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Structure and Electronic Factors in Heterogeneous Catalysis: C≡C, C≡O, and C-H Activation Processes on Metals and Oxides

  • Chapter
Theoretical Aspects of Heterogeneous Catalysis

Part of the book series: Van Nostrand Reinhold Catalysis Series ((NRECSES))

Abstract

Progress in surface science and heterogeneous catalysis is by nature interdisciplinary. There are attempts to draw upon the viewpoint of the X-ray and electron crystallographer, hoping to obtain hard structural data. Yet, diffraction data from surfaces is difficult to obtain and analyze. Low energy electron diffraction (LEED) has played a prominent surface science role during the past 20 years,1 showing the patterns of well-ordered adsorbate overlayers on single-crystal surfaces of metals and a few cova-lent and ionic solids, but bond lengths and other structure details have been difficult to determine with this technique. Diffractive helium scattering has found limited use for structure determinations. Extended X-ray absorption fine structure spectroscopy (EXAFS) in its various forms is presently evolving as an interesting new tool for determining local coordination numbers and bond lengths at catalyst surfaces.

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  1. Alfred B. Anderson
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© 1990 Van Nostrand Reinhold

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Anderson, A.B. (1990). Structure and Electronic Factors in Heterogeneous Catalysis: C≡C, C≡O, and C-H Activation Processes on Metals and Oxides. In: Theoretical Aspects of Heterogeneous Catalysis. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9882-3_10

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  • DOI: https://doi.org/10.1007/978-94-010-9882-3_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-9884-7

  • Online ISBN: 978-94-010-9882-3

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