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Terminally reactive oligomers: telechelic oligomers and macromers

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New Methods of Polymer Synthesis
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Abstract

Oligomers are short-chain polymers; the name originates from the Greek words ‘oligo’, meaning few, and ‘mer’, meaning part. The dividing line between oligomers and polymers is a somewhat arbitrary one but is best considered as corresponding to a region beyond which the bulk physical and mechanical properties of the polymer no longer depend significantly on chain-length. This region will vary from polymer to polymer depending upon the chemical complexity of the repeat unit but corresponds typically to a degree of polymerization in the range 10–100.

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Ebdon, J.R. (1991). Terminally reactive oligomers: telechelic oligomers and macromers. In: Ebdon, J.R. (eds) New Methods of Polymer Synthesis. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9552-5_6

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