J., Dwyer, J., Zeolites 8: 317–321 (1988).

    Article  Google Scholar 

  94. Lago, R.M., Haag, W.O., Mikovsky, R.J., Olson, D.H., Hellring, S.D., Schmitt, K.D., Kerr, G.T., Studies in Surface Science and Catalysis, Proceedings of the 7th International Zeolite Conference, Tokyo, Aug. 17–22, 1986. New York: Elsevier, 1986, Vol. 28, pp. 677–684.

    Google Scholar 

  95. Baes, CF., Mesmer, R.E., The Hydrolysis of Cations. New York: John Wiley and Sons, 1976.

    Google Scholar 

  96. Kuehl, G.H., Schweizer, A.E., J. Catal. 38: 469–476 (1975).

    Article  CAS  Google Scholar 

  97. Bolton, A.P., Lanewala, M.A., J. Catal. 18: 154–163 (1970).

    Article  CAS  Google Scholar 

  98. Mirodatus, C., Barthomeuf, D., J. Catal. 57: 136–146 (1979).

    Article  Google Scholar 

  99. Anufriev, D.M., Kuznetsov, P.N., lone, K.G., React. Kinet. Catal. Lett. 9: 297–302 (1978).

    Article  CAS  Google Scholar 

  100. Anufriev, D.M., Kuznetsov, P.N., Lone, K.G., J. Catal. 65: 221–226 (1980).

    Article  CAS  Google Scholar 

  101. DeCanio, S.J., Sohn, J.R., Fritz, P.O., Lunsford, J.H., J. Catal. 101: 132–141 (1986).

    Article  CAS  Google Scholar 

  102. Tsutsumi, K., Takahashi, H., J. Catal. 24: 1–7 (1972).

    Article  CAS  Google Scholar 

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Wachter, W.A. (1990). The Role of Next Nearest Neighbors in Zeolite Acidity and Activity. In: Theoretical Aspects of Heterogeneous Catalysis. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9882-3_3

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  • DOI: https://doi.org/10.1007/978-94-010-9882-3_3

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