Organometallic 1.2 Shift Type Migration Reactions

  • Heinz Berke
  • Roald Hoffmann
Part of the Quantum Theory Chemical Reactions book series (QTCR, volume 2)

Abstract

The general reaction, Open image in new window a 1.2 shift of a ligand L to an unsaturated coordinated fragement xy, is a fundamental step in the organometallic realm. The case xy = CO has been popularly called the carbonyl insertion reaction. It is a key step in many homogeneous catalytic transformations (1–7), and possibly in some heterogeneous processes as well (8–10). Theoretical analyses of this crucial process are lacking, with the exception of a recent paper by Ruiz, Flores-Riveros and Navaro (11).

Keywords

Reaction Path Migrate Group Insertion Reaction Fragment Molecular Orbital Acceptor Orbital 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© D. Reidel Publishing Company 1981

Authors and Affiliations

  • Heinz Berke
    • 1
  • Roald Hoffmann
    • 1
    • 2
  1. 1.Department of ChemistryUniversity of KonstanzKonstanzGermany
  2. 2.Dept. of ChemistryCornell UniversityIthacaUSA

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